EVO-STIK IMPACT SPRAY ADHESIVE

Hazard statements (CLP)

H222, H319, H336, H412

Code

Statements

H222

Extremely flammable aerosol

SECTION 2: Hazards identification

Classification (1999/45/EEC) Classification of the substance or mixture Classification (EC 1272/2008)

Other physicochemical hazards

Flam. Aerosol 1 - H222 Human health EUH066;Eye Irrit. 2 - H319;STOT SE 3 - H336

Environmental hazards

Aquatic Chronic 3 - H412 Classification (1999/45/EEC) Xi;R36. F+;R12. R52/53, R66, R67. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16

Signal word

Danger

Hazard statements

H222 Extremely flammable aerosol. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P102 Keep out of reach of children. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing vapour/spray. P337+313 If eye irritation persists: Get medical advice/attention. P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P501 Dispose of contents/container in accordance with local regulations.

Supplemental label elements

P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P264 Wash contaminated skin thoroughly after handling. P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P403+233 Store in a well-ventilated place. Keep container tightly closed. P410+412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F. EUH066 Repeated exposure may cause skin dryness or cracking.

Other hazards

Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn even after use. Do not spray on a naked flame or any incandescent material - NO SMOKING

2.1 Classification of the substance or mixture

Physical and Chemical Hazards Flam. Aerosol 1 - H222 Human health EUH066;Eye Irrit. 2 - H319;STOT SE 3 - H336 Environment Aquatic Chronic 3 - H412 Classification (1999/45/EEC) Xi;R36. F+;R12. R52/53, R66, R67. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. 2.2. Label elements Label In Accordance With (EC) No. 1272/2008 Signal Word Danger Hazard Statements H222 Extremely flammable aerosol. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H412 Harmful to aquatic life with long lasting effects. Precautionary Statements P102 Keep out of reach of children. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P280 Wear protective gloves/protective clothing/eye protection/face protection. 2 / 7 P261 Avoid breathing vapour/spray. P337+313 If eye irritation persists: Get medical advice/attention. P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P501 Dispose of contents/container in accordance with local regulations. Supplementary Precautionary Statements P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P264 Wash contaminated skin thoroughly after handling. P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P403+233 Store in a well-ventilated place. Keep container tightly closed. P410+412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F. Supplemental label information EUH066 Repeated exposure may cause skin dryness or cracking. 2.3. Other hazards Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50C. Do not pierce or burn even after use. Do not spray on a naked flame or any incandescent material - NO SMOKING. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures ACETONE 10-30% CAS-No.: 67-64-1 EC No.: 200-662-2 Registration Number: 01-2119471330-49 Classification (EC 1272/2008) Classification (67/548/EEC) Flam. Liq. 2 - H225 F;R11 EUH066 Xi;R36 Eye Irrit. 2 - H319 R66 STOT SE 3 - H336 R67 BUTANE 10-30% CAS-No.: 106-97-8 EC No.: 203-448-7 Classification (EC 1272/2008) Classification (67/548/EEC) Flam. Gas 1 - H220 F+;R12 NAPHTHA (PETROLEUM), HYDROTREATED LIGHT, <0.1% BENZENE 5-10% CAS-No.: 64742-49-0 EC No.: 265-151-9 Classification (EC 1272/2008) Classification (67/548/EEC) Not classified. Xn;R65. Xi;R38. F;R11. N;R51/53. R67. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 3 / 7 4.1. Description of first aid measures General information Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Inhalation Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Keep the affected person warm and at rest. Get prompt medical attention. Ingestion Not relevant Skin contact Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist. 5.2. Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards Aerosol cans may explode in a fire. 5.3. Advice for firefighters Special Fire Fighting Procedures Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Let evaporate. Keep out of confined spaces because of explosion risk. If leakage cannot be stopped, evacuate area. 6.4. Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. 7.2. Conditions for safe storage, including any incompatibilities Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50°C. 7.3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 4 / 7 Name STD TWA - 8 Hrs STEL - 15 Min Notes ACETONE WEL 500 ppm 1210 mg/m3 1500 ppm 3620 mg/m3 BUTANE WEL 600 ppm 1450 mg/m3 750 ppm 1810 mg/m3 WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. Hand protection Use protective gloves. Eye protection Use eye protection. Other Protection Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Aerosol. Colour Clear Odour Hydrocarbon. Solvent. Solubility Slightly soluble in water. Initial boiling point and boiling range 40 (°C) Relative density 0.665 Flash point (°C) - 40 Not noted. Comments Can pressure 70psi 9.2. Other information SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity 10.2. Chemical stability Avoid Heat, sparks, flames. Stable under normal conditions. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents. Strong alkalis. Strong mineral acids. 5 / 7 10.5. Incompatible materials Materials To Avoid Strong acids. Strong oxidising substances. Strong alkalis. 10.6. Hazardous decomposition products Hydrogen cyanide (HCN). During fire, toxic gases (CO, CO2) are formed. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Inhalation Vapours may cause headache, fatigue, dizziness and nausea. Prolonged inhalation of high concentrations may damage respiratory system. May cause sensitisation by inhalation. Ingestion May cause discomfort if swallowed. Skin contact Acts as a defatting agent on skin. May cause cracking of skin, and eczema. Eye contact Irritating to eyes. Route of entry Inhalation. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment. 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vPvB assessment 12.6. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) 1950 14.2. UN proper shipping name 6 / 7 Proper Shipping Name AEROSOLS 14.3. Transport hazard class(es) ADR/RID/ADN Class 2.1 ADR/RID/ADN Class Class 2: Gases ADR Label No. 2.1 IMDG Class 2.1 ICAO Class/Division 2.1 Transport Labels