US-600M

BASF SE

Revision date : 2025-06-10

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GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

(W/W) >= 50 % - < 75 %

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

(W/W) >= 20 % - < 25 %

EC/CAS

247-714-0/26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

(W/W) >= 15 % - < 20 %

General Information

Version

2.0

Revision date

2025-06-10

Product name

US-600M

1.2.1 Relevant identified uses

polyurethane component, industrial chemicals

Emergency telephone

+49 180 2273-112

Icons in SDS

GHS08 M004 M009 M010 M011 M017

Company Information

company name

BASF SE

e-mail address of the competent person responsible for the Safety Data Sheet

pss.monomers@basf.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture According to UN GHS criteria Acute Tox. 4 (Inhalation - mist) Skin Irrit. 2 Eye Irrit. 2A Resp. Sens. 1 Skin Sens. 1B Carc. 2 STOT SE 3 (irritating to respiratory system) STOT RE (Olfactory organs) 2 (by inhalation) For the classifications not written out in full in this section the full text can be found in section 16

2.2 Label elements

Globally Harmonized System (GHS)

Signal word

Danger

Hazard statements

H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).

Prevention

P280 Wear protective gloves, protective clothing and eye protection or face protection. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash contaminated body parts thoroughly after handling.

Response

P312 Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P313 IF exposed or concerned: Get medical attention. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P337 + P313 If eye irritation persists: Get medical attention. P362 + P364 Take off contaminated clothing and wash it before reuse.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

(Disposal) P501 Dispose of contents and container to hazardous or special waste collection point. Labeling of special preparations (GHS) Contains isocyanates. May produce an allergic reaction.

2.3 Other hazards

According to UN GHS criteria The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Avoid any contact with the substance in case of known allergy to isocyanates, skin complaints, hypersensitivity reactions, chronic respiratory disease, asthmatic attacks or bronchial attacks

2.1 Classification of the substance or mixture

According to UN GHS criteria Acute Tox. 4 (Inhalation - mist) Skin Irrit. 2 Eye Irrit. 2A Resp. Sens. 1 Skin Sens. 1B Carc. 2 STOT SE 3 (irritating to respiratory system) STOT RE (Olfactory organs) 2 (by inhalation) For the classifications not written out in full in this section the full text can be found in section 16.

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