Melapur MC15 ED

BASF SE

Revision date : 2019-02-27

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GHS08
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

253-575-7/37640-57-6

Name of the chemical

1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with 1,3,5-triazine

Concentration

100%

Listed in

General Information

Revision date

2019-02-27

Product name

Melapur MC15 ED

Chemical name

1,3,5-triazine-2,4,6(1H,3H,5H)-trione, compound with 1,3,5-triazine-2,4,6-triamine

CAS No.

37640-57-6

REACH No

01-2119510711-53-0000,

1.2.1 Relevant identified uses

flameproofing agent, polyurethane component, additive for the plastics industry Not recommended use: The product is not recommended to be used in contact with mucous membranes, abraded skin, or blood; or for the manufacture of implants for the human body as it has not been tested for these applications

Emergency telephone

+49 180 2273-112

Icons in SDS

Company Information

company name

BASF SE

e-mail address of the competent person responsible for the Safety Data Sheet

product-safety-north@basf.com

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H373

Hazard statements

Code

Statements

H373

May cause damage to organs through prolonged or repeated exposure

Section 2

2.1 Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP] STOT RE (Kidney) 2 H373 For the classifications not written out in full in this section the full text can be found in section 16.

2.2 Label elements

Globally Harmonized System, EU (GHS)

Signal word

Warning

Hazard statements

H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P260 Do not breathe dust/gas/mist/vapours.

Response

P311 Call a POISON CENTER or doctor/physician.

Precautionary statements

Disposal) P501 Dispose of contents/container to hazardous or special waste collection point. According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with 1,3,5-triazine-2,4,6-triamine (1:1)

2.3 Other hazards

According to Regulation (EC) No 1272/2008 [CLP] The product is under certain conditions capable of dust explosion.

