ANTRACOL WP 70

Hazard statements (CLP)

H317, H332, H373, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazardous Ingredients

• Propineb

Hazard statements

H332 Harmful if inhaled. H317 May cause an allergic skin reaction. H373 May cause damage to organs (Thyroid, Peripheral nervous system) through prolonged or repeated exposure if inhaled or swallowed. H411 Toxic to aquatic life with long lasting effects. EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Precautionary statements

P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P314 Get medical advice/ attention if you feel unwell. P501 Dispose of contents/container as hazardous waste to an approved waste disposal plant.

2.3 Other hazards

Dust may form explosive mixture in air.

2.1 Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Acute toxicity: Category 4 H332 Harmful if inhaled. Skin sensitisation: Category 1 H317 May cause an allergic skin reaction. Specific target organ toxicity - repeated exposure: Category 2 H373 May cause damage to organs (Thyroid, Peripheral nervous system) through prolonged or repeated exposure if inhaled or swallowed. Chronic aquatic toxicity: Category 2 H411 Toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended. Labelling according to EC Directives Hazardous components which must be listed on the label: • Propineb Signal word: Warning Hazard statements H332 Harmful if inhaled. H317 May cause an allergic skin reaction. H373 May cause damage to organs (Thyroid, Peripheral nervous system) through prolonged or repeated exposure if inhaled or swallowed. H411 Toxic to aquatic life with long lasting effects. EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Precautionary statements P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P314 Get medical advice/ attention if you feel unwell. P501 Dispose of contents/container as hazardous waste to an approved waste disposal plant. 2.3 Other hazards Dust may form explosive mixture in air. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures Chemical nature Wettable powder (WP) Propineb 700g/kg Hazardous components Hazard statements according to Regulation (EC) No. 1272/2008 Name CAS-No. / Classification Conc. [%] EC-No. / Regulation (EC) No REACH Reg. No. 1272/2008 Propineb 9016-72-2 Skin Sens. 1, H317 70 STOT RE 2, H373 Acute Tox. 4, H332 Aquatic Acute 1, H400 Methenamine 100-97-0 Flam. Sol. 2, H228 0,7 Skin Sens. 1, H317 Further information For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures Inhalation Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately. Skin contact Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists. Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately. Rinse mouth. 4.2 Most important symptoms and effects, both acute and delayed Symptoms Symptoms reinforced by alcohol (Antabuse effect) 4.3 Indication of any immediate medical attention and special treatment needed Treatment Treat symptomatically. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. Follow-up measures: Strict abstinence from alcohol for 1 to 2 weeks, due to antabuse effect. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable Water spray, Carbon dioxide (CO2), Foam, Sand 5.2 Special hazards arising In the event of fire the following may be released:, Hydrogen cyanide from the substance or (hydrocyanic acid), Carbon monoxide (CO), Nitrogen oxides (NOx), mixture Sulphur oxides 5.3 Advice for firefighters Special protective In the event of fire, wear self-contained breathing apparatus. equipment for firefighters Further information Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Precautions Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment. 6.2 Environmental Do not allow to get into surface water, drains and ground water. precautions 6.3 Methods and materials for containment and cleaning up Methods for cleaning up Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal. 6.4 Reference to other Information regarding personal protective equipment, see section 8. sections Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Advice on safe handling Use only in area provided with appropriate exhaust ventilation. Advice on protection against Keep away from heat and sources of ignition. Dust may form explosive fire and explosion mixture in air. Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands immediately after work, if necessary take a shower. Remove soiled clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt). 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage Keep containers tightly closed in a dry, cool and well-ventilated place. areas and containers Store in original container. Store in a place accessible by authorized persons only. Advice on common storage Keep away from food, drink and animal feedingstuffs. 7.3 Specific end use(s) Refer to the label and/or leaflet. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Components CAS-No. Control parameters Update Basis Propineb 9016-72-2 0,2 mg/m3 OES BCS* (SK-SEN)