Note: Ingredients listed on restricted chemical lists
EC/CAS
618-498-9/9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
40 - 80
General Information
Version
3.0
Revision date
2023-12-16
Product name
045432 POLYURETHANE FOAM FIRE RESISTANT
1.2.1 Relevant identified uses
Professional use
supplier name
BLINKER ESPAÑA, S.A.U
Emergency telephone
800 250 250
Icons in SDS
Company Information
company name
BLINKER ESPAÑA, S.A.U
e-mail address of the competent person responsible for the Safety Data Sheet
msds@blinkergroup.com, blinkerfrance@blinkerfrance.com, blinker@blinker.pt
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H222, H229, H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H222
Extremely flammable aerosol
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture
Adverse physicochemical, human health and environmental effects
Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled
Hazard pictograms
GHS02 GHS07 GHS08
Signal word
Danger
Contains
4,4` diphenylmethanediisocyanate, isomere, homologe and mixtures
Hazard statements
H222 - Extremely flammable aerosol. H229 - Pressurised container: May burst if heated. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P101 - Si se necesita consejo médico, tener a mano el envase o la etiqueta. P102 - Keep out of reach of children. P210 - Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P211 - Do not spray on an open flame or other ignition source. P251 - Pressurized container: Do not pierce or burn, even after use. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P405 - Store locked up. P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Supplemental label elements
EUH204 - Contains isocyanates. May produce an allergic reaction.
Additional information
As of August 24, 2023, it is mandatory to have adequate training to proceed with industrial or professional use. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. Persons already sensitised to diisocyanates may develop allergic reactions when using this product.
Other hazards which do not result in classification
Substance / mixture does not contain PBT / vPvB substances. Flammable or explosive vapour/air mixtures may be formed. Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Aerosol, Category 1 H222;H229 Acute toxicity (inhal.), Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.