1AA-CA09

Berryman Products, Inc

Revision date : 2016-02-01

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GHS09 GHS08 GHS01 GHS05 GHS07
Health risk rating 5
Safety risk rating 5
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

67-64-1

Name of the chemical

acetone

Concentration

80-92%

EC/CAS

111-76-2

Name of the chemical

Ethylene glycol monobutyl ether (EGBE)

Concentration

2-5%

EC/CAS

67-63-0

Name of the chemical

Propan-2-ol

Concentration

1-2%

EC/CAS

1330-20-7

Name of the chemical

Xylene

Concentration

1-2%

Listed in

General Information

Revision date

2016-02-01

Product name

1AA-CA09

Emergency telephone

(800) 535-5053

Icons in SDS

GHS01 GHS05 GHS07 GHS08 GHS09

Company Information

company name

Berryman Products, Inc

GHS Information

Signal word

Danger

Section 2

Aspiration hazard

Vomiting can cause serious inflammation and accumulation of fluids in the lungs. (Pheumonitis and pulmonary edema) Aspiration into the lungs can produce severe lung damage and isa medical emergency. Target Organs - Kidneys, Liver, Eyes, Hearing, Lungs, Brain, Skin, Central and Peripheral Nervous System, Gastrointestinal and Cardiovascular Systems. CARCINOGENIC — Product may contain trace amountsof following. CHEM ICAL CAS# NTP ACGIH IARC PERCENT Ethylbenzene 100-41-4 Yes (A3) Proven for animal (2B) Possible for human <0.2% MUTAGENIC AND TERATOGENIC EFFECTS- M ay cause fetal and reproductive abnormalities. CHEM ICAL CAS# PERCENT Toluene 108-88-3 10-15% M ethanol 67-56-1 1-2% Xylene 1330-20-7 1-2% HMIS NFPA If swallowed, vomiting may occur spontaneously, but DO NOT INDUCE If vomiting occurs, keep head below hips to prevent aspiration into lungs. Never give anything by mouth to an unconscious person. Call a physician or hospital emergency room immediately. SECTION—5 FIRE FIGHTING MEASURES FLASH POINT n.o.s. METHOD NFPA FLAM M ABILITY CLASSIFICATION -16°C (3°F) (Acetone) TAG Closed Cup Class IB Flam mable Liquid FLAM M ABLEUMITS LOW ER UPPER AUTO-IGNITION TEM PERATURE 2.6% 12.8% 465°C (869°F) EXTINGUISHING M EDIA Use DRY chemicals, CO2, alcohol foam. W ater spray to coolor protect exposed materials. EXPLOSION HAZARDS Mechanical Impact Static Discharge Reactive with: Not Expected Expected Acids and oxidizers such as chlorine and other halogens, chromates, perchlorates, peroxides and oxygen. SPECIAL FIRE AGHTING PROCEDURES M ay explode if ignited in an enclosed area. Hashback along vapor trail may occur. SPECIAL FIRE AGHTING PROTECTIVE EQUIPM ENT Use M SHA/ NIOSH approved self-contained breathing apparatus and full protective gear. (Full Bunker Gear) HAZARDOUS COM BUSTION PRODUCTS Burning or thermal decomposition can produce carbon monoxide and/or carbon dioxide and other toxic fumes. SECTION—6 ACCIDENTAL RELEASE MEASURES SPILL OR LEAK — DANGER! EXTREM ELY FLAM M ABLE LIQUID AND VAPOR. Warn personal to move away and eliminate ignition sources and ventilate area. Wear the appropriate safety equipment. Contain spill or stop the flow and absorb with an inert material and place in an appropriate waste disposal unit and dispose of in accordance with all State and Federal Guidelines and Regulations. SECTION—7 HANDLING AND STORAGE HANDLING — EXTREM ELY FLAM M ABLE LIQUID AND VAPOR, Avoid flame, sparks static discharge and all electric devices. Avoid inhalation of vapors or contact with eyes or skin. Do not allow material to contaminant water sources. Open container slowly to relive pressure. Bond and ground all equipment when transferring form one vessel to another. Can accumulate static discharge by flow or agitation. The use of explosion-proof equipment is recommended and may be required. Wash thoroughly after handling and do not wear any contaminated clothing or shoes.

