Note: Ingredients listed on restricted chemical lists
EC/CAS
100-42-5
Name of the chemical
Styrene ( Vinyl benzene )
Concentration
N/A
General Information
Revision date
2005-01-04
Product name
July 5, 2001
Substance name
July 5, 2001
CAS No.
100-42-5
1.2.1 Relevant identified uses
Wood repair Time)
Manufacturer Name
Bondo Corporation
Icons in SDS
Company Information
company name
Bondo Corporation
GHS Information
Signal word
Warning
Section 2
Principle Routes of Exposure
Inhalation, skin contact, ingestion, eyes Exposure Effects Acute and Chronic: Inhalation Acute Nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, headache, possible unconsciousness, central nervous system depression. Skin contact Acute Extraction of natural oils with resulting dry skin, irritation, redness and dermatitis. Can pass through the skin into the blood. Eye contact Acute Irritation, redness, pain, blurred vision, sensation of seeing halos around lights and reversible damage. Ingestion Acute Gastrointestinal irritation, nausea, vomiting and diarrhea; kidney damage, blood system damage Chronic: Repeated overexposure to these products may cause central nervous system damage, kidney damage, liver abnormalities, lung damage, cardiac abnormalities, reproductive organ damage, skin sensitization and dermatitis. Inhalation, skin contact, ingestion, eyes Personal Protective Equipment: In cases where no monitoring for airborne contaminants has been carried out, assume maximum exposure and use antistatic paint suit, goggles, gloves, and air supplied respiratory equipment. All personal protective equipment should meet NIOSH or OSHA requirements. Respiratory Protection: If monitoring demonstrates levels below TLV or PEL wear a NIOSH/MSHA approved respirator device. See safety equipment supplier for evaluation and recommendation. Ventilation: Provide sufficient ventilation to keep vapor concentration below the given TLV and/or PEL. Protective Gloves: Required for prolonged or repeated contact. Use solvent resistant gloves. Barrier creams are not substitutes for full physical protection. Refer to safety equipment supplier for effective glove recommendations. Eye Protection: Use safety goggles or face shield designed to protect against splash of liquids when working with open liquids such as during mixing or pouring. Other Protective Equipment: Eye bath and shower should be available. Use chemical resistant apron, boots or other clothing if needed to avoid repeated or frequent contact. Liquid may penetrate shoes and leather causing delayed irritation. Section 9 – Physical and Chemical Properties Evaporation Rate: Slower than ether Vapor Density: 3.6 Vapor Pressure: 4.5 mm Hg Weight per Gallon (Specific Gravity): 9.2 lb/gal (1.10)
Other Health Effects
Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Section 4 – First Aid Measures Emergency and First Aid Procedures: In all cases if symptoms persist, seek medical attention. Inhalation - move to fresh air, give artificial respiration if necessary. Skin contact - remove contaminated clothing, wash with soap and water or recognized skin cleaner. Do not use solvents or thinners. Eye contact - contact lenses must be removed, flush with water for at least 15 minutes, consult a physician immediately. Ingestion - drink one or two glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center immediately. Treat symptomatically Medical Conditions Prone to Aggravation: Pulmonary conditions, skin disorders, eye disorders, liver conditions, kidney conditions, neurological disorders, allergies, pregnancy, reproductive system disorders. Section 5 – Fire Fighting Measures Flash Point (SFCC): 82F (28C) Lower Explosive Limit: 1.1 Extinguishing Media: foam, carbon dioxide, dry chemical or water fog or spray. Water jet or stream is unsuitable. Unusual Fire and Explosion Hazards: Invisible vapors may travel to source of ignition and flash back. Since vapors are heavier than air, dangerous concentrations may not be apparent to casual observation. Keep containers tightly closed, isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heat. Fire will produce dense black smoke containing hazardous products of combustion. Symptoms may not be immediately apparent. Obtain medical attention. Special Fire Fighting Procedures: Water should be used to cool containers exposed to fire. Fire fighting personnel should wear self-contained breathing apparatus. Section 6 – Accidental Release Steps To Be Taken In Case Material Is Released Or Spilled: Remove all sources of ignition. Avoid breathing vapors, ventilate confined area. Remove with inert absorbent using non-sparking tools. If necessary report to applicable government agency. Section 7 – Handling and Storage
