Note: Ingredients listed on restricted chemical lists
EC/CAS
207-826-2/496-72-0
Name of the chemical
Toluene-3,4-Diamine and its salts, when used as a substance in hair dye products
Concentration
(W/W) >= 50 %
EC/CAS
202-453-1/95-80-7
Name of the chemical
4-methyl-m-phenylenediamine
Concentration
(W/W) <= 1 %
General Information
Version
3.0
Revision date
2025-01-14
Product name
TDA 90% Vicinal
Chemical name
1,2-Benzenediamine, ar-methyl-
1.2.1 Relevant identified uses
Chemical, Raw material
Emergency telephone
+49 180 2273-112
Icons in SDS
Company Information
company name
BASF SE
e-mail address of the competent person responsible for the Safety Data Sheet
pss.monomers@basf.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H301, H312, H317, H319, H332, H341, H350, H361, H361d, H373, H411
Hazard statements
Code
Statements
H301
Toxic if swallowed
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No 1272/2008 [CLP Classification of the substance or mixture
Signal word
Danger
Hazard statements
H301 Toxic if swallowed. H312 Harmful in contact with skin. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H361 Suspected of damaging fertility. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.
Prevention
P273 Avoid release to the environment. P280 Wear protective gloves, protective clothing and eye protection or face protection.
Response
P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage
P405 Store locked up.
Precautionary statements
(Disposal) P501 Dispose of contents and container to hazardous or special waste collection point. Labeling of special preparations (GHS) Restricted to professional users. Hazard determining component(s) for labelling: 4-Methyl-o-phenylenediamine, Toluene-2,3-diamine, 4-methyl-m-phenylenediamine
2.1 Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP] Acute Tox. 4 (Inhalation - mist) H332 Harmful if inhaled. Acute Tox. 3 (oral) H301 Toxic if swallowed. Acute Tox. 4 (dermal) H312 Harmful in contact with skin. Eye Dam./Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Muta. 2 H341 Suspected of causing genetic defects. Carc. 1B H350 May cause cancer. Repr. 2 H361f Suspected of damaging fertility. Repr. H361d Suspected of damaging the unborn child. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. For the classifications not written out in full in this section the full text can be found in section 16.
