Fluorinated elastomer (FKM), components of hot-hardened elastomers

BOHLENDER GmbH

Revision date : 2016-12-07

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GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

25190-89-0

Name of the chemical

1-Propene, 1,1,2,3,3,3-hexafluoro-, polymer with 1,1-difluoroethene and 1,1,2,2-tetrafluoroethene

Concentration

0-99

EC/CAS

9011-17-0

Name of the chemical

1,1-Difluorethylene-hexafluorpropene polymer

Concentration

0-99

EC/CAS

469-080-6/921213-47-0

Name of the chemical

Phenol, 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis-, reaction products with benzene, chlorine and sulfur chloride (S2Cl2)

Concentration

0-5 080-6

EC/CAS

201-247-9/80-07-9

Name of the chemical

bis(4-chlorophenyl) sulphone

Concentration

0-5

EC/CAS

216-036-7/1478-61-1

Name of the chemical

4,4'-[2,2,2-trifluoro-1- (trifluoromethyl)ethylidene]diphenol, Bisphenol AF

Concentration

0-5

EC/CAS

215-710-8/1344-95-2

Name of the chemical

Silicic acid, calcium salt

Concentration

0-3

Listed in

EC/CAS

278-305-5/75768-65-9

Name of the chemical

Benzyltriphenylphosphonium, Salz mit 4,4’-[2,2,2-Trifluor-1-(trifluormethyl)ethyliden]bis[phenol] (1:1)

Concentration

0 - 2,5

EC/CAS

204-783-1/126-33-0

Name of the chemical

Tetrahydrothiophene 1,1-dioxide

Concentration

0-1

Listed in

General Information

Revision date

2016-12-07

Product name

Fluorinated elastomer (FKM), components of hot-hardened elastomers

1.2.2. Uses advised against

None

Icons in SDS

GHS07 GHS08

Company Information

company name

BOHLENDER GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

info@bohlender.de

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H317, H319, H360, H360D, H400, H410

Hazard statements

Code

Statements

H317

May cause an allergic skin reaction

Section 2

2.1 Classification of the substance or mixture

Regulation (EC) No. 1272/2008

Classifications

Serious eye damage/eye irritation, category 2 - Eye Irrit. 2; H319 Skin sensitisation, category 1A - Skin Sens. 1A; H317 Reproductive toxicity, category 1B - Repr. 1B; H360 Short-term (acute) aquatic hazard, category 1 - Aquatic Acute 1; H400 Long-term (chronic) aquatic hazard category 1 - Aquatic Chronic 1; H410 See section 16 for the full text of the H-Statements used in this safety data sheet.

2.2 Label elements

Regulation (EC) No. 1272/2008

Signal word

Danger, Attention Coding / Symbol(s): GHS07 (exclamation mark) GHS08 (health hazards)

Hazard pictograms

Product identifier (contains): Substance Name CAS-No. Concentration by weight Phenol, 4,4'-[2,2,2-trifluor-1-(trifluormethyl)ethylidene]bis-, Reaction 921213-47-0 0-5 % product with Benzene, chlorine and sulphur chloride (S2Cl2) PHENOL,4,4'-[2,2,2-TRIFLUOR-1-(TRIFLUORMETHYL) ETHYLIDENE 126049-00-1 0-3 % BIS-, ION(1-), TRIBUTYL (2-METHOXYPROPYL)PHOSPHONIUM Tetrahydrothiophene-1,1-dioxide 126-33-0 0-1 %

Hazard statements

H-Sentences) H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H360D May damage the unborn child.

Precautionary statements

P-Sentences)

Prevention

P201 Obtain special instructions before use. P280E Wear protective gloves.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P308 + P313 IF exposed or concerned: Get medical advice/attention.

Additional information

Supplemental safety advice: Fire-fighting measures: Product itself does not burn without external flame. Avoid contamination of tobacco products with the polymer. Please read the current safety data sheet prior to use. Heating fluoroelastomers to temperatures over 250 °C can cause vapours which are hazard if inhaled. These vapours can cause irritations in eyes, nose, throat and lung. 10 % of the compound consists of one or more components of unknown acute dermal toxicity.

Contains

2 % of components with unknown aquatic toxicity References regarding classifications / labelling: Regulation (EC) 1272/2008, Annex I, paragraph 1.3.4: Metals in massive form, alloys, mixtures containing polymers and mixtures containing elastomers do not require a label according to this Annex, if they do not present a hazard to human health by inhalation, ingestion or contact with skin or to the aquatic environment in the form in which they are placed on the market, although classified as hazardous in accordance with the criteria of this Annex.

2.3 Other hazards

Product can cause burns in hot condition. Fumes evolved during harding can be hazard if inhaled. These fumes can cause irritations of the eyes, throat and lung.

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