Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
30-40
EC/CAS
5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
20-30
EC/CAS
7631-86-9
Name of the chemical
Silver adsorbed on silicon dioxide
Concentration
0.5-1.5
EC/CAS
1344-28-1
Name of the chemical
aluminium oxide
Concentration
0.5-1.5
General Information
Revision date
2014-01-16
Product name
SP-200 PART A
1.2.1 Relevant identified uses
Polyurethane resin
Manufacturer Name
BJB Enterprises, Inc
Emergency telephone
(800) 424-9300, (703) 527-3887
Icons in SDS
Company Information
company name
BJB Enterprises, Inc
GHS Information
Signal word
DANGER
Section 2
SECTION 2: Hazards identification
GHS Classification GHS CLASSIFICATIONS Health Acute Toxicity (Inhalation), Category 4 Skin Irritation, Category 2 Eye Irritation, Category 2A Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Carcinogenicity, Category 2 Target Organ Toxicity (Single exposure), Category 3 Target Organ Toxicity (Repeated exposure), Category 2
Signal word
DANGER
Hazard statements
H332: Harmful if inhaled. H315: Causes skin irritation. H319: Causes serious eye irritation. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317: May cause an allergic skin reaction. H351: Suspected of causing cancer . H335: May cause respiratory irritation. H373: May cause damage to organs through prolonged or repeated exposure .
Prevention
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P285: In case of inadequate ventilation wear respiratory protection. P264: Wash … thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response
P304+P341 IF INHALED If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician P302+P352 IF ON SKIN Wash with plenty of soap and water P321: Specific treatment (see … on this label). P333+P313 If skin irritation or rash occurs Get medical advice/attention P362: Take off contaminated clothing and wash before reuse. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P308+P313 IF exposed or concerned Get medical advice/attention
Storage
P403+P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up.
Disposal
P501: Dispose of contents/container in accordance with local/regional/national/international regulations. EMERGENCY OVERVIEW
Appearance/Odor
Pale yellow liquid with a slight musty odor IMMEDIATE CONCERNS: Harmful by inhalation. Use in well ventilated areas. Irritating to eyes, skin, and respiratory system. May cause sensitization by inhalation and skin contact. This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even minimal concentrations of diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for several hours after exposure. Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures. Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling.
Potential health effects
EYES: Causes serious eye irritation. SKIN: Causes skin irritation. May cause an allergic skin reaction. INGESTION: May be harmful if swallowed. INHALATION: Harmful if inhaled. Inhalation at levels above the occupational exposure limit could cause respiratory sensitization and risk of serious damage to the respiratory system.
Medical Conditions Generally Aggravated by Exposure
Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure
Principle Routes of Exposure
Eye and skin contact, inhalation of vapors, or accidental ingestion TARGET ORGANS Contains material which causes damage to the following organs upper respiratory tract SENSITIZATION: May cause allergic skin and respiratory reaction.
2.1 Classification of the substance or mixture
Health: Acute Toxicity (Inhalation), Category 4 Skin Irritation, Category 2 Eye Irritation, Category 2A Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Carcinogenicity, Category 2 Target Organ Toxicity (Single exposure), Category 3 Target Organ Toxicity (Repeated exposure), Category 2