Resin Solution, Flammable

SECTION 2: Hazards identification

CLASSIFICATION AND LABELLING ACCORDING TO NOHSC CODES

2.1 Classification of the substance or mixture

SYMBOL FLAMABLE / F / SYMBOL HARMFUL GOVERNING DIRECTIVE : National Code of practice for the Labelling of Hazardous Substances. CLASSIFIED AS DANGEROUS GOODS ACCORDING TO THE CRITERIA OF THE ADG CODE Leaks of gas or spills of liquid can readily form flammable mixtures at temperatures at or above flash point.

Hazard pictograms

Xi Irritant Xn Harmful N Dangerous for the environment

Hazard statements

R11 Highly flammable. R18 In use, may form flammable/explosive vapor-air mixture. R20/2122 Harmful by inhalation, in contact with skin and if swallowed. R33 Danger of cumulative effects. R36/37/38 Irritating to eyes, respiratory system and skin. R40 Limited evidence of carcinogenic effect. R42/43 May cause sensitisation by inhalation and skin contact. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. R61 May cause harm to the unborn child. R62 Possible risk of impaired fertility. R65 May cause lung damage if swallowed. R67 Vapors may cause drowsiness and dizziness.

Precautionary statements

S02 Keep out of the reach of children. S3/7/9 Keep container tightly closed in a cool, well ventilated place. S16 Keep away from sources of ignition - No smoking. S20/21 When using, do not eat, drink or smoke. S23 Do not breathe fumes/vapour/spray S24/25 Avoid contact with skin and eyes. S29 Do not empty into drains. S33 Take precautionary measures against static discharges. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S43B In case of fire use sand, earth, chemical powder or alcohol type foam S45 In case of accident or if you feel unwell, seek medical advice immediately. (Show label or MSDS where possible). S51 Use only in well ventilated areas. S61 Avoid release into the environment. S62 If swallowed, do NOT induce vomiting. 2.

Potential health effects

ACUTE EXPOSURE The following acute (short term) health effects may occur immediately or shortly after exposure to this product: High vapor concentrations are irritating to the eyes and the respiratory tract, may cause coughing, headaches and dizziness, are anaesthetic and may have other central nervous system effects. Very high levels can cause death. Narcotic effects occur at levels below the exposure standard. If a large amount ( > 1 ml/kg) is ingested and retained, symptoms of CNS depression and irritation occur and include weakness, dizziness, unconsciousness and convulsions. TARGET ORGANS : Central nervous system, eyes, skin, gastro-intestinal tract, blood, liver and kidneys - CHRONIC EXPOSURE Principal routes of exposure are usually by skin contact/absorption and inhalation of vapour. Chronic (long term) health effects can occur at some time after exposure to liquid hydrocarbons and can last for months or years. Evidence from animal tests indicate that repeated or prolonged solvent inhalation exposures could result in kidney disorders, nervous system impairment, liver and blood changes. [PATTYS]. Repeated exposure to this product can cause poor memory, difficulty in concentration and other brain effects. SKIN : Prolonged or repeated skin contact causes severe irritation and may lead to de-fatting and dermatitis. Capable of causing skin sensitisation and allergic skin reactions. MIXED EXPOSURES Because smoking can cause heart disease, as well as lung cancer, emphysema, and other respiratory problems, it may worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will reduce your risk of developing health problems. Because more than light alcohol consumption can cause liver damage, drinking alcohol can increase the liver damage caused by liquid hydrocarbons.

Medical Conditions Generally Aggravated by Exposure

None identified ROUTES OF ENTRY : Ingestion, inhalation, skin contact, eye contact, absorption SWALLOWED Considered an unlikely route of entry in commercial/industrial environments. The liquid is irritating and may be toxic if swallowed. Tends to break into a foam if the patient vomits. Ingestion can result in nausea, cramps, pain, vomiting, diarrhoea and central nervous system depression. Small amounts of liquid aspirated into respiratory system during ingestion or from vomiting may cause broncho-pneumonia or pulmonary oedema. If the victim is uncoordinated there is a greater likelihood of vomit entering the lungs and causing subsequent complications. EYE The vapour and the liquid are both severe eye irritants if exposure is prolonged. The liquid is capable of causing severe damage with loss of sight if not promptly and adequately treated. Corneal changes have been reported in furniture polishers exposed to xylene. SKIN Contact with the skin may result in severe irritation and drying of the skin which may lead to dermatitis if contact is prolonged. Toxic effects may result from skin absorption. Capable of causing skin sensitisation and allergic skin reactions. Open cuts, abraded or irritated skin should not be exposed to this material. The material may accentuate any pre-existing skin condition. 2. - continued INHALED This product is a central nervous system depressant. CNS depression characterised by dizziness and headache. Vapor/mist is extremely irritating to mucous membranes, upper respiratory tract and lungs. Inhalation hazard is increased at higher temperatures. Toxic effects are increased by consumption of alcohol. Repeated exposure may cause sensitisation and/or allergic reactions. Acute effects from inhalation of high concentrations of vapour are pulmonary irritation, including coughing, with nausea; central nervous system depression - characterized by headache, dizziness, increased reaction time, loss or co-ordination, fatigue, lassitude, irritability and gastrointestinal disturbances (e.g. nausea, anorexia and flatulence). If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death. Volunteers inhaling xylene at 100 ppm for 5 to 6 hours showed changes in manual co-ordination, reaction time and slight ataxia. Tolerance developed during the work week but was lost over the weekend. Physical exercise may antagonize this effect. Xylene body burden in humans exposed to 100 or 200 ppm xylene in air depends on the amount of body fat with 4% to 8% of total absorbed xylene accumulating in human adipose tissues.