General Information
Version
2.6
Product name
Product nama
1.2.1 Relevant identified uses
d the chemical and restrictiona on uae
Emergency telephone
1-800-255-3924, +1 813-248
Icons in SDS
Company Information
company name
Belzona Inc
e-mail address of the competent person responsible for the Safety Data Sheet
sds@belzona.com
GHS Information
Signal word
Waming
Section 2
Physical hazards
Not Classified Health hamrda Skin Sens. 1 - H317 STOT RE 2 - H373 The full text for all hazard statements is displayed in Section 16. L.ab81 element& 1/10
Signal word
Waming H8Za'd atatarnanta H317 May cause an allergic skin reaction. H373 May cause damage to organs (Uver) through prolonged or repealed exposure if swallowed. P261 Avoid breathing vapors. P272 Contaminated work clothing must not be allowed out of the wcl't(place. P280 Wear protective gloves, protective clothing and eye protection. P302+P352 If an skin: Wash with plenty of water. P314 Get medical attention if you feel unwell. P333+P3131f skin irritation or rash occurs: Get medical attention. P362+P364 Take off contaminated clothing and wash It before reuse. P501 Dispose of contents/container In accordance with all Federal, state/Provincial and local regulations. Contama N,N-DIALKYLAMINO-DIPHENYLMETI-IANE
2.3 Other hazards
Not applicable. Hazawda not otharwiae Not applicable. classlllad (HNOC) Ia. Compoeltlorvtrrormatlon on lrvadlanlll Mixbne I~E~ CAS number: 5285-60-9 1,1', 1•, 1•-ETHYLENEDINITRILOTETRAPROP~L 6-10% CAS number: 102-60-3 POL YETHER POL YOL I CAS number: 25322-69-4 ~on of1ht aid maaauraa General Information In all cases of doubt, or when symptoms persist, seak medical attantian. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air. Keep the patient warm and at rest. Give nothing by mouth. Ingestion If accidentally swallowed obtain Immediate medical attention. Keep at rvst. Rinse mouth with plentyofwater. Do NOT induce vomiting. SkinContacl: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. If irritation or inflammation persists, seek medical attention. 2/10 Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart, and seek medical advice. Most important aymploms and effects, both acute and delayed Ingestion May cause stomach pain or vomiting. Skin contact May cause an allergic skin reaction. Eye contact May irritate eyes. Indication of immediate medical attention and special treatment needed Notes for the doctor None. Is. Fire-fighting measures Extinguishing media Suitable extinguishing media Use: sand, alcohol resistant foam, carbon dioxide, chemical powder, or water fog for larger fires. Do NOT use water jet. Special hazards arising from the substance or mixture Flammability Class 3.2 Combustible liquid IIIB Specific hazards When heated and in case of fire, hannful vapors/gases may be formed. Advice for firefighters Protective actions during Fire will produce dense black smoke containing hazardous products of combustion. Exposure flreflghtlng to decomposition products may be a hazard to health. Appropriate positive-pressure self- contained breathing apparatus (SCBA) and full fire fighting turn-out gear (Bunker gear) should be worn. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains, sewers, ditches or waterways. Ia. Accidental release measures Personal precautions, protective equipment and emergency procedures Personal precautions Exclude non-essential personnel. Avoid contact with skin and eyes. Environmental precautions Prevent product entering drains or sewers. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Methods and material for containment and cleaning up Methods for cleaning up Scrape the majority of the product into a suitable labeled container. Cover the spi II area with sand or other suitable inert material and sweep up into the container. Clean surfaces down with a water and detergent mixture. Do not allow spilled product or the associated washings to enter surface water drains or watercourses. Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13 .. 17. Hancllng and storage Precautions for safe handling 3110 Usage precautions Vapors may collect in the container headspace during transit or prolonged storage. Avoid breathing vapor when opening the container. Where possible open containers and mix components in a well ventilated place away from the application area. Avoid contact with eyes, skin and clothing. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Always keep in containers made of the same material as the supply container. Good housekeeping methods and regular safe removal of waste materials should be observed. FIRE/EXPLOSION This product is combustible. Exclude sources of heat, sparks and open flame. Ensure emergency equipment (for fires, spills, leaks, etc.) is readily available. Advice on general Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure occupational hygiene eye wash facilities (fountain, bottle, vials, etc.) are readily available. Do not put contaminated articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets. Where necessary, contaminated work clothing and shoes should be removed to prevent cross contamination of surfaces and the risk of inadvertent skin contact and ingestion. Conditions for safe storage, including any incompatibilities Storage precautions Observe the label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Store separately from oxidizing agents and strongly alkaline and strongly acidic materials. ENVIRONMENTAL STORAGE PRECAUTIONS Spillage, incorrect storage of chemicals or waste materials or unsuitable disposal activities can result in pollutants seeping through the soil, causing serious harm to groundwater- which is a vital source of drinking water. All wastes, especially liquid wastes, should be securely stored on site in designated areas that are isolated from waterways and groundwater and diked to contain any spillages. Specific end usas(s) Specific end usa(s) Application by plastic applicator or spatula provided. Mix with Solidifier component before