Toluene-2,4-diisocyanate

Hazard statements (CLP)

H315, H317, H319, H330, H334, H335, H351

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Directive 1999/45/EC: Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 2 H330 Fatal if inhaled GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Carc. 2 H351 Suspected of causing cancer GHS07 Skin Irrit. 2 H315 Causes skin irritation Eye Irrit. 2A H319 Causes serious eye irritation Skin Sens. 1 H317 May cause an allergic skin reaction STOT SE 3 H335 May cause respiratory irritation Classification according to Directive 67/548/EEC or Directive 1999/45/EC   Very toxic Very toxic by inhalation   Harmful Limited evidence of a carcinogenic effect Contd. of page 1)   Irritant Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin contact Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Information concerning particular hazards for human and environment The product has to be labeled due to the calculation procedure of international guidelines Classification system The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data

2.2 Label elements

· Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. · Code letter and hazard designation of product:    Very toxic

Hazardous Ingredients

toluene-2,4-diisocyanate toluene-2,6-diisocyanate

Hazard statements

Very toxic by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitisation by inhalation and skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Precautionary statements

Keep locked up and out of the reach of children. Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). After contact with skin, wash immediately with plenty of water Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). In case of accident by inhalation: remove casualty to fresh air and keep at rest.

Special rules for supplemental label elements for certain mixtures

Contains isocyanates. See information supplied by the manufacturer.

PBT Substances

Not applicable

vPvB Substances

Not applicable

2.1 Classification of the substance or mixture

  GHS06 Skull and crossbones Acute Tox. 2 H330 Fatal if inhaled.   GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer.   GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC    Very toxic Very toxic by inhalation.    Harmful Limited evidence of a carcinogenic effect. (Contd. of page 1)    Irritant Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Information concerning particular hazards for human and environment: The product has to be labeled due to the calculation procedure of international guidelines. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data.