LUPRANATE 5030 ISOCYANATE

BASF SE

Revision date : 2020-12-30

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GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

905-806-4/26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

>= 95 %

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

>= 25 % - < 50 %

EC/CAS

201-114-5/78-40-0

Name of the chemical

Phosphoric acid, triethyl ester, TEP

Concentration

>= 1 % - < 3 %

Listed in

EC/CAS

247-714-0

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

General Information

Version

1.0

Revision date

2020-12-30

Product name

LUPRANATE 5030 ISOCYANATE

1.2.1 Relevant identified uses

Chemical

1.2.2. Uses advised against

Consumer spray applications, Consumer applications requiring temperartures above 40°C, Professional cleaning applications with aprotic polar solvents (meeting the IUPAC definition)

Emergency telephone

+49 180 2273-112

Icons in SDS

GHS08 M004 M008 M009 M010 M011 M017 M026

Company Information

company name

BASF SE

e-mail address of the competent person responsible for the Safety Data Sheet

pss.monomers@basf.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture According to UN GHS criteria Acute Tox. 4 (Inhalation - mist) Skin Corr./Irrit. 2 Eye Dam./Irrit. 2A Resp. Sens. 1 Skin Sens. 1B Carc. 2 STOT SE 3 (irritating to respiratory system) STOT RE (Olfactory organs) 2 (by inhalation) For the classifications not written out in full in this section the full text can be found in section 16

2.2 Label elements

Globally Harmonized System, UN (GHS)

Signal word

Danger

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated inhalation exposure.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe spray. P261 Avoid breathing spray. P264 Wash with polyethylene glycol, followed by plenty of water thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves, protective clothing and eye protection or face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection.

Response

P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P304 + P341 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical attention. P312 Call a POISON CENTER or physician if you feel unwell. P314 Get medical advice/attention if you feel unwell. P321 Specific treatment (see on this label). P332 + P313 If skin irritation occurs: Get medical attention. P333 + P313 If skin irritation or rash occurs: Get medical attention. P337 + P313 If eye irritation persists: Get medical attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P362 + P364 Take off contaminated clothing and wash it before reuse. P363 Wash contaminated clothing before reuse.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

(Disposal) P501 Dispose of contents/container in accordance with local regulations. Labeling of special preparations (GHS) Contains isocyanates. May produce an allergic reaction.

2.3 Other hazards

According to UN GHS criteria See section 12 - Results of PBT and vPvB assessment.

2.1 Classification of the substance or mixture

According to UN GHS criteria Acute Tox. 4 (Inhalation - mist) Skin Corr./Irrit. 2 Eye Dam./Irrit. 2A Resp. Sens. 1 Skin Sens. 1B Carc. 2 STOT SE 3 (irritating to respiratory system) STOT RE (Olfactory organs) 2 (by inhalation) For the classifications not written out in full in this section the full text can be found in section 16.

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