SatPax 70% Ethanol (denatured) / 30% DI H2O

Berkshire Corporation

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GHS02 GHS07 GHS08
Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

General Information

Product name

SatPax 70% Ethanol (denatured) / 30% DI H2O

supplier name

Berkshire Corporation

Icons in SDS

Company Information

company name

Berkshire Corporation

e-mail address of the competent person responsible for the Safety Data Sheet

csr@berkshire.com

Section 2

SECTION 2: Hazards identification

OSHA OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

2.1 Classification of the substance or mixture

FLAMMABLE SOLIDS - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 2

2.2 Label elements

Section 4. First aid measures Ingestion Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention following exposure or if feeling unwell. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Most important symptoms/effects, acute and delayed

Potential Acute Health Effects

Eye contact : Causes serious eye irritation. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Irritating to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing Use dry chemical, CO2, water spray (fog) or foam. media Unsuitable extinguishing Do not use water jet or water-based fire extinguishers. media Specific hazards arising Flammable solid. from the chemical Hazardous thermal Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide Section 5. Fire-fighting measures Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Spill Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not ingest. Use only with adequate ventilation. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. Remove contaminated clothing and protective equipment before entering eating areas. Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved area. including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits United States Ingredient name Exposure limits Ethyl Alcohol ACGIH TLV (United States, 3/2012). STEL: 1000 ppm 15 minutes. NIOSH REL (United States, 6/2009). TWA: 1900 mg/m³ 10 hours. TWA: 1000 ppm 10 hours. OSHA PEL (United States, 6/2010). TWA: 1900 mg/m³ 8 hours. TWA: 1000 ppm 8 hours. Methanol ACGIH TLV (United States, 3/2012). Absorbed through skin. STEL: 328 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 262 mg/m³ 8 hours. TWA: 200 ppm 8 hours. NIOSH REL (United States, 6/2009). Absorbed through skin. STEL: 325 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 260 mg/m³ 10 hours. TWA: 200 ppm 10 hours. OSHA PEL (United States, 6/2010). TWA: 260 mg/m³ 8 hours. TWA: 200 ppm 8 hours. Mexico Ingredient name Exposure limits Ethyl Alcohol NOM-010-STPS (Mexico, 9/2000). LMPE-PPT: 1900 mg/m³ 8 hours. LMPE-PPT: 1000 ppm 8 hours. Methanol NOM-010-STPS (Mexico, 9/2000). Absorbed through skin. LMPE-CT: 310 mg/m³ 15 minutes. LMPE-CT: 250 ppm 15 minutes. LMPE-PPT: 260 mg/m³ 8 hours. LMPE-PPT: 200 ppm 8 hours. Appropriate engineering : Use only with adequate ventilation. If user operations generate vapor, use process controls enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep vapor concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Recommended: Safety glasses. Skin protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Section 8. Exposure controls/personal protection Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Recommended: Vapor respirator. Section 9. Physical and chemical properties Appearance Physical state Solid. [Solid containing liquid (prewetted wiper)] Color White substrate with colorless liquid. Odor Rubbing alcohol. Odor threshold Not available. pH Not available. Melting point Not available. Boiling point : 78.8°C (173.8°F) Flash point Closed cup: 17°C (62.6°F) Open cup: 20°C (68°F) Burning time : Not available. Burning rate : Not available. Evaporation rate Not available. Flammability (solid, gas) : Not available. Lower and upper explosive : Not available. (flammable) limits Vapor pressure 6 kPa (45 mm Hg) [room temperature] Vapor density Not available. Relative density Not available. Solubility Not available. Solubility in water : Not available. Eye contact : Causes serious eye irritation.

TOXICOLOGICAL INFORMATION

Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure Ethyl Alcohol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours LD50 Oral Rat 7 g/kg - Methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours LC50 Inhalation Gas. Rat 64000 ppm 4 hours LD50 Dermal Rabbit 15800 mg/kg - LD50 Oral Rat 5600 mg/kg - Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Ethyl Alcohol Eyes - Moderate irritant Rabbit - 100 µL - Skin - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Mild irritant Rabbit - 24 hours 500 mg - Eyes - Moderate irritant Rabbit - 0.066666667 - minutes 100 mg Eyes - Severe irritant Rabbit - 500 mg - Skin - Mild irritant Rabbit - 400 mg - Methanol Eyes - Moderate irritant Rabbit - 24 hours 100 mg - Skin - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Moderate irritant Rabbit - 40 mg - Sensitization There is no data available. Carcinogenicity There is no data available. Specific target organ toxicity (single exposure) Name Category Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : Irritating to mouth, throat and stomach. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards. Long term exposure Potential immediate : No known significant effects or critical hazards. effects Potential delayed effects : No known significant effects or critical hazards.

Principle Routes of Exposure

Target organs Methanol Category 1 Not determined Specific target organ toxicity (repeated exposure) There is no data available.

Aspiration hazard

There is no data available. Information on the likely : Not available.

Potential chronic health

effects General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards.

Teratogenic Effects

No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Route ATE value Oral 3333.3 mg/kg Dermal 10000 mg/kg Inhalation (vapors) 100 mg/L

ECOLOGICAL INFORMATION

Toxicity Product/ingredient name Result Species Exposure Ethyl Alcohol Acute EC50 17.921 mg/L Marine water Algae - Ulva pertusa 96 hours Acute EC50 2000 µg/L Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 µg/L Marine water Crustaceans - Artemia franchiscana - 48 hours Larvae Acute LC50 42000 µg/L Fresh water Fish - Oncorhynchus mykiss 4 days Chronic NOEC 4.995 mg/L Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks Methanol Acute EC50 16.912 mg/L Marine water Algae - Ulva pertusa 96 hours Acute EC50 10000000 µg/L Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 2500000 µg/L Marine water Crustaceans - Crangon crangon - Adult 48 hours Acute LC50 100 mg/L Fresh water Fish - Pimephales promelas - Juvenile 96 hours (Fledgling, Hatchling, Weanling) Chronic NOEC 9.96 mg/L Marine water Algae - Ulva pertusa 96 hours Persistence and degradability There is no data available. Bioaccumulative potential Product/ingredient name LogPow BCF Potential Ethyl Alcohol -0.32 - low Methanol -0.77 <10 low Mobility in soil Soil/water partition : Not available. coefficient (KOC)

Other hazards

No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. United States - RCRA Toxic hazardous waste "U" List Ingredient CAS # Status Reference number Methanol 67-56-1 Listed U154 Section 15. Regulatory information SARA 311/312

Classifications

Fire hazard Immediate (acute) health hazard

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