Epoxy Primer Kit - Part A

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

OSHA Hazards FLAMMIBILITY: 1 REACTIVITY: 0 PERSONAL PROTECIVE EQUIPMENT: G HEALTH: 2 FLAMMIBILITY: 1 REACTIVITY: 0 PERSONAL PROTECIVE EQUIPMENT: G

Potential health effects

EYES: THIS EYES: MATERIAL CAN CAUSE EYE IRRITATION OR REDNESS. HIGH VAPOR CONCENTRATIONS CAN CAUSE SEVERE IRRITATION TO THIS THE MATERIAL EYES. CAN CAUSE EYE IRRITATION OR REDNESS. HIGH VAPOR CONCENTRATIONS CAN CAUSE SEVERE IRRITATION SKIN: TO THE EYES. IRRITATION TO THE SKIN CAN OCCUR BUT DERMAL TOXICITY IS LOW. SKIN: INGESTION: IRRITATION TO THE SKIN CAN OCCUR BUT DERMAL TOXICITY IS LOW. INGESTION OF MATERIAL CAN CAUSE NAUSEA OR OTHER SIMILAR RESPONSES. INGESTION: INHALATION: INGESTION OF MATERIAL CAN CAUSE NAUSEA OR OTHER SIMILAR RESPONSES. HIGH CONCENTRATIONS OF VAPOR CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT, NAUSEA, AND DIZZINESS. INHALATION: HEALTH HAZARDS (ACUTE AND CHRONIC): HIGH CONCENTRATIONS OF VAPOR CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT, NAUSEA, AND DIZZINESS. PROLONGED OR REPEATED EXPOSURE MAY CAUSE ASTHMA AND SKIN EYES: MAY CAUSE IRRITATION BUT NO CORNEAL INJURY IS LIKELY. SKIN: MAY CAUSE IRRITATION OR ALLERGIC SKIN RESPONSE. INGESTION: THIS MATERIAL HAS A PROBABLE LOW ACUTE ORAL TOXICITY. INHALATION: NO GUIDE FOR CONTROL KNOWN, HOWEVER, EXPOSURE TO HEATED VAPORS CAN CAUSE IRRITATION TO THE NOSE, THROAT OR MUCOUS MEMBRANES. HEALTH HAZARDS (ACUTE AND CHRONIC): EPOXY RESINS CAN CAUSE SENSITIZATION BY EXPOSURE THROUGH CONTACT OR HIGH CONCENTRATIONS OF VAPOR. EYES: INJURY IS UNLIKELY BUT STAIN FOR EVIDENCE OF CORNEAL INJURY.

Health hazards

(ACUTE AND CHRONIC) SENSITIZATION OR OTHER ALLERGIC RESPONSES. PROLONGED OR REPEATED EXPOSURE MAY CAUSE ASTHMA AND SKIN

Medical Conditions Generally Aggravated by Exposure

SENSITIZATION OR OTHER ALLERGIC RESPONSES. RESPIRATORY CONDITIONS OR OTHER ALLERGIC AILMENTS CARCINOGENICITY RESPIRATORY CONDITIONS OR OTHER ALLERGIC AILMENTS RESPIRATORY INGREDIENTS OF THIS PRODUCT ARE REGULATED AS CARCINOGENS. CARCINOGENICITY

