Conforms to

Hazard statements (CLP)

H315, H319, H411

Code

Statements

H315

Causes skin irritation

Signal word

Warning

Hazard statements

H315 - Causes skin irritation. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects.

Precautionary statements

P273 -Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. . P302+P352+P332+P313 - IF ON SKIN Wash with plenty of soap and water. If skin irritation.occurs Get medical advice/attention P305+P351+P338+P337+P313 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenss. if present and easy to do. Continy rinsing. · '· If eye irritation persists: Get medical advice/attention. · · · · P362+P364 - Take off contaminated clothing and wash it before reuse. P391 - Collect spillage.

Additional information

No information available. 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to Avoid Conditions to Avoid: Excessive heat, flame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. 11.1. Information on toxicological effects Acute toxicity Based on the data available, the criteria for classification are not met. Experimental/calculated data: LDS0(acute/oral): > 2000 mg/kg. (Rat). (OECD 423). LDS0 (acute/dermal):> 5000 mg/kg. (Rabbit). Skin corrosion/irritation Causes skin irritation. Experimental/calculated data: · Skin irritation: Irritant. (Rabbit). Serious eye damage/irritation Causes serious eye irritation. Experimental/calculated data: · Eye irritation: Irritant. (Rabbit) . {OECD 405). Respiratory or skin sensitisation Based on the data available, the criteria for classification are not met. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 12.1. Toxicity Assessment: Toxic to aquatic life with long lasting effects. Experimental/calculated data: Toxicity for fish LCS0 (96h) 2,3 mg/L. {Brachydanio rerio). (OECD 203) Toxicity for aquatic invertebrates: ECS0 (48h) 3,7 mg/L . (Daphnia magna).- {OECD 202). Toxicity for algae: ErCS0 (72h) > 9,42 mg/L. (Scenedesmus subspicatus). {OECD 201). Toxicity for bacteria/effect on activated sludge EC20 (0.Sh) > 1000 rng/l. (OECD 209) 12.2. Persistence and degradability Biodegradation 76 %. (OECD 301 F). The product is readily biodegradable 12.3. Bioaccumulative potential log Kow: 4,5 - 5. 12.4. Soil mobility No information available. 12.5. Results of PBT and vPvB assessment Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907/2006, Annex XIII. . 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel 01425 655555 Email technical@madarcorporation.co.uk 12.6. Endocrine disrupting properties Product not containing any component identified as having endocrine disrupting properties for the environment according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605. 12.7. Other adverse efects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number UN3082 14.2. UN Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (GAMMA- SUBSTANCE, LIQUID, N.O.S. (GAMMA- SUBSTANCE, LIQUID, N.O.S. (GAMMA- METHYLIONONE) 14.3. Transport Hazard Class(es) 9 14.4. Packing Group Ill 14.5. Environmental hazards Yes Additional information 14.6 Special precautions for user None known 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture No information available 15.2. Chemical safety assessment A chemical safety assessment has been carried out for the subsance or mixture by the supplier Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H315 - Causes skin irritation. H320 - Causes eye irritation. H411 - Toxic to aquatic life with long lasting effects. The information included in this safety data sheet is based on the available data at the moment this document is issued. It is meant to be a description of safety '" requirements for our product and does not stand for a guarantee of its properties. The user is responsible for taking all necessary steps leading to compliance i with local rules and legislation. 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK SPECIFICATION SHEET PRINT DATE 26/01/26 PRODUCT METHYLIONONE GAMMA BASF APPLICATIONS Raw material for industrial use intended for the manufacture of flavours and/or fragrances. IUPAC NAME 3-BUTEN-2-ON E, 3-METHYL-4-(2,6,6-TRIMETHYL-2-CYCLOH EXEN-1-YL) SYNONYMS ISO-ALPHA-METHYL IONONE FORMULA C14 H22 0 MOLECULAR WEIGHT 206,00 CAS 1335-46-2 CAS 2 127-51-5 EINECS 215-635-0 EINECS 2 204-846-3 FEMA 2714 TARIFF NUMBER 2914230000 KOSHER CERTIFICATE AVAILABLE ON REQUEST REACH REGISTRATION NO. 01-2119471851-35 SPECIFICATIONS ASPECT AT 20° C CLEAR MOBILE LIQUID COLOUR PALE YELLOW- YELLOW ODOUR WOODY, VIOLET, FLORAL TASTE DENSITY A 20° C (g / ml) 0,926 - 0,936 DENSITY 25/25 0,926 - 0,931 REFRACTIVE INDEX nD20 1,4980 - 1,5020 REFRACTIVE INDEX nD25 OPTICAL ROTATION (0) BOILING POINT (°C) MELTING POINT (°C) FLASH POINT (°C) 126,00 ASSAY(% GC) ISOMERS SUM > 94%. IONONE ISO-METHYL ALPHA: 60-70% ACID VALUE (mg KOH/g) SOLUBILITY INSOLUBLE IN WATER VAPOUR PRESSURE NOT DETERMINED OTHER SOLUBILITIES SOLUBLE IN ETHANOL OTHER TECHNICAL DATA N-ALPHA ISOMER 20-30%, ISO-BETA ISOMER <6% Y N-BETA ISOMER <19% STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 24 MONTHS, QUALITY SHOULD BE CHECKED,BEFORE USE. IT CONTAINS ALPHA-TOCOPHEROL 500 ppm AS ANTIOXIDANT .. WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DO NOT PRESENT IT AS ALL INCLUSIVE AND AS SUCH SHOULD BE USED AS A GUIDE. IT IS THE SOLE RESPONSIBILITY OF THE RECEIVER OF OUR PRODUCT TO,COMPLY WITH EXISTING REGULATIONS AND INSTRUCTIONS, ' ·! -:> THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNOLOGICAL REASONS, WE RECOMMEND NOT TO, USE IT UNLESS FILTERED WHEN USED AS A RAW MATERIAL IN FOOD INTENDED FOR FINAL CONSUMERS, 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK

