Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
(W/W) 40 % - 70 %
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
(W/W) 10 % - 30 %
General Information
Version
5.0
Revision date
2014-12-15
Product name
LUPRANATE M70L ISOCYANATE
1.2.1 Relevant identified uses
Chemical, Raw material
Emergency telephone
+49 180 2273-112
Icons in SDS
Company Information
company name
BASF SE
e-mail address of the competent person responsible for the Safety Data Sheet
pss.monomers@basf.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Directive 1999/45/EC: Classification of the substance or mixture
2.2 Label elements
Globally Harmonized System, EU (GHS)
Signal word
Danger
Hazard statements
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated inhalation exposure.
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statements
(Disposal) P501 Dispose of contents/container to hazardous or special waste collection point. Labeling of special preparations (GHS) EUH204: Contains isocyanates. May produce an allergic reaction.
R-phrase(s)
R20 R36/37/38 R40 R42/43 R48/20 Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Harmful: Danger of serious damage to health by prolonged exposure through inhalation.
S-phrase(s)
S23.3 S36/37 S45 Do not breathe vapour/spray. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
2.1 Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP] Acute Tox. 4 (Inhalation - vapour) Eye Dam./Irrit. 2 Skin Corr./Irrit. 2 STOT SE 3 (irritating to respiratory system) Skin Sens. 1 Resp. Sens. 1 Carc. 2 STOT RE 2 (Inhalation - vapour) According to Directive 67/548/EEC or 1999/45/EC Possible Hazards: Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. Harmful: Danger of serious damage to health by prolonged exposure through inhalation. For the classifications not written out in full in this section the full text can be found in section 16.