TDA 95% Vicinal

BASF SE

Revision date : 2018-03-06

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GHS09 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

207-826-2/496-72-0

Name of the chemical

Toluene-3,4-Diamine and its salts, when used as a substance in hair dye products

Concentration

>= 50 % - < 75 %

EC/CAS

212-513-9/25376-45-8

Name of the chemical

Diaminotoluene

Concentration

>= 3 % - < 5 %

EC/CAS

246-910-3/95-80-7

Name of the chemical

4-methyl-m-phenylenediamine

Concentration

N/A

EC/CAS

202-453-1/823-40-5

Name of the chemical

2-Methyl-m-phenylendiamin

Concentration

N/A

EC/CAS

248-105-2/26915-12-8

Name of the chemical

Toluidines, their isomers, salts and halogenated and sulphonated derivatives

Concentration

>= 0,3 % - < 1 %

General Information

Version

1.0

Revision date

2018-03-06

Product name

TDA 95% Vicinal

Chemical name

TDA 90% VICINALS

1.2.1 Relevant identified uses

Intermediate

Emergency telephone

+49 180 2273-112

Icons in SDS

GHS08 GHS09 M004 M008 M009 M010 M011 M017

Company Information

company name

BASF SE

e-mail address of the competent person responsible for the Safety Data Sheet

pss.monomers@basf.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301, H311, H317, H319, H332, H341, H350, H361, H373, H411

Hazard statements

Code

Statements

H301

Toxic if swallowed

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture According to UN GHS criteria Acute Tox. 4 (Inhalation - vapour) Acute Tox. 3 (dermal) Acute Tox. 3 (oral) Eye Dam./Irrit. 2A Skin Sens. 1 Carc. 1B Muta. 2 Repr. 2 (fertility) STOT RE (Liver, Testes) 2 Aquatic Chronic 2 Aquatic Acute 2 For the classifications not written out in full in this section the full text can be found in section 16 Label elements Globally Harmonized System, UN (GHS) Pictogram

Signal word

Danger Hazard Statement H301 Toxic if swallowed H311 Toxic in contact with skin H317 May cause an allergic skin reaction H319 Causes serious eye irritation H332 Harmful if inhaled H341 Suspected of causing genetic defects H350 May cause cancer H361 Suspected of damaging fertility H373 May cause damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects Precautionary Statements (Prevention) P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P260 Do not breathe dust/gas/mist/vapours P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash with plenty of water and soap thoroughly after handling P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P273 Avoid release to the environment P280 Wear protective gloves/protective clothing/eye protection/face protection P281 Use personal protective equipment as required Precautionary Statements (Response) P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308 + P313 IF exposed or concerned: Get medical advice/attention P312 Call a POISON CENTER or doctor/physician if you feel unwell P314 Get medical advice/attention if you feel unwell P321 Specific treatment (see on this label) P322 Specific measures (see on this label) P330 Rinse mouth P333 + P313 If skin irritation or rash occurs: Get medical advice/attention P337 + P313 If eye irritation persists: Get medical advice/attention P361 Take off immediately all contaminated clothing P363 Wash contaminated clothing before reuse P391 Collect spillage Precautionary Statements (Storage) P405 Store locked up

Precautionary statements

(Disposal) P501 Dispose of contents/container to hazardous or special waste collection point. According to UN GHS criteria Hazard determining component(s) for labelling: 4-Methyl-o-phenylenediamine, 4-methyl-m- phenylenediamine; 2,4-toluenediamine

2.3 Other hazards

According to UN GHS criteria No specific dangers known, if the regulations/notes for storage and handling are considered.

2.1 Classification of the substance or mixture

According to UN GHS criteria Acute Tox. 4 (Inhalation - vapour) Acute Tox. 3 (dermal) Acute Tox. 3 (oral) Eye Dam./Irrit. 2A Skin Sens. 1 Carc. 1B Muta. 2 Repr. 2 (fertility) STOT RE (Liver, Testes) 2 Aquatic Chronic 2 Aquatic Acute 2 For the classifications not written out in full in this section the full text can be found in section 16.

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