use. Please refer to the relevant Belzona® Instructions For Use for further information. Ia. Exposure controlsiPeraonal protection Control parameters Occupational exposure limits No exposure limits known for ingredient(s). Exposure controls Appropriate engineering Use in well ventilated areas or provide adequate mechanical ventilation. controls Eyall'ace protection It is recommended that eye protection, for example safety glasses with side shields or goggles are worn at all times during the handling and use of this material. . During subsequent machining, grinding, abrasion or removal of this product appropriate eye protection should be selected according to the type of tools or equipment used . Hand protection . The breakthrough time of the gloves selected should exceed the expected use period. Where this is not possible, gloves should be changed in good time, and in any case before the breakthrough time is exceeded. Where doubt exists, advice should be sought from manufacturers or vendors of protective gloves in order to determine appropriate types for the particular circumstances. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. SPECIFIC RECOMMENDATIONS Wear protective gloves made of the following material: Nitrile rubber. STANDARD APPLICATIONS I EMERGENCY SITUATIONS Medium- heavy weight gauntlet type gloves that provide wrist protection are suitable. APPLICATION OF SMALL QUANTITIES Light weight disposable gloves are normally suitable. 4/10 other skin and body STANDARD APPLICATIONS Synthetic polyethylene coveralls such as the Tyvek PRO- protection TECH® or equivalent coveralls manufactured to provide protection against liquid chemicals should be worn. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. APPLICATION OF SMALL QUANTITIES Cotton overalls are normally suitable. Respiratory protection Respiratory protection is not normally required, but the hazards of the Solidifier component should be considered for mixing and application purposes. Immediate danger to life and Where entry into unknown or Immediately Dangerous To Life or Health (IDLH) atmospheres is health required, an OSHNNIOSH approved pressure-demand self-contained breathing apparatus (SCBA) with a full facepiece or a pressure-demand supplied-air respirator (SAR) with a full facepiece in combination with an auxiliary pressure-demand SCBA respirator should be worn. Is. Physical and chemical properties Information on basic physical and chemical properties Appearance Paste. Color Dark gray. Odor Amine. Odor threshold Not applicable. pH Alkaline. Melting point Not available. Initial boiling point and range >240°C/>464°F@ 760 mm Hg Flash point >160°C/>320°F Closed cup. Evaporation rate Not available. Upper/lower flammability or Not available. explosive limits Vapor pressure < 0.13 kPa @ 20°C/68°F Vapor density Relative density 2.25-2.35@ 20°C/68°F Solublllty(les) Slightly soluble in water. Partition coefticient Not available. Autoignition temperature >250°C/>482°F Decomposition Temperature Not available. VIscosity Not available. Explosive properties Not applicable. Oxidizing properties Not applicable.
Further information
This section contains typical values for Health, Safety and Environmental guidance only and is not intended to represent a technical specification for the product. l1 o. Stabllty and readlvtty Reactivity There are no known reactivity hazards associated with this product. 5/10 Stability Stable under recommended storage and handling conditions {see Section 7). Possibility of hazardous No hazardous reactions expected when stored and handled as recommended. raactions Conditions to avoid Keep away from oxidizing agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Matertals to avoid Keep away from oxidizing agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Hazardous decomposition Does not decompose when used and stored as recommended. producls !11. Toxicological irtormation Information on toxicological etracls Acute toxicity - oral Notes (oral LO.) Based on available data the classification criteria are not met. Acute toxicity - dermal Notes (dennal LO.) Based on available data the classification criteria are not met. Acute toxicity - inhalation Notes (inhalation LC.O) Based on available data the classification criteria are not met. Skin corrosion/irritation Animal data Based on available data the classification criteria are not met. Serious aye damage/irritation Serious aye damage/irritation Conclusive data but not sufficient for classification. Respiratory sensitization Based on available data the classification criteria are not met. Skin sensitization May cause skin sensitization or allergic reactions in sensitive individuals. Germ cell mutagenicity Genotoxicity- in vitro Based on available data the classification criteria are not met. Genotoxlclty- In vivo Based on available data the classification criteria are not met. Caroinogenicity Carcinogenicity Based on available data the classification criteria are not met. IARC carcinogenicity Not listed. NTP carcinogenicity Not listed. OSHA Caroinogenicity Not listed. Reproductive toxicity Reproductive toxicity - fertility Based on available data the classification criteria are not met. Reproductive toxicity - Based on available data the classification criteria are not met. development Specific target organ toxicity - single exposure 6/10 STOT - single exposure Based on available data the classification criteria are not met. Specific target organ toxicity - repeated exposure STOT- repeated exposure Harmful: danger of serious damage to health by prolonged exposure if swallowed. Target organs Liver Aspiration hazard Based on available data the classification criteria are not met. Route of exposure Oral Skin and/or eye contact Medical considerations Skin contact constitutes a pronounced hazard. Persons with a history of skin sensitization problems should only be employed in processes in which this product is used under appropriate medical supervision. Toxicological information on ingi"BdieniB. N,N-DIALKYLAMINO-DIPHENYLMETHANE Acute toxicity- oral Acute toxicity oral (LD.a 1,340.0 mglkg) Species Rat l12. Ecological infonnation Ecotoxlclty There is no data on the product itself. The following information is provided on the basis of the individual component data available. Toxicity Based on the individual component data, the product is expected to have experimental LC50/EC50/IC50 values between 1 and 10 mg/1 in most sensitive species. Persistence and degradability Persistence and degradability This product is not expected to be readily biodegradable. Bioaccumulative potential Blo-Accumulatlve Potential Based on the individual component data, the product is expectad to bioaccumulate. Partition coeflicient Not available. Mobility in soil Mobility There is no data available on the product itself. Other adverse efl'8cts None known. 