2.1 Classification of the substance or mixture

Skin Irritant - Category 2 - H315 Eye Irritant - Category 2 - H319 Hazardous to the aquatic environment, long-term (chronic) - Category 2 - H411 2.2. Label Elements Signal Word: Warning Hazard statements: H315 - Causes skin irritation. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects. Precautionary statements: P273 -Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. . P302+P352+P332+P313 - IF ON SKIN: Wash with plenty of soap and water. If skin irritation.occurs: Get medical advice/attention. P305+P351+P338+P337+P313 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenss. if present and easy to do. Continy rinsing. · '· If eye irritation persists: Get medical advice/attention. · · · · P362+P364 - Take off contaminated clothing and wash it before reuse. P391 - Collect spillage. 2.3. Other hazards Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907/2006, Annex XIII. Product not containing any component identified as having endocrine disrupting properties for the environment according to Regulation (EU) 2017/2100 or Regulation (EU) 3.1. Substances Chemical name: CAS GAMMA-METHYLIONONE number: 1335-46-2 EC number: 215-635-0 Hazardous constituents: CASNo Chemical Name %(w/w) EC No Classification according to Regulation 1272/2008 1335-46-2 Skin lrrit. 2 - H315 METHYL-IONONE 2':50 Eye lrrit. 2 - H319 215-635-0 Aquatic Chronic 2 - H411 See the full text of the hazard statements in section 16. 3.2. Mixtures Not applicable. 4.1. Description of necessary first aid measures Ingestion: Rinse mouth with water. Obtain medical advice. Keep at rest. Do not induce vomiting. Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice. Inhalation: Remove person to fresh air and keep at rest. Seek immediate medical advice. Skin contact: Take off immediately all contaminated clothing. Thoroughly wash affected skin with soap and water. Seek medical attention if symptoms persist. 4.2. Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed No information available. 5.1. Extinguishing Media Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. 5.2. Special hazards arising from the substance or mixture Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions. 5.3. Advice for firefighters High temperatures can lead to high pressures inside closed containers. Avoid inhalation of vapors that are created. Use appropriate respiratory protection. Do not allow spillage of fire to be poured into drains or watercourses. Wear self-contained breathing apparatus and protective clothing. 6.1. Personal precautions, protective equipment and emergency procedures Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprotected personnel from entering. Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8. 6.2. Environmental precautions To avoid possible contamination of the environment, do not discharge into a_ny drains, suriace waters or groundwaters. ' ;;I 6.3. Methods and materials for containment and cleaning up Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry.lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. 6.4. Reference to other sections Information regarding exposure controls, personal protection and disposal considerations can be.found in sections 8 and 13. 7.1. Precautions for safe handling Do not store or handle this material near food or drinking water. Do not smoke. Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses. Observe the rules of safety and hygiene at work. Keep in the original container or an alternative made from a compatible material. 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light. Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges). Keep away from incompatible materials (see section 10). 7.3. Specific end use(s) No information available. 