Health hazards

2 Health Fire Hazard 3 Flammability Reactivity 0 Reactivity 0 Personal Protection G Specific hazard Page 1 of 6 2649 EYE CONTACT - Immediately flush eyes with cold water for at least 15 minutes while lifting upper and lower eyelids. Be sure to remove any contact lenses. Obtain immediate medical attention. SKIN CONTACT - Immediately flush skin with plenty of water for at least 15 minutes while removing any contaminated clothing or shoes. Cover the irritated skin with an emollient. Obtain medical attention if irritation persists. Wash any contaminated clothing and/or shoes before reuse. INHALATION — Remove person to fresh air, if they have problem breathing or any signs of overexposure, obtain immediate medical attention. INGESTION -— DO NOT INDUCE VOMITING. If person is fully conscious give one to two glasses of water to dilute and obtain immediate medical attention.

Storage

Keep container tightly closed when not in use and store in a cool, well-ventilated area away for direct sunlight or any ignition sources. Use proper signage. Store only in approved containers. Keep away from incompatible materials listed in Section 10.

TOXICOLOGICAL INFORMATION

TOXICITY RESULT EXPOSURE COM PONENT FORM SUBJECT VALUE TIME Acetone LD50 ORAL RABBIT 5340 mg/kg Toluene LD50 ORAL RAT 2.6 to 7.5 g/kg LC50 INHALED RAT 8000 ppm 4 HR LD50 ORAL RAT 2.6 to 7.5 g/kg LC50 INHALED RAT 8000 ppm 4 HR 2-Butoxyethanol LD50 SKIN RABBIT 220 mg/kg LD50 SKIN GUINEA PIG > 2000 mg/kg LC50 INHALED RAT 700 ppm 7 hr M ethanol LD50 ORAL RAT 5628 mg/kg LD50 SKIN RABBIT 15800 mg/kg LC50 INHALED RAT 64000 ppm 4hr Isopropyl Alcohol LD50 ORAL MOUSE 3800 gm/kg LD50 ORAL RABBIT 6410 mg/kg LD50 ORAL RAT 5045 mg/kg LD50 SKIN RABBIT 12800 mg/kg M ethyl Ethyl Ketone LD50 ORAL RAT 2737 mg/kg LC50 SKIN RABBIT 23,500 mg m3 8 HR LD50 ORAL RABBIT 6480 mg/m3 Xylene Isomers LD50 ORAL RAT 4300 mg/kg LC50 INHALED RAT 5000 ppm 4 HR LD50 ORAL RAT 4300 mg/kg LC50 INHALED RAT 5000 ppm 4 HR Amyl Acetate LD50 ORAL RAT 6,500 mg/kg LD50 SKIN RABBIT 8327 mg/kg Page 3 of 6 2661 SECTION — 12

ECOLOGICAL INFORMATION

ECOTOXICITY RESULT EXPOSURE COM PONENT SUBJECT VALUE TIME Acetone LC50 M osquito Fish 13000 mg/! 48 HR Toluene LC50 Fish 10 to 100 mg/I 96 HR 2-Butoxyethanol LC50 Daphnia magna 835 mg/l EC50 Water flea 2500 mg/I LC50 Flathead M innow 1900 mg/l LC50 Lepomis macrochirus 435 mg/l M ethanol LC50 Goldfish 250 ppm 11 HR LC50 Rainbow trout 8000 mg/L 48 HR LC50 Flathead M innow 29.4q/L 96 HR Isopropyl Alcohol LC50 Goldfish 5000 mg/! 24 HR LC50 Flathead M innow 11830 mg/I 1 HR M ethyl Ethyl Ketone LC50 Fish > 100 gm/I 96 HR Xylene LC50 Oncorhynchus mykiss 8.2 mg/l 96 HR LC50 Lepomis macrochirus 12 mg/l 96 HR LC50 Pimephales promelas 13.3 mg/l 96 HR Amyl Acetate LC50 Fish 10 to 100 mg/I 96 HR ENVIRONM ENTAL FATE This material, as supplied, when discarded or disposed of, is a hazardous waste according to Federal Regulations (40 CFR 261) due to its ignitability and due to the composition containing some or all of its components. Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, weather the material isa hazardous waste. The transportation, storage, treatment and disposal of RCRA waster material must be conducted in compliance with 40 CFR 262, 263, 264 and 270. Disposal can only occur in property permitted facilities, Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDSincomplete, inaccurate, or otherwise inappropriate. SECTION — 13 DISPOSAL CONSIDERATIONS DO NOT DUM P INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. Dispose of any waste in accordance with all State and Federal Guidelinesand Regulations. SECTION — 14 TRANSPORT INFORMATION D.O.T. CLASAFICATION

