TOCATA

Hazard statements (CLP)

H315, H317, H319, H351, H360Df, H410

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

1999/45/EC According to Regulation (EC) No 1272/2008 [CLP] Skin Corr./Irrit. 2 Carc. Cat. 3 Use Repr. Cat. 2 Eye Dam./Irrit. 2 Skin Sens. 1 by Carc. 2 Aquatic Chronic 2 According to Directive 67/548/EEC or 1999/45/EC Repr. Cat. 3 Irritating to skin. May cause sensitization by skin contact. Limited evidence of a carcinogenic effect. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause harm to the unborn child. For the classifications not written out in full in this section the full text can be found in section 16.

2.2 Label elements

Globally Harmonized System (GHS) in accordance with IE regulations.

Signal word

Danger

Hazard statements

H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H410 Very toxic to aquatic life with long lasting effects. H360Df May damage the unborn child. Suspected of damaging fertility. EUH401 To avoid risks to human health and the environment, comply with the instructions for use.

Prevention

P261 Avoid breathing mist. P202 Do not handle until all safety precautions have been read and understood. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash contaminated body parts thoroughly after handling. P280 Wear protective gloves/clothing/eye protection.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact - 2020 lenses, if present and easy to do. Continue rinsing. P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P303 + P352 IF ON SKIN (on hair): Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.

Storage

31 P332 + P313 If skin irritation occurs: Get medical advice/attention. Oct P362 + P364 Take off contaminated clothing and wash before reuse. P391 Collect spillage. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. P405 Store locked up.

Precautionary statements

Disposal) P501 Dispose of contents/container to a licensed waste disposal contractor or by collection site except for triple rinsed empty containers which can be disposed of as non-hazardous waste. Labeling of special preparations (GHS): SPECIMEN May produce an allergic reaction. Contains: 1,2-BENZISOTHIAZOL-3(2H)-ONE According to Regulation (EC) No 1272/2008 [CLP]

Hazardous Ingredients

for labelling FENPROPIMORPH, EPOXICONAZOLE, Use METRAFENONE According to Directive 67/548/EEC or 1999/45/EC Classification/labelling in accordance with Irish regulations. Hazard symbol(s) N Dangerous for the environment. T Toxic.

R-phrase(s)

R38 Irritating to skin. R43 May cause sensitization by skin contact. R40 Limited evidence of a carcinogenic effect. R62 Possible risk of impaired fertility. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R61 May cause harm to the unborn child.

S-phrase(s)

S36/37 Wear suitable protective clothing and gloves. S2 Keep out of the reach of children. S13 Keep away from food, drink and animal feeding stuffs. S46 If swallowed, seek medical advice immediately and show this container or label. S35 This material and its container must be disposed of in a safe way. S57 Use appropriate container to avoid environmental contamination. Hazard determining component(s) for labelling: FENPROPIMORPH, EPOXICONAZOLE, METRAFENONE - 2020 The product contains: 1,2-BENZISOTHIAZOL-3(2H)-ONE May produce an allergic reaction.

2.3 Other hazards

According to Regulation (EC) No 1272/2008 [CLP] See section 12 – Results of PBT and vPvB assessment. If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.