Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
2119457014-47
General Information
Revision date
2015-12-18
Product name
MasterSeal M 808 PART B
CAS No.
101-68-8
1.2.1 Relevant identified uses
Product for construction chemicals
Emergency telephone
+49 180 2273-112
Icons in SDS
Company Information
company name
BASF SE
e-mail address of the competent person responsible for the Safety Data Sheet
product-safety-north@basf.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP] Acute Tox. 4 (Inhalation - mist) Skin Corr./Irrit. 2 Eye Dam./Irrit. 2 Resp. Sens. 1 Skin Sens. 1 Carc. 2 STOT SE 3 (irritating to respiratory system) STOT RE (Respiratory system) 2 H319, H315, H332, H334, H317, H335, H351, H373 For the classifications not written out in full in this section the full text can be found in section 16.
2.2 Label elements
According to Regulation (EC) No 1272/2008 [CLP]
Signal word
Danger
Hazard statements
H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Respiratory system) through prolonged or repeated exposure.
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P201 Obtain special instructions before use. P261 Avoid breathing mist. P202 Do not handle until all safety precautions have been read and understood. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash with plenty of water and soap thoroughly after handling.
Response
P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/attention if you feel unwell. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Precautionary statements
Disposal) P501 Dispose of contents/container to hazardous or special waste collection point. Labeling of special preparations (GHS): EUH204: Contains isocyanates. May produce an allergic reaction. Only for professional users. According to Regulation (EC) No 1272/2008 [CLP] Hazard determining component(s) for labelling: 4,4'-Methylenediphenyl diisocyanate, oligomeric reaction products with butane-1,3-diol, 2,4'-diisocyanatodiphenylmethane, 1,1'-methylenebis(4- isocyanatobenzene) homopolymer, [(methylethylene)bis(oxy)]dipropanol and propane-1,2-diol, DIPHENYLMETHANE-4,4'-DIISOCYANATE (MDI)
2.3 Other hazards
According to Regulation (EC) No 1272/2008 [CLP] If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.