Storage

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: AVOID ALL SKIN CONTACT. AVOID BREATHING VAPORS. RESEAL PARTIALLY USED CONTAINERS. PROPERLY LABEL ALL CONTAINERS. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. OBSERVE CONDITIONS OF GOOD INDUSTRIAL HYGIENE AND SAFE WORKING PRACTICES. OTHER PRECAUTIONS: MIXED MATERIALS CONTAIN THE HAZARDS OF ALL THE COMPONENTS, THEREFORE, READ THE MSDS OF ALL COMPONENTS TO BECOME FAMILIAR WITH ALL HAZARDS PRIOR TO USING THIS PRODUCT. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ® Emergency Phone: Chem-Tel 800-255-3924 (24 hours) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: NIOSH APPROVED RESPIRATOR PROTECTION REQUIRED IN THE ABSENCE OF PROPER ENVIRONMENTAL CONTROLS. VENTILATION AVOID BREATHING VAPORS, VENTILATION MUST BE SUFFICIENT TO CONTROL VAPORS. PROTECTIVE GLOVES: IMPERVIOUS GLOVES, NEOPRENE OR RUBBER. EYE PROTECTION: SPLASH PROOF GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: CLEAN BODY COVERING CLOTHING AS WELL AS APRON FOOTWEAR OR OTHER EQUIPMENT SHOULD BE USED AS DEEMED NECESSARY TO AVOID CONTACT WITH THE MATERIAL. WORK HYGIENIC PRACTICES: OBSERVE GENERAL GOOD HYGIENIC PRACTICES. SEE SECTION THREE FOR OCCPATIONAL EXPOSURE LIMIT VALUES. 9. SECTION PHYSICAL 9: PHYSICAL AND AND CHEMICAL CHEMICAL PROPERTIES PROPERTIES

Appearance/Odor

LOW VISCOSITY LIQUID – amber clear BOILING POINT OR RANGE F: 212 0 VAPOR DENSITY (AIR = 1): N/A SPECIFIC GRAVITY (H2O = 1): 1.0 EVAPORATION RATE: N/A SOLUBILITY IN WATER: EMULSIFIABLE Odor Threshhold: N/A pH: N/A Melting point/freezing point: N/A Vapor Pressure: N/A Auto Ignition Temperature: N/A Partition Coefficient n-octanol/water N/A Decomposition Temperature: N/A 10. SECTION STABILITY 10: STABILITY AND AND REACTIVITY REACTIVITY STABILITY: STABLE CONDITIONS TO AVOID (STABILITY): AVOID CONTACT WITH OPEN FLAMES AND ALL SOURCES OF IGNITIONS AND SPARKS. INCOMPATIBILITY (MATERIAL TO AVOID): AVOID CONTACT WITH STRONG OXIDIZING AGENTS, MINERAL ACIDS AND EPOXY RESINS IN UNCONTROLLED AMOUNTS. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: CO, CO2, NOX HAZARDOUS POLYMERIZATION: WILL NOT OCCUR 11. SECTION TOXILOGICAL 11: TOXICOLOGICAL INFORMATION No data for the product itself. Component data: Component CAS# 57-55-6: Ingestion LD50 = 20000 mg/kg Component CAS# 107-98-2: Ingestion LD50 >5900 mg/kg Component CAS# 108-65-6: ingestion LD50 = 8532 Component CAS# 8052-41-3 Draize test (rabbit) eye 500 mg/24hr – Moderate. Epidemiology Studies involving petroleum refinery workers indicate that persons with routine exposure to petroleum based constituents may be at an increased risk to the development of benign neoplasms, digestive tract cancer and skin cancer. Component CAS# 111-40-0 inhalation LC50 (4hr) <0.3 mg/l (rat); Skin LD50 >5000 mg/kg( rabbit) Ingestion LD50 2960 mg/kg (rat) Severe Eye irritation, Moderate skin irritation, May cause sensitization by skin contact. Component Acetic Acid: Absorbed through the skin. Estimated 4 hr exposure Oral LD50 3310 mg/kg (rat), Estimated Dermal LD50 1060 mg/ kg (rabbit), Vapor LC50 5620 mouse).Chronic effects on humans – Mutagenetic for mammalian somatic cells. Mutagenic for bacteria and yeast. May cause damage to kidneys, mucous membranes, skin, teeth. Corrosive by inhalation or skin contact, corrosive to eyes. Component CAS# 107-98-2: Ingestion LD50 rat 4016 mg/kg, Dermal LD50 rabbit >2000 mg/kg, Inhalation LC50 6 hr Vapor, rat >25.8 mg/l. May cause eye or skin irritation. May effect Kidney or liver. Has been reported to be toxic to fetus in laboratory animals. Component CAS# 112-57-2 Toxicological Data on Ingredients Tetraethylenepentamine ORAL (LD50) Acute 3990 mg/kg [Rat]. DERMAL LD50) Acute 0.66 mg/kg [Rabbit]. Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive, sensitizer, permeator), of eye contact (corrosive), of inhalation (lung corrosive). LOW VISCOSITY LIQUID – amber clear BOILING POINT OR RANGE F: 212 0 VAPOR DENSITY (AIR = 1): N/A SPECIFIC GRAVITY (H2O = 1): 1.0 EVAPORATION RATE: N/A SOLUBILITY IN WATER: EMULSIFIABLE Odor Threshhold: N/A pH: N/A Melting point/freezing point: N/A Vapor Pressure: N/A Auto Ignition Temperature: N/A Partition Coefficient n-octanol/water N/A Decomposition Temperature: N/A SECTION 10: STABILITY AND REACTIVITY STABILITY: STABLE CONDITIONS TO AVOID (STABILITY): AVOID CONTACT WITH OPEN FLAMES AND ALL SOURCES OF IGNITIONS AND SPARKS. INCOMPATIBILITY (MATERIAL TO AVOID): AVOID CONTACT WITH STRONG OXIDIZING AGENTS, MINERAL ACIDS AND EPOXY RESINS IN UNCONTROLLED AMOUNTS. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: CO, CO2, NOX HAZARDOUS POLYMERIZATION: WILL NOT OCCUR