Precautionary statements
To Be Taken In Handling And Storing Minimize contact between the worker and this material. Do not transfer to unlabeled containers. No smoking. Store containers out of sun and away from heat, sparks, and open flames. Close all containers after each use. Consult NFPA and local codes for additional storage requirements. Hygienic Practices: Do not eat, drink or smoke in work areas. Wash hands before eating, smoking, or using the washroom. Launder clothing before reuse. Other Precautions: Vapors are heavier than air and may travel along floors. Use explosion proof equipment in areas where there is spraying or open containers. Do not take internally. Observe label precautions. Keep closures tight and container upright to prevent leakage. Avoid breathing sanding dust. The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risks as required by regulations. Section 8 – Exposure Controls
Appearance/Odor
organic odor, paste Freezing point, Coefficient of water/oil distribution ,pH: Not applicable or not available Section 10 – Stability and Reactivity Stability: Stable under non-emergency conditions. Materials to Avoid: Alkalis, acids, oxidizers, alkali metals, halogenated solvents, nitric acid, halogen compounds, water, sodium hydroxide. Hazardous Polymerization: Will not occur. Conditions to Avoid: High temperatures, flame, sparks, high humidity, light, water, moisture Hazardous Decomposition Products: Oxides of carbon, toxic fumes, various hydrocarbons, aldehydes.
TOXICOLOGICAL INFORMATION
Carcinogenicity (risk of cancer): Styrene is listed by IARC as possibly carcinogenic to humans (Group 2B). The IARC 2B classification is not based on significant new evidence that styrene might be a carcinogen, but on a revised IARC classification scheme and new data on styrene oxide. Sensitization (effects of repeated exposure): These products may cause skin and inhalation sensitization to certain individuals. Teratogenicity (risk of malformation in an unborn fetus): None known Reproductive Toxicity (risk of sterility): None known Mutagenicity (risk of heritable genetic effects): Mutation data has been reported for styrene. Threshold Limit Value: None established for this product. For further information, see Section 2 - Hazardous Ingredients
ECOLOGICAL INFORMATION
General Information: Avoid runoff into ground, storms or sewer that lead into waterways. Water runoff can cause environmental damage. The nature and packaging size of these products minimizes the potential for adverse ecological impact. Environmental Impact Data (percentage by weight): Ozone Depleters none Heavy Metals none See individual compositions, section 2. There are extensive ecological data available on the various components of these products. An adequate representation of all these data is beyond the scope of this document. Please contact the information phone number found in Section 1.
Disposal
Information Waste Disposal Method: Dispose of in accordance with federal, state or provincial and local pollution requirements. Clean-up preferably with a detergent, avoid the use of solvents. This information applies only to the material as manufactured; processing, use or contamination may make this information inappropriate, inaccurate or incomplete. The generator of the waste has the responsibility for proper waste classification, transportation and disposal. Section 14 – Transportation Information US Ground Shipments: Consumer Commodity ORM-D Section 15 - Regulatory Information OSHA: These products are considered hazardous under the Federal OSHA Hazard Communication Standard. WHMIS: B2;D1A;D2A SARA Title III: Section 302 Extremely Hazardous Substances: None Section 311 / 312 Hazard Categories: Immediate health, delayed health, fire hazard. Section 313 Toxic Chemicals: styrene. You may be required to submit this MSDS to state and local emergency response agencies (SERC & LEPC) and to your local fire department. Also, you may be affected by other sections of this law, depending on the chemicals and amounts that you inventory at your location. To learn more about your responsibilities, call the EPA Hotline (800) 