Epoxy Urethane Sealer - Clear

Hazard statements (CLP)

H334

Code

Statements

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled

SECTION 2: Hazards identification

OSHA 2. SECTION _________________________________________________________________________________________________________________ _________________________________________________________________________________________________________________ Hazard Overview

2.1 Classification of the substance or mixture

Dermal target Toxicity organ toxicity category single 4, Respiratory exposure sensitization category 3, Specific category target 1B, Skin organ toxicity corrosion/irritation following repeated category exposure 2, skin sensitizer category category 2, Acute Dermal 1B, Serious Toxicity eye category irritation 4, category Respiratory 2B, Acute sensitization toxicity category inhalation 1B, category Skin 4, corrosion/irritation Acute hazard to aquatic category environment 2, skin sensitizer category category 3, Chronic 1B, hazards Serious to eye aquatic irritation environment category category 2B, Acute 3 toxicity inhalation category 4, Acute GHS Label hazard Elements to aquatic and environment Precautionary category Statements

Environmental hazards

2, skin sensitizer category category 3, Chronic 1B, hazards Serious to eye aquatic irritation category category 2B, Acute 3 toxicity inhalation category 4, Acute

2.2 Label elements

hazard Elements to aquatic and environment Precautionary category

Hazard statements

3, Chronic hazards to aquatic environment category 3 GHS Label Label Elements: Elements Flame, and Health Precautionary Hazard Exclamation Mark Label Hazard Elements: Flame, Health Hazard Exclamation Mark Warning: Statements: Flammable liquid and vapor Warning: Warning: Flammable May cause liquid respiratory and vapor irritation Warning: May cause respiratory damage to irritation organs (auditory) through prolonged or repeated exposure Warning: May cause be harmful damage in contact to organs with (auditory) skin. through prolonged or repeated exposure Warning: Danger: May May cause be harmful allergy in or contact asthma with symptoms skin. or breathing difficulties if inhaled. Danger: Warning: May Causes cause skin allergy irritation or asthma symptoms or breathing difficulties if inhaled. Warning: Warning: Causes May cause skin an irritation allergic skin reaction Warning: May Causes cause serious an allergic eye irritation skin reaction Warning: Causes Harmful serious if inhaled eye irritation Warning: Harmful to Harmful aquatic if life inhaled Harmful to aquatic life with long lasting effects Harmful

Precautionary statements

to aquatic life with long lasting effects Precautionary P102 Keep out statements: of reach of children. P102 P103 Keep Read out label of before reach of use children. P103 P210 Read Keep away label before from heat/sparks/open use flames/hot surfaces. — No smoking. P210 P233 Keep away container from tightly heat/sparks/open closed. flames/hot surfaces. — No smoking. P233 P240 Keep Ground/bond container container tightly closed. and receiving equipment. P240 P241 Ground/bond Use explosion-proof container electrical/ventilating/lighting/…/equipment. and receiving equipment. P241 P242 Use explosion-proof only non-sparking electrical/ventilating/lighting/…/equipment. tools. P242 P243 Use Take only non-sparking tools. against static discharge. P243 P280 Take Wear precautionary protective gloves/protective measures against clothing/eye static discharge. protection/face protection. P280 P271 Wear Use only protective outdoors gloves/protective or in a well-ventilated clothing/eye area. protection/face protection. P271 P260 Use Do not only breathe outdoors dust/fume/gas/mist/vapours/spray or in a well-ventilated area. P260 P284 Do Wear not respiratory breathe dust/fume/gas/mist/vapours/spray protection P284 P264 Wear Wash respiratory hands thoroughly protection after handling. P264 P272 Wash Contaminated hands thoroughly work clothing after should handling. not be allowed out of the workplace. P272 P280 Contaminated Wear protective work gloves clothing and clothing should not to prevent be allowed skin out contact. of the workplace. P280 P273 Wear Avoid protective release to gloves the environment. and clothing to prevent skin contact. P273