8.1. Control parameters Components with occupational exposure limits: None known. 8.2. Exposure controls Appropriate engineering controls: Measures should be taken to prevent materials from being splashed into the body. Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required. Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse. Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved. Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment. Environmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environmental protection legislation. In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9.1. Information on basic physical and chemical properties Appearance: Liquid Colour: Conforms to standard Odour: Conforms to standard Odour theshold: Not determined pH: Not determined Melting point/freezing point: Not determined Boling point/boiling range: Not determined Flash point: 126 °( Evaporation rate: Not determined Flammability: Not determined Lower flammability/Explosive limit: Not determined Upper flammability/Explosive limit: Not determined Vapour pressure: Not determined Vapour Density: Not determined Density: 0,926-0,936 g/mL (20°() Relative density: 0,926-0,936 (20°9 Water solubility: INSOLUBLE IN WATER Solubility in other solvents: SOLUBLE IN ETHANOL Partition coefficient n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity, dynamic: Not determined Viscosity, kinematic: Not determined Explosive properties: Not determined Oxidising properties: NONE EXPECTED 9.2. Additional information No information available. 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. 10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated. 10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. 10.4. Conditions to Avoid Conditions to Avoid: Excessive heat, flame or other ignition sources. 10.5. Incompatible materials Avoid contact with strong acids and bases and oxidizing agents. 10.6. Hazardous decomposition products During combustion may form carbon monoxide and unidentified organic compounds. 11.1. Information on toxicological effects Acute toxicity Based on the data available, the criteria for classification are not met. Experimental/calculated data: LDS0(acute/oral): > 2000 mg/kg. (Rat). (OECD 423). LDS0 (acute/dermal):> 5000 mg/kg. (Rabbit). Skin corrosion/irritation Causes skin irritation. Experimental/calculated data: · Skin irritation: Irritant. (Rabbit). Serious eye damage/irritation Causes serious eye irritation. Experimental/calculated data: · Eye irritation: Irritant. (Rabbit) . {OECD 405). Respiratory or skin sensitisation Based on the data available, the criteria for classification are not met. Germ cell mutagenicity Based on the data available, the criteria for classification are not met. Carcinogenicity Based on the data available, the criteria for classification are not met. Reproductive toxicity Based on the data available, the criteria for classification are not met. STOT-single exposure Based on the data available, the criteria for classification are not met. STOT-repeated exposure Based on the data available, the criteria for classification are not met. Aspiration hazard Based on the data available, the criteria for classification are not met. 12.1. Toxicity Assessment: Toxic to aquatic life with long lasting effects. Experimental/calculated data: Toxicity for fish: LCS0 (96h): 2,3 mg/L. {Brachydanio rerio). (OECD 203). Toxicity for aquatic invertebrates: ECS0 (48h) : 3,7 mg/L . (Daphnia magna).- {OECD 202). Toxicity for algae: ErCS0 (72h) : > 9,42 mg/L. (Scenedesmus subspicatus). {OECD 201). Toxicity for bacteria/effect on activated sludge: EC20 (0.Sh): > 1000 rng/l. (OECD 209). 12.2. Persistence and degradability Biodegradation : 76 %. (OECD 301 F). The product is readily biodegradable 12.3. Bioaccumulative potential log Kow: 4,5 - 5. 