UN Number

UN1993 PROPER SHIPPING NAM E FLAM M ABLE LIQUIDS, n.o.s. N.O.S (Acetone, Toluene, M ethanol)

Hazard categories

PACKING GROUP PGIl LABEL CODES 3 FLAM M ABLE LIQUID REPORTABLE QUANTITY 1000 LBS EM ERGENCY RESPONSE NUM BER 127 (Acetone) 130 (Toluene) M ARINE POLLUTANT NO Page 4 of 6 2672 SECTION— 15 REGULATORY INFORMATION TSCA CASNo. Sec8(b) Sec 8(d) Sec 4(a) Sec 12(b) Chemical Name Inventory Health & Safety Chem ical Test Rules Export Notification Acetone 67-64-1 Y Toluene 108-88-3 Y 2-Butoxyethanol 111-76-2 Y M ethanol 67-56-1 Y Isopropyl Alcohol 67-63-0 Y M ethyl Ethyl Ketone 78-93-3 Y Xylene, all isomers 1330-20-7 Y Amyl Acetate 628-63-7 Y Reportable Quantities CASNo.

2.1 Classification of the substance or mixture

127 (Acetone) 130 (Toluene) M ARINE POLLUTANT NO

SECTION 2: Hazards identification

> >

Signal word

Danger Category: GHS Codes Description H302/H3 12/H332 Harmful if swallowed, inhaled, or in contact with skin. H314 Acid causes severe skin burns and eye damage. H315/H318 Causes skin irritation, serious eye damage. H302/H3 13/H332 Contact with internal components may cause irritation or severe burns. H350 May cause cancer if ingested or inhaled. H360 May damage fertility or the unborn child if ingested or inhaled. H373 Causes damage to central nervous system, blood and kidneys through prolonged or repeated exposure if ingested or inhaled. Health: STOT RE 2 H220 Extremely flammable gas (hydrogen). May form explosive air/gas mixture Acute Tox. 4 during charging. Repr. 1A H203 Explosive, fire, blast or projection hazard. Skin Corr. 1A H410 Very toxic to aquatic life with long lasting effects. Flam. Gas 1 P260 Do not breathe dust/fume/gas/mist/vapors/spray. Carc. 1A (arsenic) P314 If exposed/concerned, or if you feel unwell seek medical attention/advice. P301/330/331 IF SWALLOWED OR CONSUMED: rinse mouth. Do NOT induce Aquatic Chronic 1 vomiting. Call a poison center/doctor if you feel unwell. Aquatic Acute 1 P303/361/353 IF ON CLOTHING OR SKIN (or hair): Remove/Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. P304/340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305/35 1/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P311 Immediately call a POISON CENTER or doctor/physician. H362 May cause harm to breast-fed children. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P263 Avoid contact during pregnancy/while nursing. P264 Wash thoroughly after handling. Handling: P270 Do not eat drink or smoke when using this product. ° P280 Wear protective gloves/protective clothing/eye protection/face protection. P403/P405 Store locked up, in a well-ventilated area, in accordance with local and national regulation. P271 Use only outdoors or in a well-ventilated area. P501 Dispose of contents/container in accordance with local & national laws. P201 Keep out of reach of children. WARNING: Batteries subjected to abusive charging at excessively high currents for prolonged periods of time without vent caps in place may create a surrounding atmosphere of the offensive strong inorganic acid mist containing sulfuric acid. Page 1 of 7 2305 Reactivity: Highly reactive with water and alkalis HiIl. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient CAS Number % by Wt. Inorganic compounds of: Lead 7439-92-1 42-70 Antimony 7440-36-0 0.3-1.0 Tin 7440-31-5 0.15-0.4 Calcium 7440-70-2 0.00-0.03 Arsenic 7440-38-2 0.01-0.03 Electrolyte (sulfuric acid/water/solution) 7664-93-9 23-50 Case Material: Polypropylene 9003-07-0 2.5-10.5 Plate Separator Material: Polyethylene 9002-88-4 0.7-1.7 Note: Inorganic lead and electrolyte (water and sulfuric acid solution) are the primary components of every battery manufactured by Exide Technologies or its subsidiaries. Other ingredients may be present dependent upon battery type. Polypropylene is the principal case material of automotive and commercial batteries.

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