TWIST SC500

Bayer (Pty) Ltd

Revision date : 2016-02-26

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GHS09
Health risk rating 4
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

2634-33-5

Name of the chemical

1,2-Benzisothiazol-3(2H)-one

Concentration

>0,005

EC/CAS

55965-84-9

Name of the chemical

Mixture of 5-chloro-2-methyl-2H- isothiazol-3-one (EINECS 247-500-7) and 2-methyl-2H-isothiazol-3-one (EINECS 220-239-6)

Concentration

>0,0002

General Information

Version

2 / ZA

Revision date

2016-02-26

Product name

TWIST SC500

1.2.1 Relevant identified uses

Fungicide

supplier name

Bayer (Pty) Ltd

Emergency telephone

+27 (0861) 555 777, +1 (760) 476 3964

Icons in SDS

GHS09 M004 M009 M010 M011

Company Information

company name

Bayer (Pty) Ltd

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H400, H410

Hazard statements

Code

Statements

H400

Very toxic to aquatic life

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture Globally Harmonised System of Classification and Labelling of Chemicals (GHS) Acute aquatic toxicity: Category 1 H400 Very toxic to aquatic life Chronic aquatic toxicity: Category 1 H410 Very toxic to aquatic life with long lasting effects

Hazardous Ingredients

• Trifloxystrobin

Hazard statements

H410 Very toxic to aquatic life with long lasting effects. EUH208

Contains

Trifloxystrobin, 1,2-benzisothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one. May produce an allergic reaction. EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P501 Dispose of contents/container in accordance with local regulation.

2.3 Other hazards

No other hazards known.

2.1 Classification of the substance or mixture

Globally Harmonised System of Classification and Labelling of Chemicals (GHS) Acute aquatic toxicity: Category 1 H400 Very toxic to aquatic life. Chronic aquatic toxicity: Category 1 H410 Very toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Hazard label for supply/use required. Hazardous components which must be listed on the label: • Trifloxystrobin Signal word: Warning Hazard statements H410 Very toxic to aquatic life with long lasting effects. EUH208 Contains Trifloxystrobin, 1,2-benzisothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one. May produce an allergic reaction. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P501 Dispose of contents/container in accordance with local regulation. 2.3 Other hazards No other hazards known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Chemical nature Suspension concentrate (=flowable concentrate)(SC) Trifloxystrobin, 500 g/l Hazardous components Hazard statements according to Regulation (EC) No. 1272/2008 Name CAS-No. / Classification Conc. [%] EC-No. / Regulation (EC) No REACH Reg. No. 1272/2008 Trifloxystrobin 141517-21-7 Skin Sens. 1, H317 43,7 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 1,2-Benzisothiazol-3(2H)- 2634-33-5 Acute Tox. 4, H302 > 0,005 – < one Skin Irrit. 2, H315 0,05 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Acute 1, H400 Mixture of: 55965-84-9 Acute Tox. 3, H331 > 0,0002 – < 5-chloro-2-methyl-4-isothi Acute Tox. 3, H311 0,0015 azolin-3-one and Acute Tox. 3, H301 2-methyl-4-isothiazolin-3- Skin Sens. 1, H317 one Skin Corr. 1B, H314 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Further information Trifloxystrobin 141517-21-7 M-Factor: 100 (acute) For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures General advice Remove contaminated clothing immediately and dispose of safely. Move out of dangerous area. Place and transport victim in stable position (lying sideways). Inhalation Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately. Skin contact Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists. Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth. 4.2 Most important symptoms and effects, both acute and delayed Symptoms No symptoms known or expected. 4.3 Indication of any immediate medical attention and special treatment needed Treatment Treat symptomatically. Gastric lavage is not normally required. However, if a significant amount (more than a mouthful) has been ingested, administer activated charcoal and sodium sulphate. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable High volume water jet 5.2 Special hazards arising In the event of fire the following may be released:, Hydrogen cyanide from the substance or (hydrocyanic acid), Carbon monoxide (CO), Nitrogen oxides (NOx), mixture Hydrogen fluoride 5.3 Advice for firefighters Special protective In the event of fire, wear self-contained breathing apparatus. In the equipment for firefighters event of fire and/or explosion do not breathe fumes. Further information Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Precautions Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment.

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