Iso E Super

Hazard statements (CLP)

H315, H317

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification of the substance or mixture Class and category of danger Skin irritation,Category2 Skin sensitisation,Sub category 1B

Signal word

Warning

Hazard statements

H315:Causes Skin Irritation. H317:May Cause An Allergic Skin Reaction.

Precautionary statements

P280: Wear protective gloves P302P352 IF ON SKIN Wash with plenty of sleepandwater

Other hazards

None

2.1 Classification of the substance or mixture

Class and category of danger: Skin irritation,Category2 Skin sensitisation,Sub category 1B. 2.2 Label elements Signal word: Warning Hazard statements: H315:Causes Skin Irritation. H317:May Cause An Allergic Skin Reaction. Precautionary statements: P280: Wear protective gloves P302P352: IF ON SKIN:Wash with plenty of sleepandwater. Pictograms: 2.3 Other hazards Other hazards: None Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name CAS Ethanone,1-(1,2,3,5,6,7,8,8a-octahydro-2,3,8,8- tetramethyl-2- 68155-66-8,54464-57-2, naphthalenyl)- 68155-67-9 Phenol,2,6-bis(1,1-dimethylethyl)-4-methyl- 128-37-0 Substances with workplace exposure limits, not listed above: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure to fresh air and keep at rest.If victim is unconscious,remove foreign bodies from the mouth.If victim has stopped breathing,give artificial respiration.Obtain medical advice. Eye exposure: Remove contaminated clothes.Wash thoroughly with water (and soap).Contact physician if symptoms persist. Skin exposure: Flush immediately with water for at least 15 minutes.Contact physician if symptoms persist. Ingestion: Rinse mouth with water and obtain medical advice. 4.2 Most important symptoms and effects, both acute and delayed Causes mild skin irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Flammable properties Flash point: 273°F(134℃) 5.2 Fire fighting Use water spray,dry chemical,carbon dioxide or appropriate foam. 5.3 Protective equipment and precautions for firefighters: Wear NIOSH approved self-contained breathing apparatus and full firefighters protective clothing when fighting fires involving chemicals.Use water spray to cool containers exposed to fire. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation and contact with skin and eyes.A self-contained breathing apparatus is recommended in case of a major spill. 6.2 Environmental precautions: Keep away from drains,surface-and groundwater and soil. 6.3 Methods and material for containment and cleaning up: Clean up spillage promptly.Remove ignition sources.Provide Adequate ventilation.Avoid excessive inhalation of vapours.Gross Spillages should be contained by use of sand or inert powder and disposed of according to the local regulations. Section 7. Handling and storage 7.1 Precautions for safe handling: Avoid excessive inhalation of concentrated vapors.Follow good manufacturing practices for housekeeping and personal hygiene.Wash any exposed skin immediately after any chemical contact,before breaks and meals,and at the end of each work period.Contaminated clothing and shoes should be thoroughly cleaned before reuse. If appropriate,procedures used during the handling of this material should also be used when cleaning equipment or removing residual chemicals from tanks or other containers,especially when steam or hot water is used,as this may increase vapor concentrations in the workplace air.Where chemicals are openly handled,access should be restricted to properly trained employees.Keep all heated processes at the lowest necessary temperature in order to minimize emissions of volatile chemicals into the air. 7.2 Advice on protection against fire and explosion: Keep away from ignition sources and naked flame. 7.3 Requirements for storage areas and containers: Store in a cool,dry,ventilated area away from heat sources.Keep containers upright and tightly closed when not in use. Section 8. Exposure controls/personal protection 8.1 Engineering measures Engineering measures: Where feasible,isolate mixing rooms and other areas where this material is used or openly handled.Maintain these areas under negative air pressure relative to the rest of the plant. Where feasible,use closed systems to transfer and process this material. 8.2 Exposure Controls Eye / Skin Protection Use tight-fitting goggles,face shield or safety glasses with side shields if eye contact might occur. Hand protection Avoid skin contact.Use chemically resistant gloves. Respiratory Protection Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition,use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. No respiratory protection is required during normal operations in a workplace where engineering controls such as adequate ventilation,etc.are sufficient. If engineering controls and safe work practices are not sufficient,an approved,properly fitted respirator with organic vapor cartridges or canisters and particulate filters should be used: a)while engineering controls and appropriate safe work practices and/or procedures are being implemented;or b)during short term maintenance procedures when engineering controls are not in normal operation or are not sufficient;or c)if normal operational workplace vapor concentration in the air is increased due to heat; d)during emergencies;or e)if engineering controls and operational practices are not sufficient to reduce airborne concentrations below an established occupational exposure limit. Hygiene measures To the extent deemed appropriate,implement pre-placement and regularly scheduled ascertainment of symptoms and spirometry testing of lung function for workers who are regularly exposed to this material. To the extent deemed appropriate,use an experienced air sampling expert to identify and measure volatile chemicals that could be present in the workplace air to determine potential exposures and to ensure the continuing effectiveness of engineering controls and operational practices to minimize exposure. Protective measures In December 2003,the National Institute for Occupational Safety and Health ("NIOSH")published an Alert on preventing lung disease in workers who use or make flavorings [NIOSH Publication Number 2004-110]. In August 2004,the United States Flavor and Extract Manufacturers Association (FEMA)issued a report entitled "Respiratory Safety in the Flavor Manufacturing Workplace". Both of these reports provide recommendations for reducing employee exposure and for medical surveillance in the workplace. The recommendations in these reports are generally applicable to the use of any chemical in the workplace and you are strongly urged to review both of these reports. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: liquid at 68 F(20℃)(1,013.00 hPa(1,013 hPa)) Odour: conforms to standard Flash point: 273°F(134℃) Boiling point: 554.72 °F(290.40 ℃) at 1,013.00 hPa(1,013 hPa) Note:Calculated Vapour pressure: 00 hPa(0.00233 hPa) at 73 F(23 ℃) Method:Purge & Trap Relative density: Not determined Solubility(ies): 0.9611-0.9670 Method:ISO 279 Water solubility: 0.00268 g/l at 68 F(20 ℃) Method:OECD Test Guideline 105 Partition coefficient: n-octanol/water :log Pow:5.650 Section 10. Stability and reactivity 10.1 Conditions to avoid: Remarks:Direct sources of heat. 10.2 Chemical stability: Remarks:Presents no significant reactivity hazard,by itself or in contact with water.Avoid contact with strong acids,alkali or oxidizing agents. 10.3 Hazardous decomposition products: Note:Carbon monoxide and unidentified organic compounds may be formed during combustion. Section 11. Toxicological information 11.1 Information on toxicological effects Acute oral toxicity (Component) Component;68155-66-8 LD50 Rat Dose:>5,000 mg/kg Method:OECD Test Guideline 401 Remarks:IFF Acute dermal toxicity(Component) Component:68155-66-8 LD50 Rat Dose:>5,000 mg/kg