#2_A

ddFeed Control of exposure and risk management measures Contributing exposure scenario ERC3: Formulation in materials As no environmental hazard was identified no Use descriptors covered environmental-related exposure assessment and risk characterization was performed. Operational conditions Contributing exposure scenario PROC4: Use in batch and other process (synthesis) where Use descriptors covered opportunity for exposure arises. Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 60 % Physical state Solid, low dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 480 min 5 days per week Indoor/Outdoor Indoor Risk Management Measures Local exhaust ventilation Effectiveness: 90 % Use suitable chemically resistant Effectiveness: 80 % gloves. Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, worker, modified version, Reduction factor for local exhaust ventilation Assessment method (LEV) has been used for the calculation of dermal exposure estimates., The concentration of the substance has been considered using a linear approach. Worker - dermal, long-term - systemic Exposure estimate 0.0823 mg/kg bw/day Risk Characterization Ratio (RCR) 0.004957 EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - inhalation, long-term - systemic Exposure estimate 0.03 mg/m³ Risk Characterization Ratio (RCR) 0.142857 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see exposure estimates) Contributing exposure scenario PROC5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or Use descriptors covered significant contact). Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 60 % Physical state Solid, high dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 240 min 5 days per week Indoor/Outdoor Indoor Risk Management Measures Local exhaust ventilation Effectiveness: 90 % Wear suitable respiratory protection. Effectiveness: 90 % Wear chemically resistant gloves in combination with ‘basic’ employee Effectiveness: 90 % training. Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, worker, modified version, Reduction factor for local exhaust ventilation Assessment method (LEV) has been used for the calculation of dermal exposure estimates., The concentration of the substance has been considered using a linear approach. Worker - dermal, long-term - systemic Exposure estimate 0.0823 mg/kg bw/day Risk Characterization Ratio (RCR) 0.004957 EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - inhalation, long-term - systemic Exposure estimate 0.09 mg/m³ Risk Characterization Ratio (RCR) 0.428571 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see exposure estimates) Contributing exposure scenario PROC8a: Transfer of substance or preparation (charging/discharging) from/to ves-sels/large containers at Use descriptors covered non-dedicated facilities Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 100 % Physical state Solid, high dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 240 min 5 days per week Indoor/Outdoor Indoor Risk Management Measures Local exhaust ventilation Effectiveness: 90 % Wear suitable respiratory protection. Effectiveness: 95 % Wear chemically resistant gloves in combination with specific activity Effectiveness: 95 % training Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, Worker, Reduction Assessment method factor for local exhaust ventilation (LEV) has been used for the calculation of dermal exposure estimates. Worker - dermal, long-term - systemic Exposure estimate 0.0686 mg/kg bw/day Risk Characterization Ratio (RCR) 0.004131 Assessment method EASY TRA v3.6, ECETOC TRA v3.0, Worker Worker - inhalation, long-term - systemic Exposure estimate 0.15 mg/m³ Risk Characterization Ratio (RCR) 0.714286 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Contributing exposure scenario PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at Use descriptors covered dedicated facilities Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 100 % Physical state Solid, high dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 240 min 5 days per week Indoor/Outdoor Indoor Risk Management Measures Local exhaust ventilation Effectiveness: 95 % Wear suitable respiratory protection. Effectiveness: 90 % Wear chemically resistant gloves in combination with ‘basic’ employee Effectiveness: 90 % training. Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, Worker, Reduction Assessment method factor for local exhaust ventilation (LEV) has been used for the calculation of dermal exposure estimates. Worker - dermal, long-term - systemic Exposure estimate 0.0686 mg/kg bw/day Risk Characterization Ratio (RCR) 0.004131 Assessment method EASY TRA v3.6, ECETOC TRA v3.0, Worker Worker - inhalation, long-term - systemic Exposure estimate 0.075 mg/m³ Risk Characterization Ratio (RCR) 0.357143 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Contributing exposure scenario PROC8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at Use descriptors covered dedicated facilities Exposure is considered negligible. Contributing exposure scenario PROC9: Transfer of substance or preparation into small Use descriptors covered containers (dedicated filling line, including weighing). Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 100 % Physical state Solid, high dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 240 min 5 days per week Indoor/Outdoor Indoor Risk Management Measures Local exhaust ventilation Effectiveness: 90 % Wear suitable respiratory protection. Effectiveness: 90 % Wear chemically resistant gloves in combination with ‘basic’ employee Effectiveness: 90 % training. Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, Worker, Reduction Assessment method factor for local exhaust ventilation (LEV) has been used for the calculation of dermal exposure estimates. Worker - dermal, long-term - systemic Exposure estimate 0.0686 mg/kg bw/day Risk Characterization Ratio (RCR) 0.004131 Assessment method EASY TRA v3.6, ECETOC TRA v3.0, Worker Worker - inhalation, long-term - systemic Exposure estimate 0.12 mg/m³ Risk Characterization Ratio (RCR) 0.571429 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Contributing exposure scenario PROC14: Production of preparations or articles by Use descriptors covered tabletting, compression, extrusion, pelettisation. Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 60 % Physical state Solid, low dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 480 min 5 days per week Indoor/Outdoor Indoor Risk Management Measures Wear chemically resistant gloves in combination with specific activity Effectiveness: 95 % training Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - dermal, long-term - systemic Exposure estimate 0.1029 mg/kg bw/day Risk Characterization Ratio (RCR) 0.006196 EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - inhalation, long-term - systemic Exposure estimate 0.06 mg/m³ Risk Characterization Ratio (RCR) 0.285714 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see exposure estimates) Contributing exposure scenario Use descriptors covered PROC14: Production of preparations or articles by tabletting, compression, extrusion, pelettisation. Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 25 % Physical state Solid, low dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 480 min 5 days per week Indoor/Outdoor Indoor Risk Management Measures Use suitable chemically resistant Effectiveness: 80 % gloves. Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - dermal, long-term - systemic Exposure estimate 0.1714 mg/kg bw/day Risk Characterization Ratio (RCR) 0.010327 EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - inhalation, long-term - systemic Exposure estimate 0.025 mg/m³ Risk Characterization Ratio (RCR) 0.119048 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see exposure estimates) Contributing exposure scenario PROC14: Production of preparations or articles by Use descriptors covered tabletting, compression, extrusion, pelettisation. Use domain: industrial Operational conditions 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, compound with Concentration of the substance 1,3,5-triazine-2,4,6-triamine (1:1) Content: >= 0 % - <= 8 % Physical state Solid, low dustiness Vapour pressure of the substance 0.000001 Pa during use Process temperature 20 °C Duration and Frequency of activity 480 min 5 days per week Indoor/Outdoor Indoor Exposure estimate and reference to its source EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - dermal, long-term - systemic Exposure estimate 0.2743 mg/kg bw/day Risk Characterization Ratio (RCR) 0.016523 EASY TRA v3.6, ECETOC TRA v3.0, worker, modified Assessment method version, The concentration of the substance has been considered using a linear approach. Worker - inhalation, long-term - systemic Exposure estimate 0.008 mg/m³ Risk Characterization Ratio (RCR) 0.038095 Guidance to Downstream Users For scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see exposure estimates) * * * * * * * * * * * * * * * * 2. Short title of exposure scenario Use in plastics, Direct use of additives at converter's facilities in closed process, Feeding and mixing of plastic compounds for conversion SU3; SU12; ERC5; PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC14, PROC21, PROC24; PC32 PEST

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