Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012

Hazard statements (CLP)

H315, H318, H335

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. breathing, administer artificial respiration. Take suitable precautions for rescue workers. Information not available. H318 Causes serious eye damage. 10.2. Chemical stability. H315 Causes skin irritation.

2.1 Classification of the substance or mixture

4.2. Most important symptoms and effects, both acute and delayed. SECTION 14. Transport information. The product is stable in normal conditions of use and storage. H335 May cause respiratory irritation. 8.2. Exposure controls.

UN Number

For symptoms and effects caused by the contained substances, see chap. 11. 10.3. Possibility of hazardous reactions. The product is classified as hazardous pursuant to the provisions set forth in EC Regulation

2.2 Label elements

10.5. Incompatible materials. - DNEL: Derived No Effect Level The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. the duration and type of use. Information not available. Not applicable. - EmS: Emergency Schedule UNSUITABLE EXTINGUISHING EQUIPMENT SKIN PROTECTION Hazard labelling pursuant to EC Regulation

Hazard pictograms

ALUMINIUM SULFATE: sulphur oxides, alumnium oxides. - IC50: Immobilization Concentration 50% 5.2. Special hazards arising from the substance or mixture. EYE PROTECTION - IMDG: International Maritime Code for dangerous goods HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Wear a hood visor or protective visor combined with airtight goggles (see standard EN 166). Not applicable. - IMO: International Maritime Organization Do not breathe combustion products. RESPIRATORY PROTECTION

TOXICOLOGICAL INFORMATION

INDEX NUMBER: Identifier in Annex VI of CLP

Environmental hazards

If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type 5.3. Advice for firefighters. 11.1. Information on toxicological effects. - LC50: Lethal Concentration 50% B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases - LD50: Lethal dose 50% GENERAL INFORMATION or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it Not applicable. - OEL: Occupational Exposure Level Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the contains, using the criteria specified in the applicable regulation for classification. 14.6. Special precautions for user.

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated threshold values considered. The protection provided by masks is in any case limited. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the

Signal word

PEC: Predicted environmental Concentration Danger water used for extinction and the remains of the fire according to applicable regulations. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an toxicological effects of exposure to the product. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing Not applicable. - PEL: Predicted exposure level

Hazard statements

Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. This product may cause serious ocular lesions, cornea opacity, iris lesions, irreversible eye coloration. - PNEC: Predicted no effect concentration H318 Causes serious eye damage. 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. - REACH EC Regulation

Precautionary statements

TLV: Threshold Limit Value compliance with environmental standards. ALUMINIUM SULFATE Information not relevant. Wear eye protection / face protection. P280 SECTION 6. Accidental release measures. - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. LD50 (Oral). P305+P351+P338 Wear eye protection / face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. 1930 mg/kg Rat - TWA STEL: Short-term exposure limit 6.1. Personal precautions, protective equipment and emergency procedures. Continue rinsing. SECTION 9. Physical and chemical properties. SECTION 15. Regulatory information. - TWA: Time-weighted average exposure limit Immediately call a POISON CENTER / doctor / . . . Block the leakage if there is no hazard. P310

ECOLOGICAL INFORMATION

VOC: Volatile organic Compounds 9.1. Information on basic physical and chemical properties. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation

Contains

ALUMINIUM SULFATE 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Appearance Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or - WGK: Water hazard classes (German). liquid procedures. Colour contaminate soil or vegetation. red

2.3 Other hazards

Seveso category. Odour None. odourless Odour threshold. Not available. EPY 9.1.6 - SDS 1003 On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.