RESOL 011 Accelerator

SECTION 2: Hazards identification

CLASSIFICATION AND LABELLING ACCORDING TO NOHSC CODES

2.1 Classification of the substance or mixture

SYMBOL FLAMABLE / F / SYMBOL HARMFUL Xn / IRRITANT Xi GOVERNING DIRECTIVE : National Code of practice for the Labelling of Hazardous Substances. Leaks of gas or spills of liquid can readily form flammable mixtures at temperatures at or above flash point.

Hazard pictograms

Xi Irritant Xn Harmful N Dangerous for the environment

Hazard statements

R11 Highly flammable. R18 In use, may form flammable/explosive vapor-air mixture. R20/2122 Harmful by inhalation, in contact with skin and if swallowed. R33 Danger of cumulative effects. R36/37/38 Irritating to eyes, respiratory system and skin. R40 Limited evidence of carcinogenic effect. R42/43 May cause sensitisation by inhalation and skin contact. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. R61 May cause harm to the unborn child. R62 Possible risk of impaired fertility. R65 May cause lung damage if swallowed. R67 Vapors may cause drowsiness and dizziness.

Precautionary statements

S2 Keep out of the reach of children. S3/7/9 Keep container tightly closed in a cool, well ventilated place. S16 Keep away from sources of ignition - No smoking. S20/21 When using, do not eat, drink or smoke. S23 Do not breathe fumes/vapour/spray S24/25 Avoid contact with skin and eyes. S29 Do not empty into drains. S33 Take precautionary measures against static discharges. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S43B In case of fire use sand, earth, chemical powder or alcohol type foam S45 In case of accident or if you feel unwell, seek medical advice immediately. (Show label or MSDS where possible). S51 Use only in well ventilated areas. S61 Avoid release into the environment. S62 If swallowed, do NOT induce vomiting. 2. - continued

