P302+P352

Hazard statements (CLP)

H315, H317, H319, H335, H373, H411, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

SECTION 6. Accidental release measures. Information not available. Benzophenone Protect hands with category III work gloves (see standard EN 374). 6. Regulation (EC) 453/2010 of the European Parliament mg/kg NOT rapidly biodegradable. INERT

2.1 Classification of the substance or mixture

10.6. Hazardous decomposition products. The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. 7. Regulation (EC) 286/2011 (II Atp. CLP) of the European Parliament 6.1. Personal precautions, protective equipment and emergency procedures.

Further information

CAS. - 50 - 100 The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on 8. Regulation (EC) 618/2012 (III Atp. CLP) of the European Parliament Information not available. 1,6-HEXANEDIOL DIACRYLATE (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate Block the leakage if there is no hazard. the duration and type of use. Text of hazard (H) indications mentioned in section 2-3 of the sheet: 9. The Merck Index. - 10th Edition EC. - The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments Predicted no-effect concentration - PNEC. Rapidly biodegradable. The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments INDEX. - Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent SKIN PROTECTION 10. Handling Chemical Safety and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and bisphenol-A-epoxy acrylate Normal value for the terrestrial compartment. 0.00243

TOXICOLOGICAL INFORMATION

any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body 11. Niosh - Registry of Toxic Effects of Chemical Substances STOT RE 2 mg/kg Specific target organ toxicity - repeated exposure, category 2 12.3. Bioaccumulative potential. subsequent amendments. CAS. Normal value in fresh water. 55818-57-0 9 - 30 R53, Xi R43 Skin Sens. 1 H317 0.0073 procedures. with soap and water after removing protective clothing. 12. INRS - Fiche Toxicologique (toxicological sheet) Eye Irrit. 2 mg/l Eye irritation, category 2 Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Information not available. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. EC. Normal value for water, intermittent release. 500-130-2 0.73 11.1. Information on toxicological effects. EYE PROTECTION 13. Patty - Industrial Hygiene and Toxicology Skin Irrit. 2 mg/l Skin irritation, category 2 6.2. Environmental precautions. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it INDEX. Normal value in marine water. - 0.0007 Wear airtight protective goggles (see standard EN 166). 14. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition STOT SE 3 mg/l Specific target organ toxicity - single exposure, category 3 2.1.1. Regulation 1272/2008 (CLP) and following amendments and adjustments. 12.4. Mobility in soil. Normal value for fresh water sediment. 0.019 The product must not penetrate into the sewer system or come into contact with surface water or ground water. contains, using the criteria specified in the applicable regulation for classification. Reg. no. 01-2119490020-53 Skin Sens. 1 mg/kg Skin sensitization, category 1 RESPIRATORY PROTECTION 15. ECHA website Information not available. Normal value for marine water sediment. 0.0019 mg/kg (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2 Hazard classification and indication: Aquatic Chronic 3 Normal value of STP microorganisms. Hazardous to the aquatic environment, chronic toxicity, category 3 Xi R36/37/38, Xi R43, N R51/53 Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, 100 6.3. Methods and material for containment and cleaning up. toxicological effects of exposure to the product. B filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases CAS. mg/l 42978-66-5 10 - 20

Results of PBT and vPvB assessment

Health - Derived no-effect level - DNEL / DMEL. H373 Eye Irrit. 2 H319 May cause damage to organs through prolonged or repeated exposure. Skin Sens. 1 H317, Aquatic Chronic 2 H411 Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Note for users: EC. 256-032-2 H319 Skin Irrit. 2 Skin Irrit. 2 H315 Causes serious eye irritation. Effects on consumers. Effects on workers. remainder with inert absorbent material. Acute effects stinging eyes. Symptoms may include rubescence, edema, pain and lachrymation Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the INDEX. 607-249-00-X On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. H315

Principle Routes of Exposure

Skin Sens. 1 H317 Causes skin irritation. H317 Acute Chronic Acute Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed Vapour inhalation may moderately irritate the upper respiratory trait. Contact with skin may cause slight irritation. threshold values considered. The protection provided by masks is in any case limited. suitability and thoroughness of provided information according to each specific use of the product. Reg. no. 01-2119484613-34-0005 Chronic 1,6-HEXANEDIOL DIACRYLATE H335 Aquatic Chronic 3 H412 May cause respiratory irritation. local. systemic. local. systemic. local. systemic. of in compliance with the provisions set forth in point 13. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an Ingestion may cause health problems, including stomach pain and sting, nausea and sickness. This document must not be regarded as a guarantee on any specific product property. local. systemic.

