PROSPER TRIO EC460

Hazard statements (CLP)

H302, H302+H332, H314, H332, H335, H360, H362, H373, H400, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazardous Ingredients

• Spiroxamine • Tebuconazole • Triadimenol • N,N-Dimethyl decanamide

Signal word

Danger

Hazard statements

H302 + H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H360 May damage fertility or the unborn child. H362 May cause harm to breast-fed children. H373 May cause damage to organs (Eye) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Restricted to professional users. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. EUH208

Contains

Spiroxamine. May produce an allergic reaction

Precautionary statements

P201 Obtain special instructions before use. P263 Avoid contact during pregnancy/ while nursing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of water/ soap. P337 + P313 If eye irritation persists: Get medical advice/ attention. P312 Call a POISON CENTER/doctor/physician if you feel unwell. P501 Dispose of contents/container in accordance with local regulation.

2.3 Other hazards

No other hazards known.

2.1 Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Acute toxicity: Category 4 H302 Harmful if swallowed. Acute toxicity: Category 4 H332 Harmful if inhaled. Skin corrosion: Category 1B H314 Causes severe skin burns and eye damage. Specific target organ toxicity - single exposure: Category 3 H335 May cause respiratory irritation. Reproductive toxicity: Category 1B H360 May damage fertility or the unborn child. Effects on or via lactation H362 May cause harm to breast-fed children. Specific target organ toxicity - repeated exposure: Category 2 H373 May cause damage to organs (Eye) through prolonged or repeated exposure. Acute aquatic toxicity: Category 1 H400 Very toxic to aquatic life. Chronic aquatic toxicity: Category 1 H410 Very toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Hazard label for supply/use required. Hazardous components which must be listed on the label: • Spiroxamine • Tebuconazole • Triadimenol • N,N-Dimethyl decanamide Signal word: Danger Hazard statements H302 + H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H360 May damage fertility or the unborn child. H362 May cause harm to breast-fed children. H373 May cause damage to organs (Eye) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Restricted to professional users. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. EUH208 Contains Spiroxamine. May produce an allergic reaction. Precautionary statements P201 Obtain special instructions before use. P263 Avoid contact during pregnancy/ while nursing. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of water/ soap. P337 + P313 If eye irritation persists: Get medical advice/ attention. P312 Call a POISON CENTER/doctor/physician if you feel unwell. P501 Dispose of contents/container in accordance with local regulation. 2.3 Other hazards No other hazards known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Chemical nature Emulsifiable concentrate (EC) Spiroxamine 250 g/l, Tebuconazole 167 g/l, Triadimenol 43 g/l Hazardous components Hazard statements according to Regulation (EC) No. 1272/2008 Name CAS-No. / Classification Conc. [%] EC-No. / REGULATION (EC) No REACH Reg. No. 1272/2008 Spiroxamine 118134-30-8 Acute Tox. 4, H302 25,2 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Irrit. 2, H315 Skin Sens. 1, H317 STOT RE 2, H373 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Tebuconazole 107534-96-3 Acute Tox. 4, H302 16,8 Repr. 2, H361d Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Triadimenol 55219-65-3 Acute Tox. 4, H302 4,3 Repr. 1B, H360 Lact., H362 Aquatic Chronic 2, H411 gamma-Butyrolactone 96-48-0 Acute Tox. 4, H302 > 1 – < 15 Eye Dam. 1, H318 STOT SE 3, H336 N,N-Dimethyl decanamide 14433-76-2 Skin Irrit. 2, H315 > 20 Eye Irrit. 2, H319 STOT SE 3, H335 Aquatic Chronic 3, H412 Alkylarylpolyglycol ether 104376-75-2 Aquatic Chronic 3, H412 > 1 – < 25 Further information Spiroxamine 118134-30-8 M-Factor: 100 (acute), 100 (chronic) Tebuconazole 107534-96-3 M-Factor: 1 (acute), 10 (chronic) For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures General advice Remove contaminated clothing immediately and dispose of safely. Move out of dangerous area. Place and transport victim in stable position (lying sideways). Inhalation Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately. Skin contact Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Call a physician or poison control center immediately. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth. 4.2 Most important symptoms and effects, both acute and delayed Symptoms No symptoms known or expected. 4.3 Indication of any immediate medical attention and special treatment needed Treatment Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable High volume water jet 5.2 Special hazards arising In the event of fire the following may be released:, Hydrogen cyanide from the substance or (hydrocyanic acid), Carbon monoxide (CO), Hydrogen chloride (HCl), mixture Nitrogen oxides (NOx) 5.3 Advice for firefighters Special protective In the event of fire and/or explosion do not breathe fumes. In the event of equipment for firefighters fire, wear self-contained breathing apparatus. Further information Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Precautions Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. 6.2 Environmental Do not allow to get into surface water, drains and ground water. precautions 6.3 Methods and materials for containment and cleaning up Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations. 6.4 Reference to other Information regarding safe handling, see section 7. sections Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Advice on safe handling Use only in area provided with appropriate exhaust ventilation. Advice on protection against No special precautions required. fire and explosion Hygiene measures