ECOLOGICAL INFORMATION

No data for the product itself. Component data: ® Emergency Phone: Chem-Tel 800-255-3924 (24 hours) RESPIRATORY PROTECTION: NIOSH APPROVED RESPIRATOR PROTECTION REQUIRED IN THE ABSENCE OF PROPER ENVIRONMENTAL CONTROLS. VENTILATION AVOID BREATHING VAPORS, VENTILATION MUST BE SUFFICIENT TO CONTROL VAPORS. PROTECTIVE GLOVES: IMPERVIOUS GLOVES, NEOPRENE OR RUBBER. EYE PROTECTION: SPLASH PROOF GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: CLEAN BODY COVERING CLOTHING AS WELL AS APRON FOOTWEAR OR OTHER EQUIPMENT SHOULD BE USED AS DEEMED NECESSARY TO AVOID CONTACT WITH THE MATERIAL. WORK HYGIENIC PRACTICES: OBSERVE GENERAL GOOD HYGIENIC PRACTICES. SEE SECTION THREE FOR OCCPATIONAL EXPOSURE LIMIT VALUES. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES No data for the product itself. Component data: Component Acetic Acid: Ecotoxicity in water( LC50) 423 mg/l 24 hours [Fish (goldfish)] , 88 ppm 96 hours [Fish (fathead minnow)}, 75ppm 96 hours [Fish (bluegill sunfish] >100 ppm 96 hours [Daphnia]. BOD-5: 0.34-0.88 g/oxygen/g Component CAS@ 107-98-2: Bioconcentration potential is low (BCF less than 100). Potential for mobility in soil is high (KOC between 0 and 50). Material is readily biodegradable and is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100mg/l in the most sensitive species tested.. LC50 fathead minnow 96 hr 20800 mg/l, LC50 water flea 48 hr lethally 23300 mg/l, EbC50 green algae biomass growth inhibition 7 d >1000 mg/l. Toxicity to microorganisms IC50 activated sludge > 1000 mg/l Component CAS# 112-57-2: The products of degradation are less toxic than the product itself. SECTION

