BCS-CL73507 SC 200 G

Hazard statements (CLP)

H400, H410

Code

Statements

H400

Very toxic to aquatic life

SECTION 2: Hazards identification

Classification According to Directive 67/548/EEC or 1999/45/EC: Classification of the substance or mixture

Hazardous Ingredients

• Tetraniliprole • 1,2-Benzisothiazol-3(2H)-one • Mixture of 5-Chlor-2-methyl-3(2H)-isothiazolon and 2-Methyl-2H-isothiazol-3-on

Hazard statements

H410 Very toxic to aquatic life with long lasting effects. EUH208

Contains

1,2-Benzisothiazolin-3-one, 5-chloro-2-methyl-isothiazol-3-one/2-methyl- isothiazol-3-one. May produce an allergic reaction. EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Precautionary statements

P501 Dispose of contents/container in accordance with local regulation.

2.3 Other hazards

No other hazards known.

2.1 Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Acute aquatic toxicity: Category 1 H400 Very toxic to aquatic life. Chronic aquatic toxicity: Category 1 H410 Very toxic to aquatic life with long lasting effects. Classification according to EU Directives 67/548/EEC or 1999/45/EC N Dangerous for the environment, R50/53 2.2 Label elements Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Hazard label for supply/use required. Hazardous components which must be listed on the label: • Tetraniliprole • 1,2-Benzisothiazol-3(2H)-one • Mixture of 5-Chlor-2-methyl-3(2H)-isothiazolon and 2-Methyl-2H-isothiazol-3-on Signal word: Warning Hazard statements H410 Very toxic to aquatic life with long lasting effects. EUH208 Contains 1,2-Benzisothiazolin-3-one, 5-chloro-2-methyl-isothiazol-3-one/2-methyl- isothiazol-3-one. May produce an allergic reaction. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Precautionary statements P501 Dispose of contents/container in accordance with local regulation. 2.3 Other hazards No other hazards known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Chemical nature Suspension concentrate (=flowable concentrate)(SC) Tetraniliprole 200 g/l Hazardous components R-phrase(s) according to EC directive 67/548/EEC Hazard statements according to Regulation (EC) No. 1907/2006 Name CAS-No. / Classification Conc. [%] EC-No. EC Directive Regulation (EC) No 67/548/EEC 1272/2008 Tetraniliprole 1229654-66- R43 Skin Sens. 1, H317 18,20 3 N; R50/53 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 1,2-Benzisothiazol- 2634-33-5 Xn; R22 Acute Tox. 4, H302 > 0,005 – 3(2H)-one 220-120-9 Xi; R38, R41 Skin Irrit. 2, H315 < 0,05 R43 Eye Dam. 1, H318 N; R50 Skin Sens. 1, H317 Aquatic Acute 1, H400 Mixture of 5-Chlor- 55965-84-9 T; R23/24/25 Acute Tox. 3, H331 > 0,0002 – 2-methyl-3(2H)- C; R34 Acute Tox. 3, H311 < 0,0015 isothiazolon and 2- R43 Acute Tox. 3, H301 Methyl-2H- N; R50/53 Skin Corr. 1B, H314 isothiazol-3-on Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Glycerine 56-81-5 Not classified > 1,00 200-289-5 Further information Substances which do not meet the classification criteria according to Directive 67/548/EEC as amended: Glycerine (56-81-5): Substance with an EU indicative Occupational Exposure Limit value (OEL) below the threshold value for reporting. For the full text of the R-phrases/ Hazard statements mentioned in this Section, see Section 16. SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures General advice Move out of dangerous area. Place and transport victim in stable position (lying sideways). Remove contaminated clothing immediately and dispose of safely. Inhalation Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately. Skin contact Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Ingestion Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately. 4.2 Most important symptoms and effects, both acute and delayed Symptoms No symptoms known or expected. 4.3 Indication of any immediate medical attention and special treatment needed Treatment Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable Water spray, Carbon dioxide (CO2), Foam, Sand 5.2 Special hazards arising In the event of fire the following may be released:, Hydrogen chloride from the substance or (HCl), Hydrogen cyanide (hydrocyanic acid), Hydrogen fluoride, mixture Carbon monoxide (CO), Nitrogen oxides (NOx) 5.3 Advice for firefighters Special protective In the event of fire and/or explosion do not breathe fumes. In the event equipment for fire-fighters of fire, wear self-contained breathing apparatus. Further information Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Precautions Avoid contact with spilled product or contaminated surfaces. Use