PUR

big

Revision date : 2024-02-17

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GHS02 GHS08 GHS07
Health risk rating 5
Safety risk rating 4
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

25% <50%

EC/CAS

200-857-2/75-28-5

Name of the chemical

iso-Butan, enthält  0,1% Butadien

Concentration

5%≤C<10

General Information

Version

0200

Revision date

2024-02-17

Product name

PUR

1.2.1 Relevant identified uses

polyurethane

1.2.2. Uses advised against

known

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 M011 M014 M017

Company Information

company name

big

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H222, H229, H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H222

Extremely flammable aerosol

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Contains

polymethylene polyphenyl isocyanate, conc monomer ≥0.1%

Signal word

Danger

Hazard statements

H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. H351 Suspected of causing cancer. Created by Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG) Publication date 2016-12-14 878-16433-054-en Technische Schoolstraat 43 A B-2440 Geel Date of revision 2024-02-17 http://www.big.be © BIG vzw Reason for revision 3; 8; 11; 12; 13; 15 PUR H334 May cause allergy or asthma symptoms or breathing difficul�es if inhaled. H317 May cause an allergic skin reac�on. H332 Harmful if inhaled. H373 May cause damage to organs through prolonged or repeated exposure if inhaled. H315 Causes skin irrita�on. H319 Causes serious eye irrita�on. H335 May cause respiratory irrita�on.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other igni�on sources. No smoking. P211 Do not spray on an open flame or other igni�on source. P251 Do not pierce or burn, even a�er use. P308 + P313 IF exposed or concerned: Get medical advice/a�en�on. P405 Store locked up. P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122°F. P501 Dispose of contents/container in accordance with local/regional/na�onal/interna�onal regula�on.

Additional information

- Persons already sensitised to diisocyanates may develop allergic reactions when using this product. - Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. - This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. As from 24 August 2023 adequate training is required before industrial or professional use.

2.3 Other hazards

Gas/vapour spreads at floor level: ignition hazard Caution! Substance is absorbed through the skin

2.1 Classification of the substance or mixture

Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008 Class Category Hazard statements Aerosol category 1 H222: Extremely flammable aerosol. Aerosol category 1 H229: Pressurised container: May burst if heated. Carc. category 2 H351: Suspected of causing cancer. Resp. Sens. category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Sens. category 1 H317: May cause an allergic skin reaction. Acute Tox. category 4 H332: Harmful if inhaled. STOT RE category 2 H373: May cause damage to organs through prolonged or repeated exposure if inhaled. Skin Irrit. category 2 H315: Causes skin irritation. Eye Irrit. category 2 H319: Causes serious eye irritation. STOT SE category 3 H335: May cause respiratory irritation.

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