Potential health effects

ACUTE EXPOSURE No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. The following acute (short term) health effects may occur immediately or shortly after exposure to this product : High vapor concentrations are irritating to the eyes, nose, mouth, and throat, mucous membranes and the respiratory tract, may cause sore throat, insomnia coughing, headaches, tiredness, dizziness, a burning sensation to the eyes, blurred vision, mental sluggishness, lethargy, weakness, tremor, nausea and vomiting, unconsciousness, are anaesthetic and may have other central nervous system effects. Very high levels can cause death. Gastroenteritis, heartburn and intestinal pain, diarrhoea, loss of appetite and anorexia, may also occur. Acute exposure may also result in narcosis, pulmonary oedema and severe kidney and liver damage. Narcotic effects can occur at levels below the exposure standard. Exposure to very high concentrations can be fatal. If a large amount (>1 ml/kg) is ingested and retained can cause gastrointestinal irritation, kidney damage, symptoms of CNS depression and irritation occur and include weakness, dizziness, unconsciousness and convulsions. Systemic effects from short-term high exposures may include lung, kidney and brain damage. Tolerance is reported to be acquired over the work week and lost over the weekend. It is readily absorbed by the skin. Prolonged, repeated skin contact with low viscosity materials may de-fat the skin resulting in possible irritation and dermatitis. Breathing air which contains solvents, resulting from its use in spraying applications, may cause delayed lung damage. Corneal damage may occur after prolonged contact. TARGET ORGANS Eyes, skin, respiratory system, central nervous system, mucous membranes, G.I. tract, blood, reproductive system, liver and kidneys. - ACUTE EXPOSURE (continued) SKIN Will have a degreasing action on the skin. Product is a skin irritant. Frequent or prolonged contact with the skin may cause severe irritation with itching and local redness and may de-fat and dry the skin, leading to discomfort, irritant contact dermatitis and possible tissue destruction. Substance is readily absorbed through skin and may cause central nervous system depression. Toxic effects may result from skin absorption. Absorption by skin may readily exceed vapour inhalation exposure. Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous membranes may also contribute to overall exposure and may also invalidate the exposure standard. Capable of causing skin sensitisation and allergic skin reactions. The material may accentuate any pre-existing skin condition. Bare unprotected skin, abraded or irritated skin, open cuts and etc., should not be exposed to this material. INHALED This product is a central nervous system depressant. CNS depression characterised by dizziness and headache. Vapor/mist concentrations above recommended exposure levels are extremely irritating to the eyes, mucous membranes, lungs and the upper respiratory tract. Symptoms of exposure may include restlessness, headache, vomiting, stupor, low blood pressure and rapid and irregular pulse, eye and throat irritation, weakness of the legs, dizziness and light-headedness. Acute effects from inhalation of high concentrations of vapour may be dryness of the mouth and throat, nasal irritation (experienced as discomfort and discharge), coughing and sneezing, gastrointestinal disturbances (e.g. nausea, anorexia and flatulence), pulmonary irritation, nausea, vomiting, central nervous system depression (characterized by headache and dizziness, increased reaction time, fatigue, irritability, impaired judgement, lassitude, loss of co-ordination, uncoordinated movements, slurred speech, drowsiness, mental confusion), and if exposure is prolonged in extreme cases, unconsciousness even coma and possible death. . Inhalation hazard is increased at higher temperatures. Toxic effects are increased by consumption of alcohol. Repeated exposure may cause sensitisation and/or allergic reactions. Central nervous system (CNS) depression may be evident early. Serious poisonings may result in respiratory depression and may be fatal. Aspiration of liquid into lungs can cause serious (even fatal) pneumonitis. Significant exposure to this chemical may adversely affect people with chronic disease of the respiratory system, skin and/or eyes. 2. - continued - ACUTE EXPOSURE (continued) - CHRONIC EXPOSURE Principal routes of exposure are usually by accidental skin and eye contact contact/absorption and inhalation of vapours especially at higher temperatures. Chronic (long term) health effects can occur at some time after exposure to chemicals and can last for months or years. Symptoms of chronic exposure may include weakness, loss of appetite, burning eyes, stomach-ache, nausea, vomiting, sore throat, tiredness, insomnia, heart burn, intestinal pain, slightly enlarged liver, colitis, and dermatitis. The vapours may cause smarting of the eyes and respiratory tract. Can be absorbed through the skin with resultant toxic effects. Capable of causing skin sensitisation and allergic skin reactions. Skin contact may aggravate an existing dermatitis. Inhalation of material may aggravate asthma and inflammatory or fibrotic pulmonary diseases. Prolonged or continuous skin contact with the liquid may cause de-fatting with drying, cracking, irritation and dermatitis following. Evidence from animal tests indicate that repeated or prolonged solvent inhalation exposures could result in kidney disorders, nervous system impairment, liver and blood changes. [PATTYS]. Experiments with rats have shown nerve changes characteristic of neuropathy (disease of the peripheral nerves usually causing weakness and numbness). Animal studies show that repeated exposure to this material can produce embryotoxic and teratogenic effects, and adverse effects on male reproductive organs and blood cells. This chemical has not been adequately evaluated to determine whether brain or other nerve damage could occur with repeated exposure. However, many solvents and other petroleum based chemicals have been shown to cause such damage. Effects may include reduced memory and concentration, personality changes (withdrawal, irritability), fatigue, sleep disturbances, reduced co-ordination, and/or effects on nerves supplying internal organs (autonomic nerves) and/or nerves to the arms and legs (weakness, "pins and needles"). MIXED EXPOSURES Because smoking can cause heart disease, as well as lung cancer, emphysema, and other respiratory problems, it may worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will reduce your risk of developing health problems. Because more than light alcohol consumption can cause liver damage, drinking alcohol can increase the liver damage caused by liquid hydrocarbons.

Medical Conditions Generally Aggravated by Exposure

Skin disorders, damaged skin, respiratory system disease, kidney, liver, or blood disorders. ROUTES OF ENTRY : Ingestion, inhalation, skin contact, eye contact, absorption SWALLOWED Considered an unlikely route of entry in commercial/industrial environments. The liquid is highly irritating and toxic if swallowed. Ingestion may result in irritation of the mouth, throat, the gastro-intestinal tract. May be harmful and cause corrosion and damage of the gastrointestinal tract if swallowed in large quantity. Tends to break into a foam if the patient vomits. Ingestion of small quantities can result in headache, weakness, dizziness, drowsiness, pain, nausea, cramps, abdominal pain, vomiting, diarrhoea and central nervous system depression. Ingestion in large quantities may lead to unconsciousness and is expected to cause central nervous system depression and severe poisoning and may lead to kidney injury. Small amounts of liquid aspirated into respiratory system during ingestion or from vomiting may cause potentially lethal pulmonary oedema. If the victim is uncoordinated there is a greater likelihood of vomit entering the lungs and causing subsequent complications. EYE The vapour and the liquid are both severe eye irritants if exposure is prolonged. The liquid is highly irritating to the eyes and is capable of causing temporary discomfort or pain (experienced as excess blinking and tear production) with mild redness of the conjunctiva (similar to wind burn), temporary impairment of vision and other transient eye damage/ulceration. The liquid is capable of causing corneal damage with loss of sight if not promptly and adequately treated. At concentrations of 100 - 200 ppm, the vapour may irritate the eyes and respiratory tract. More marked irritation at higher concentrations. 2. - continued