113. Disposal conslderalona Waste treatment methods 7110 Disposal methods Do NOT dump into any sewers, on the ground, or into any body of water. Controlled wastes include non-hazardous industrial and hazardous chemical wastes. Disposal must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations are the responsibility solely of the waste generator ... COMPONENT DISPOSAL TRANSIT PACKAGING: shrink or stretch wrap, boxes and fittings that have not been contaminated with product should be re-used or recycled. UNREACTED PRODUCT, and empty uncleaned containers should be disposed of as non-hazardous waste. REACTED PRODUCT, that has been mixed and cured in accordance with the relevant 'Instructions For Use' will form an inert filled polymeric compound that may be able to be disposed of as non-hazardous solid waste. Refer to your local licensed, permitted waste agent or facility. Waste class . Waste class is not relevant. . 114. Transport lnfcnnatlon General This product is not regulated for transport by US DOT, and qualifies for exemption (TOG 1.45.1) if shipped on land in Canada. Labeling and packaging requirements may vary with pack and load size. Please refer to the current transport regulations. Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. UN Number UN No. (TDG) 3077 UN No. (IMDG) 3077 UN No. (ICAO) 3077 UN No. (DOn Not applicable. UN proper shipping name Proper shipping name {TOG) Environmentally hazardous substance, solid, n.o.s. (containing N,N-dialkylamino- diphenylmethane mixture) Proper shipping name {IMDG) Environmentally hazardous substance, solid, n.o.s. (containing N,N-dialkylamino- diphenylmethane mixture) Proper shipping name {ICAO) Environmentally hazardous substance, solid, n.o.s. (containing N,N-dialkylamino- diphenylmethane mixture) Proper shipping name {Don Not applicable Transport hazard class(as) DOT hazard class Not applicable. TOG class 9 IMDGCiass 9 ICAO classldMslon 9 Packing group TOG Packing Group Ill IMDG packing group Ill ICAO packing group Ill DOT packing group Not applicable. 8/10 Environmental hazards Environmentally Hazardous Substance Yes Not a marine pollutant under US DOT. Special precautions for user Not applicable. Transport In bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code 115. Regulatory lnformalon US Federal Regulations SARA 313 Emission ReporUng SECTION 313: This product does not contain toxic chemical subject to the reporting requirements of Section 313 of Title Ill of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372. SARA(311/312) Hazard categories None US State Regulations State Regulations Comments U.S California Safe Drinking Water & Toxic Enforcement Act (Proposition 65): To the best of our knowledge, this product does not contain any chemicals known to the State of California to cause cancer or reproductive toxicity. lnventortes Canada- DSLJNDSL All the ingredients are listed or exempt. US-TSCA All the ingredients are listed or exempt. 118. Olh.-lnfcrmatlon General Information The information contained within this safety data sheet does not constitute the users own assessment of workplace risks as may be required by other Local Regulations. As the specific conditions of use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant Local Regulations are complied with. To the best of our knowledge, the information contained herein is accurate. However, some of the information presented and conclusions drawn are derived from sources other than direct test data on the product itself and while Belzona Inc. believes such sources to be reliable, the information is provided without any warranty regarding its correctness. Since Belzona Inc. has no control over the conditions under which the product will be used, liability will not be assumed to exceed replacement or refund of the purchase price of this product. Except as stated herein, there are no express or implied warranties including implied warranties of merchantability or fitness for a particular purpose. Belzona Inc. assumes no liability for injury or incidental or consequential damage arising out of the storage, handling, use or, disposal of this product. Key literature references and aouroes ror data Training advice For further information please contact your supplier, Belzona consultant or Belzona direct. 9/10 Revision comments REVISION. This safety data sheet has been revised in the following Section(s): 2, 3, 4, 6, 11, 12, 14, Please observe the REVISION DATE. Should you be reading a material safety data sheet that is more than 24 months old or have concerns over its validity, please contact your local Belzona Distributor or Belzona direct ( sds@belzona.com) and the most current information will be sent to you. Revision date 10/2312019 Revision 2.6 SDS No. 10588 SDS stalus English (North American). Approved. Hazard statements in full H317 May cause an allergic skin reaction. H373 May cause damage to organs (liver) through prolonged or repeated exposure if swallowed. NFPA- health hazard Irritation, minor residual injury. (1) NFPA - flammability hazard Bums only if pre-heated. ( 1) NFPA - Instability hazard Normally stable. {0)