TOXICOLOGICAL INFORMATION

No data for the product itself. Component data: Component CAS# 57-55-6: Ingestion LD50 = 20000 mg/kg Component CAS# 107-98-2: Ingestion LD50 >5900 mg/kg Component CAS# 108-65-6: ingestion LD50 = 8532 Component CAS# 8052-41-3 Draize test (rabbit) eye 500 mg/24hr – Moderate. Epidemiology Studies involving petroleum refinery workers indicate that persons with routine exposure to petroleum based constituents may be at an increased risk to the development of benign neoplasms, digestive tract cancer and skin cancer. Component CAS# 111-40-0 inhalation LC50 (4hr) <0.3 mg/l (rat); Skin LD50 >5000 mg/kg( rabbit) Ingestion LD50 2960 mg/kg (rat) Severe Eye irritation, Moderate skin irritation, May cause sensitization by skin contact. Component Acetic Acid: Absorbed through the skin. Estimated 4 hr exposure Oral LD50 3310 mg/kg (rat), Estimated Dermal LD50 1060 mg/ kg (rabbit), Vapor LC50 5620 mouse).Chronic effects on humans – Mutagenetic for mammalian somatic cells. Mutagenic for bacteria and yeast. May cause damage to kidneys, mucous membranes, skin, teeth. Corrosive by inhalation or skin contact, corrosive to eyes. Component CAS# 107-98-2: Ingestion LD50 rat 4016 mg/kg, Dermal LD50 rabbit >2000 mg/kg, Inhalation LC50 6 hr Vapor, rat >25.8 mg/l. May cause eye or skin irritation. May effect Kidney or liver. Has been reported to be toxic to fetus in laboratory animals. Component CAS# 112-57-2 Toxicological Data on Ingredients Tetraethylenepentamine ORAL (LD50) Acute 3990 mg/kg [Rat]. DERMAL LD50) Acute 0.66 mg/kg [Rabbit]. Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive, sensitizer, permeator), of eye contact (corrosive), of inhalation (lung corrosive).

Disposal

13: WASTE CONSIDERATIONS WASTE DISPOSAL METHOD: DISPOSE OF THE MATERIAL IN A WASTE DISPOSAL SITE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL LAWS. SECTION 14. TRANSPORT 14: Transport INFORMATION Information DOT: Not Regulated IMO/ IMDG: Not Regulated SECTION 15. REGULATORY 15: REGULATORY INFORMATION INFORMATION No data for the product itself. Component data: Component CAS# 57-55-6: Listed on TSCA and DSL Component CAS# 107-98-2: Listed on TSCA and DSL Component CAS# 108-65-6: Listed on TSCA and DSL Component CAS# 111-76-2: Section 313 toxic Chemical. Section 311 hazard category – Chronic fire, On TSCA list. May contain trace components of benzene, toluene, ethylbenzene and NJTSRN 800963-5170 and contains chemicals known to the state of California to cause cancer and birth defects. All components on the DSL Canada Component CAS# 8052-41-3: Component is on the TSCA and Canada DSL lists. Component is on the Pennsylvania, California, New Jersey Massachusetts and Minnesota right to know lists.

2.2 Label elements

Elements and Precautionary Statements Exclamation Mark, Aquatic Toxicity

Hazard statements

Warning: Causes serious eye irritation. Warning: Causes skin irritation Warning: May cause an allergic skin reaction Toxic to aquatic life with long lasting effects

Precautionary statements

P102 Keep out of reach of children. P103 Read label before use P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment.

Response

P302 + P352 IF ON SKIN: wash with plenty of soap and water. P333 + P313 IF SKIN irritation or rash occurs: Get medical advice/attention. P362 + P364 take off contaminated clothing and wash it before reuse. P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 IF eye irritation persists: Get medical advice/attention. P391 Collect spillage. P501 Dispose of contents/container to a waste disposal facility in accordance with local, state, federal or international laws

HMIS® ratings

HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTIVE EQUIPMENT: B

2.1 Classification of the substance or mixture

EYES: INJURY IS UNLIKELY BUT STAIN FOR EVIDENCE OF CORNEAL INJURY.