Response

Avoid release to the environment. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P303 P370 + P361 P378 + In P353 case IF of ON fire: SKIN Use Foam, (or hair): alcohol Remove/Take foam, CO2, off dry Immediately chemical for all contaminated extinction. clothing. Rinse SKIN with water/shower. P370 P304 + P378 P340 In IF case INHALED: of fire: Remove Use Foam, victim alcohol to fresh foam, air and CO2, Keep dry chemical at rest in for a position extinction. comfortable for breathing. P304 P312 + If P340 inhaled, IF Call INHALED: a POISON Remove CENTER victim or to doctor/physician fresh air and Keep if you at rest feel in unwell. a position comfortable for breathing. P312 P314 If Get inhaled, medical Call advice/attention a POISON CENTER if you feel or doctor/physician unwell if you feel unwell. P314 P302 Get + P352 medical IF ON advice/attention SKIN: wash with if you plenty feel of unwell soap and water P302 P312 + Call P352 a POISON IF ON SKIN: CENTER wash or with doctor/physician plenty of soap if and you water feel unwell P312 P361+P364 Call a POISON Take off immediately CENTER or all doctor/physician contaminated clothing if you feel and unwell wash it before reuse P361+P364 P304 + P340 Take IF INHALED: off immediately Remove all contaminated victim to fresh clothing air and Keep and wash at rest it before in a position reuse comfortable for breathing. P304 P342 + + P340 P311 IF IF INHALED: experiencing Remove respiratory victim symptoms: to fresh air call and a Keep POISON at rest CENTER in a position or doctor/physician. comfortable for breathing. P342 P333 + + P311 P313 IF IF experiencing SKIN irritation respiratory or rash occurs: symptoms: Get medical call a POISON advice/attention. CENTER or doctor/physician. P333 P305 + + P313 P351 IF + P338 SKIN If irritation in eyes: or Rinse rash cautiously occurs: Get with medical water advice/attention. for several minutes. Remove contact lenses, if present and easy to do. Continue P305 rinsing. + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue P337 + P313 IF eye irritation persists: Get medical advice/attention. rinsing. P337

Storage

+ P313 IF eye irritation persists: Get medical advice/attention. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P233 Keep container tightly closed.

Disposal

P501 Dispose of contents/container to a waste disposal facility in accordance with local, state, federal or international laws

HMIS® ratings

HEALTH: 3 FLAMMIBILITY: 3 REACTIVITY: 1 PERSONAL PROTECTIVE EQUIPMENT: G

Potential health effects

EYES: CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, OR BLURRED VISION AS WELL AS CORNEAL OPACITY AND CONJUNTIVITIS SKIN: MAY CAUSE IRRITATION, DEFATTING AND DERMATITIS. INGESTION: CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITTING, DIARRHEA AND ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PHEUMONTITIS WHICH CAN BE FATAL. CAN CAUSE CORROSIVE ACTION TO MUCOUS MEMBRANES AND DIGESTIVE TRACT. INHALATION: CAN CAUSE NAUSEA AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, HEADACHE AND POSSIBLE UNCONSCIOUSNESS. BURNING SENSATION TO MUCOUS MEMBRANES, SHORTNESS OF BREATH AND FLU LIKE SYMPTOMS MAY OCCUR. HEALTH HAZARDS (ACUTE AND CHRONIC): OVER EXPOSURE TO THIS MATERIAL CAN CAUSE CARDIAC ABNORMALITIES, ANEMIA, LIVER ABNORMALITIES, KIDNEY DAMAGE OR EVEN EYE DAMAGE. CAN CAUSE ASTHMA OR OTHER RESPIRATORY DISORDERS, BRONCHITIS, EMPHYSEMA, HYPERACTIVITY, AND EXCEMA. Can cause sensitization by exposure through contact or high concentrations of vapor. Over-exposure to this material can cause cardiac abnormalities. Overexposure can possibly cause anemia. Liver abnormalities, kidney damage or eye damage. May cause asthma or other respiratory disorders, bronchitis, emphysema, hyperactivity and eczema. Chronic Inhalation: as a result of previous repeated overexposures or a single large dose, certain individuals will develop isocyanate sensitization (chemical asthma), which will cause them to react to a later xposure to isocyanate at levels well below the TLV or MGL. These symptoms, which include chest tightness, wheezing, cough, shortness of breath or asthma attack, could be immediate or delayed up to several hours after exposure. Similar to many nonspecific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air, or other irritants. This increased lung sensitivity can persist for weeks and in several years. Chronic overexposure to isocyanates has been reported to cause lung damage, including decrease in lung function, which may be permanent. Sensitization may either be temporary or permanent. Acute skin Contact: Isocyanates react with the skin protein and moisture and can cause irritation. Symptoms of skin irritation may be reddening, swelling, rash, scaling, or blistering. Some persons may develop skin sensitization from skin contact. Cured material is difficult to remove. Chronic Skin contact: Prolonged contact with the isocyanate can cause reddening, swelling, rash, scaling, or blistering. In those who have developed a skin sensitization, these symptoms can develop as a result of contact with very small amounts of liquid material or even as a result of vapor-only exposure.

Medical Conditions Generally Aggravated by Exposure

RESPIRATORY CONDITIONS OR OTHER ALLERGIC RESPONSE. CARCINOGENICITY