Other hazards

H317 Oral. May cause an allergic skin reaction. VND 2,08 Xi R36/38, Xi R43, Note D Acute effects contact with skin may cause irritation, erythema, edema, dryness and chapped skin. Vapour inhalation may slightly irritate the emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health CAS. Eye Irrit. 2 H319, Skin Irrit. 2 H315, Skin Sens. 1 H317, Note D 13048-33-4 5 - 9 2.1.2. 67/548/EEC and 1999/45/EC Directives and following amendments and adjustments. EC. H411 235-921-9 Toxic to aquatic life with long lasting effects. mg/kg 6.4. Reference to other sections. upper respiratory trait. Ingestion may cause health disorders, including stomach pain and sting, nausea and sickness. apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. H412 Harmful to aquatic life with long lasting effects. Information not available. Any information on personal protection and disposal is given in sections 8 and 13. Upon contact with skin, this product causes sensitization (dermatitis). Dermatitis derives from skin irritation on the areas which repeatedly INDEX. 607-109-00-8 Inhalation. VND 7,24 VND 24,48

Hazard pictograms

ENVIRONMENTAL EXPOSURE CONTROLS. Provide appointed staff with adequate training on how to use chemical products. Reg. no. 01-2119484737-22-0005 Xi mg/m3 come into contact with the sensitizing agent. Cutaneous lesions may include: erythemas, edemas, papules, vesicles, pustules, scurvies, The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure Text of risk (R) phrases mentioned in section 2-3 of the sheet: mg/m3 Benzophenone ulcerations and exudative phenomena, whose intensity varies according to illness seriousness and affected areas. Erythemas, edemas and Skin. VND 1,66 VND 2,77 SECTION 13. Disposal considerations. SECTION 7. Handling and storage. T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Odour R53 MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT. Not available. Dangerous for the Environment(N) LD50 (Oral). from any incompatible materials, see section 10 for details. 727 mg/kg mouse Odour threshold. Not available. SECTION 14. Transport information. pH. (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] Not available. diacrylate 7.3. Specific end use(s). Melting point / freezing point. Not available.

R-phrase(s)

compliance with environmental standards. Changes to previous review: CAS. 119-61-9 5 - 9 43-52/53 Xn R48/22, N R51/53 mg/kg STOT RE 2 H373, Aquatic Chronic 2 H411 exudative phenomena prevail during the acute phase. Scurfy skin, dryness, ulcerations and skin thickening prevail during the chronic phase. Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. The following sections were modified: R36/37/38 mg/kg IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. 13.1. Waste treatment methods. 7.1. Precautions for safe handling. 03 / 05. EC. R36/38 204-337-6 IRRITATING TO EYES AND SKIN. The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the INDEX. R43 - MAY CAUSE SENSITISATION BY SKIN CONTACT. SECTION 9. Physical and chemical properties. bisphenol-A-epoxy acrylate should be evaluated according to applicable regulations. environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering Reg. no. 01-2119899704-20-XXXX R48/22 HARMFUL: DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED EXPOSURE IF SWALLOWED.

2.2 Label elements

LD50 (Oral). Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC 30000 mg/kg Rat R51/53 9.1. Information on basic physical and chemical properties. places in which people eat. Note: Upper limit is not included into the range. LD50 (Dermal). Avoid littering. Do not contaminate soil, sewers and waterways.

Environmental hazards

2000 mg/kg Rat Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Appearance Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Not available. 7.2. Conditions for safe storage, including any incompatibilities. The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. CONTAMINATED PACKAGING R52/53 HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC Colour Benzophenone Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. Not available.