12.4. Soil mobility No information available. 12.5. Results of PBT and vPvB assessment Product not containing any component that meets the criteria for PBT or vPvB according to Regulation (EC) 1907/2006, Annex XIII. . 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK Tel: 01425 655555 Email: technical@madarcorporation.co.uk 12.6. Endocrine disrupting properties Product not containing any component identified as having endocrine disrupting properties for the environment according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605. 12.7. Other adverse efects See also sections 6, 7, 13 and 15 Do not allow to get into waste water or waterways. 13.1. Waste treatment methods Dispose of in accordance with national and local environmental regulations. ADR/RID/ADN IMDG IATA-ICAO 14.1. UN Number UN3082 14.2. UN Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (GAMMA- SUBSTANCE, LIQUID, N.O.S. (GAMMA- SUBSTANCE, LIQUID, N.O.S. (GAMMA- METHYLIONONE) 14.3. Transport Hazard Class(es) 9 14.4. Packing Group Ill 14.5. Environmental hazards Yes Additional information 14.6 Special precautions for user None known 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture No information available 15.2. Chemical safety assessment A chemical safety assessment has been carried out for the subsance or mixture by the supplier Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3: H315 - Causes skin irritation. H320 - Causes eye irritation. H411 - Toxic to aquatic life with long lasting effects. The information included in this safety data sheet is based on the available data at the moment this document is issued. It is meant to be a description of safety '" requirements for our product and does not stand for a guarantee of its properties. The user is responsible for taking all necessary steps leading to compliance i with local rules and legislation. 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK SPECIFICATION SHEET PRINT DATE 26/01/26 PRODUCT METHYLIONONE GAMMA BASF APPLICATIONS Raw material for industrial use intended for the manufacture of flavours and/or fragrances. IUPAC NAME 3-BUTEN-2-ON E, 3-METHYL-4-(2,6,6-TRIMETHYL-2-CYCLOH EXEN-1-YL) SYNONYMS ISO-ALPHA-METHYL IONONE FORMULA C14 H22 0 MOLECULAR WEIGHT 206,00 CAS 1335-46-2 CAS 2 127-51-5 EINECS 215-635-0 EINECS 2 204-846-3 FEMA 2714 TARIFF NUMBER 2914230000 KOSHER CERTIFICATE AVAILABLE ON REQUEST REACH REGISTRATION NO. 01-2119471851-35 SPECIFICATIONS ASPECT AT 20° C CLEAR MOBILE LIQUID COLOUR PALE YELLOW- YELLOW ODOUR WOODY, VIOLET, FLORAL TASTE DENSITY A 20° C (g / ml) 0,926 - 0,936 DENSITY 25/25 0,926 - 0,931 REFRACTIVE INDEX nD20 1,4980 - 1,5020 REFRACTIVE INDEX nD25 OPTICAL ROTATION (0) BOILING POINT (°C) MELTING POINT (°C) FLASH POINT (°C) 126,00 ASSAY(% GC) ISOMERS SUM > 94%. IONONE ISO-METHYL ALPHA: 60-70% ACID VALUE (mg KOH/g) SOLUBILITY INSOLUBLE IN WATER VAPOUR PRESSURE NOT DETERMINED OTHER SOLUBILITIES SOLUBLE IN ETHANOL OTHER TECHNICAL DATA N-ALPHA ISOMER 20-30%, ISO-BETA ISOMER <6% Y N-BETA ISOMER <19% STABILITY AND STORAGE KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AND DRY PLACE, PROTECTED FROM LIGHT. WHEN STORED FOR MORE THAN 24 MONTHS, QUALITY SHOULD BE CHECKED,BEFORE USE. IT CONTAINS ALPHA-TOCOPHEROL 500 ppm AS ANTIOXIDANT .. WE BELIEVE THE ABOVE INFORMATION TO BE CORRECT BUT WE DO NOT PRESENT IT AS ALL INCLUSIVE AND AS SUCH SHOULD BE USED AS A GUIDE. IT IS THE SOLE RESPONSIBILITY OF THE RECEIVER OF OUR PRODUCT TO,COMPLY WITH EXISTING REGULATIONS AND INSTRUCTIONS, ' ·! -:> THIS PRODUCT HAS NOT BEEN FILTERED DUE TO TECHNOLOGICAL REASONS, WE RECOMMEND NOT TO, USE IT UNLESS FILTERED WHEN USED AS A RAW MATERIAL IN FOOD INTENDED FOR FINAL CONSUMERS, 19-20 Sandleheath Industrial Estate, Fordingbridge, Hampshire, SP6 1PA, UK