ACETONITRILE for HPLC

Hazard statements (CLP)

H225, H302, H312, H319, H332

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

DSD Regulation EC 1272/2008 (CLP)]

2.1 Classification of the substance or mixture

EC 67/548 or EC 1999/45

Classifications

F; R11 Xn; R20/21/22 Xi; R36

Hazard categories

Code(s), Regulation (EC) No 1272/2008 (CLP)

Health hazards

Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) H332 Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312 Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319 Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302

Physical hazards

Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) H225 -DSD (continued)

2.2 Label elements

EC 67/548 or EC 1999/45 Regulation EC 1272/2008 (CLP)

Hazard pictograms

F : Highly flammable Xn : Harmful

R-phrase(s)

R11 : Highly flammable. R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed. R36 : Irritating to eyes.

S-phrase(s)

S1/2 : Keep locked up and out of reach of children. S16 : Keep away from sources of ignition - No smoking. S36/37 : Wear suitable protective clothing and gloves.

Contains

Acetonitrile : Acetonitrile

Signal word

Danger

Hazard statements

H225 : Highly flammable liquid and vapour. H302 : Harmful if swallowed. H312 : Harmful in contact with skin. H319 : Causes serious eye irritation. H332 : Harmful if inhaled.

Precautionary statements

General : P102: Keep out of reach of children. P103: Read label before use. P101: If medical advice is needed, have product container or label at hand.

Prevention

P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating, lighting, …, equipment. P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking. P280: Wear protective gloves, protective clothing, eye protection, face protection. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust, fume, gas, mist, vapours, spray. P233: Keep container tightly closed. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product. -DSD (continued)

Response

P302+P352 IF ON SKIN Wash with plenty of soap and water P301+P312 IF SWALLOWED Call a POISON CENTER or doctor if you feel unwell. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED Remove to fresh air and keep at rest in a position comfortable for breathing. P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P337+P313 If eye irritation persists Get medical advice/attention P370+P378 In case of fire Use for extinction

Storage

P403+P235: Store in well-ventilated place. Keep cool. • Disposal considerations : P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards

The substance does not fulfil the criteria to be identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.