535-0202. TSCA status: All ingredients are TSCA registered. Proposition 65 WARNING This product contains a chemical known to the State of California to cause cancer NFPA704 Health 2 Flammability 2 Reactivity 0 Section 16 - Preparation Information Prepared by Bondo Corporation Research and Development Department Phone: 404-696-2730 Do not handle until the manufacturer’s safety precautions have been read and understood. Regulations require that all employees be trained on Material Safety Data Sheets for all products with which they come in contact. While Bondo Corporation believes that the data contained herein are accurate and derived from qualified sources, the data are not to be taken as a warranty or representation for which Bondo Corporation assumes legal responsibility. They are offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with applicable federal, state, provincial and local laws and regulations. MATERIAL SAFETY DATA SHEET Liquid Hardener Date of Original Preparation: March 7, 2001 Revision Date: January 4, 2005
Product information
Manufacturer: Bondo Corporation 3700 Atlanta Industrial Parkway NW Atlanta, GA 30331 Emergency For US transportation emergencies call - For Canadian transportation emergencies Telephone: Chemtrec: 800-424-9300 call - Canutec: 613-996-6666 Information: 404-696-2730 (USA 8 30am – 4 30pm Eastern Product Use: Hardener Time) Emergency Overview Signs of Overexposure: Nausea, cough, dizziness, weakness, headache, chest pain, lack of coordination, shortness of breath, dermatitis, redness and/or pain in eyes. Emergency First Aid: Move to fresh air, remove contaminated clothing, wash effected skin with soap and water, do not use solvents or thinners; if product gets into eyes, remove contact lenses, flush with water for 15 minutes. Handling: When handling, wear an organic vapor cartridge respirator (NIOSH / OSHA), solvent resistant gloves and safety eye protection designed to guard against liquid splashes. Close all containers tightly after use. Do not eat, drink or smoke in work areas. Clean-up: Eliminate sources of ignition. Dike to reduce extent of spill if liquid. Remove with inert absorbent (vermiculite, clay, Oil-Dry®, Kitty Litter, etc.) using non-sparking tools. Transfer to a grounded metal container, seal container. Dispose of as hazardous waste. Other Precautions: Material has an offensive odor. Prolonged exposure may reduce the user’s sensitivity to the odor, thus reducing the effectiveness of odor as a warning against exposure. Fire Fighting: Organic peroxide, refer to Guide 145 of the North American Emergency Guide Book. NFPA Flammability: Containers of hardeners are not expected to cause fire fighting problems since the individual quantities are quite small. Bondo Corporation has no oversight with respect to the guidance practices or policies or manufacturing processes of other companies handling or using this material. The information given in this MSDS is only related to the product as shipped in its original condition as described in Section 2, “Hazardous Ingredients” and Section 9 “Physical and Chemical Properties”.
Hazardous Ingredients
by Vapor ACGIH OSHA LD50 LC50 weight CAS No. Press. TLV PEL Oral Derm Inhal. LEL Hydrogen Peroxide 1-5% 7722-84-1 1.0 1.4mg/m3 75 700 2000 n. ap Methyl Ethyl Ketone Peroxide 30-40% 1338-23-4 n. ap. 0.7ppm 0.2ppm 484 n. av. 200 n. av Dimethyl Phthalate (SARA313) 50-60% 131-11-3 n. ap. 5mg/m3 6800 n. av. 1213 n.ap LD50 Oral - rat mg/m3, LD50 Dermal - rabbit mg/m3,LC50 Inhalation - rat mg/m3 unless otherwise specified. Section 3 – Hazards Identification Primary Routes of Entry: Inhalation, skin contact, ingestion, eyes. Exposure Effects Acute and Chronic: Inhalation Acute Nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, headache, possible unconsciousness, central nervous system depression. V a p o rs are co rro sive to no se , th ro at an d lu n gs. Skin contact Acute Extraction of natural oils with resulting dry skin, irritation, redness and dermatitis Eye contact Acute Co n t act ma y ca use se ve re e ye da ma g e Ingestion Acute V e ry co rro sive ; ma y be harmf u l or fa t a l Chronic: Repeated overexposure to these products may cause central nervous system damage, kidney damage, liver abnormalities, lung damage, cardiac abnormalities, reproductive organ damage, skin sensitization and dermatitis. Other Health Effects: Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.