H314

Hazard statements (CLP)

H301, H302, H311, H314, H315, H317, H318, H330, H400, H410, H411, H412

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. CONTAMINATED PACKAGING Healthcare controls LD50 (Oral) Aquatic Chronic 1 H410 M=1 > 500 mg/kg - CLP EC Regulation

2.1 Classification of the substance or mixture

8.2. Exposure controls INDEX EC50 - for Crustacea LC50 (Inhalation) 0,0082 mg/l/48h > 0,78 mg/l/4h Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent - EmS: Emergency Schedule 10.1. Reactivity EC50 - for Algae / Aquatic Plants VOC (Directive 2004/42/EC) : any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency 0,00046 mg/l/72h SECTION 14. Transport information The product is classified as hazardous pursuant to the provisions set forth in (EC) Regulation

UN Number

PHOSPHORIC ACID HAND PROTECTION LC50 - for Fish The product must not penetrate into the sewer system or come into contact with surface water or ground water. Decomposes at temperatures above 200°C/392°F. 1,6 mg/l/96h - INDEX NUMBER: Identifier in Annex VI of CLP CAS Protect hands with category III work gloves (see standard EN 374). EC50 - for Crustacea German regulation on the classification of substances hazardous to water (AwSV, vom 18. April 2017) Hazardous to the aquatic environment, chronic 7664-38-2 0,005 Skin Corr. 1B H314, Eye Dam. 1 H318, 4,8 mg/l/48h H412 Harmful to aquatic life with long lasting effects. 10.2. Chemical stability - LC50: Lethal Concentration 50% The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. EC50 - for Algae / Aquatic Plants WGK 3: Severe hazard to waters toxicity, category 3 LD50 (Oral) Classification note/notes according to Annex VI to the CLP Regulation: B 0,11 mg/l/72h 457 mg/kg bw 6.3. Methods and material for containment and cleaning up Not applicable - LD50: Lethal dose 50% EC The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on The product is stable in normal conditions of use and storage. LD50 (Dermal) 231-633-2 660 mg/kg bw

2.2 Label elements

15.2. Chemical safety assessment - OEL: Occupational Exposure Level INDEX the duration and type of use. LC50 (Inhalation) 015-011-00-6 1,23 mg/l/4h Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation SKIN PROTECTION LC50 - for Fish 1,6 mg/l/96h 10.3. Possibility of hazardous reactions 14.2. UN proper shipping name remainder with inert absorbent material. - PEC: Predicted environmental Concentration Hazard labelling pursuant to EC Regulation

Hazard pictograms

PNEC: Predicted no effect concentration EYE PROTECTION LD50 (Dermal) -- Aquatic Chronic 1 H410 M=100 2740 mg/kg Rabbit 6.4. Reference to other sections

Further information

REACH EC Regulation

Signal word

RID: Regulation concerning the international transport of dangerous goods by train INDEX RESPIRATORY PROTECTION LC50 - for Fish -- 14,7 mg/l/96h 14.3. Transport hazard class(es) Any information on personal protection and disposal is given in sections 8 and 13. Text of hazard (H) indications mentioned in section 2-3 of the sheet: - TLV: Threshold Limit Value Risk of explosion on contact with nitromethane.May react dangerously with alkalis,sodium borohydride 10.4. Conditions to avoid If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type EC50 - for Crustacea TITANIUM DIOXIDE 1,4 mg/l/48h - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.

Hazard statements

The full wording of hazard (H) phrases is given in section 16 of the sheet. B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases EC50 - for Algae / Aquatic Plants Not applicable Carc. 2 LD50 (Oral) Carcinogenicity, category 2 0,022 mg/l/72h > 10000 mg/kg Rat SECTION 7. Handling and storage - TWA STEL: Short-term exposure limit or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Chronic NOEC for Algae / Aquatic Plants H412 Harmful to aquatic life with long lasting effects. 0,0032 mg/l None in particular. However the usual precautions used for chemical products should be respected. - TWA: Time-weighted average exposure limit Acute Tox. 2 Acute toxicity, category 2 Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the SKIN CORROSION / IRRITATION EUH208

Contains

7.1. Precautions for safe handling