045432 POLYURETHANE FOAM FIRE RESISTANT

BLINKER ESPAÑA, S.A.U

Revision date : 2023-12-16

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 4
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

618-498-9/9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

40 - 80

General Information

Version

3.0

Revision date

2023-12-16

Product name

045432 POLYURETHANE FOAM FIRE RESISTANT

1.2.1 Relevant identified uses

Professional use

supplier name

BLINKER ESPAÑA, S.A.U

Emergency telephone

800 250 250

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 T013

Company Information

company name

BLINKER ESPAÑA, S.A.U

e-mail address of the competent person responsible for the Safety Data Sheet

msds@blinkergroup.com, blinkerfrance@blinkerfrance.com, blinker@blinker.pt

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H222, H229, H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H222

Extremely flammable aerosol

Section 2

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled

Hazard pictograms

GHS02 GHS07 GHS08

Signal word

Danger

Contains

4,4` diphenylmethanediisocyanate, isomere, homologe and mixtures

Hazard statements

H222 - Extremely flammable aerosol. H229 - Pressurised container: May burst if heated. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P101 - Si se necesita consejo médico, tener a mano el envase o la etiqueta. P102 - Keep out of reach of children. P210 - Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P211 - Do not spray on an open flame or other ignition source. P251 - Pressurized container: Do not pierce or burn, even after use. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P405 - Store locked up. P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Supplemental label elements

EUH204 - Contains isocyanates. May produce an allergic reaction.

Additional information

As of August 24, 2023, it is mandatory to have adequate training to proceed with industrial or professional use. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. Persons already sensitised to diisocyanates may develop allergic reactions when using this product.

Other hazards which do not result in classification

Substance / mixture does not contain PBT / vPvB substances. Flammable or explosive vapour/air mixtures may be formed. Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Aerosol, Category 1 H222;H229 Acute toxicity (inhal.), Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

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