Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
Skin Corr./Irrit. 2
General Information
Version
3.0
Revision date
2017-09-29
Product name
LUPRANATE 227 ISOCYANATE
1.2.1 Relevant identified uses
Chemical, Raw material
Emergency telephone
+49 180 2273-112
Icons in SDS
Company Information
company name
BASF SE
e-mail address of the competent person responsible for the Safety Data Sheet
pss.monomers@basf.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No 1272/2008 [CLP Classification of the substance or mixture
2.2 Label elements
Globally Harmonized System, EU (GHS)
Signal word
Danger
Hazard statements
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated inhalation exposure.
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statements
(Disposal) P501 Dispose of contents/container to hazardous or special waste collection point. Labeling of special preparations (GHS): EUH204: Contains isocyanates. May produce an allergic reaction.
2.1 Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP] Acute Tox. 4 (Inhalation - mist) Eye Dam./Irrit. 2 Skin Corr./Irrit. 2 STOT SE 3 (irritating to respiratory system) Skin Sens. 1B Resp. Sens. 1 Carc. 2 STOT RE (Olfactory organs) 2 (by inhalation) H315, H317, H319, H332, H334, H335, H351, H373 For the classifications not written out in full in this section the full text can be found in section 16.