LUPRANATE 223 ISOCYANATE

BASF SE

Revision date : 2018-06-14

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GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

30 % - 60 %

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

10 % - 30 %

EC/CAS

26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

10 % - 30 %

EC/CAS

201-114-5/78-40-0

Name of the chemical

Phosphoric acid, triethyl ester, TEP

Concentration

>= 1 % - < 3 %

Listed in

EC/CAS

247-714-0

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

General Information

Version

1.0

Revision date

2018-06-14

Product name

LUPRANATE 223 ISOCYANATE

1.2.1 Relevant identified uses

Chemical

1.2.2. Uses advised against

Consumer spray applications, Consumer applications requiring temperartures above 40°C, Professional cleaning applications with aprotic polar solvents (meeting the IUPAC definition)

Emergency telephone

+49 180 2273-112

Icons in SDS

GHS08 M004 M008 M009 M010 M011 M017

Company Information

company name

BASF SE

e-mail address of the competent person responsible for the Safety Data Sheet

pss.monomers@basf.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture According to UN GHS criteria Acute Tox. 4 (Inhalation - mist) Skin Corr./Irrit. 2 Eye Dam./Irrit. 2A Resp. Sens. 1 Skin Sens. 1B Carc. 2 STOT SE 3 (irritating to respiratory system) STOT RE (Olfactory organs) 2 (by inhalation) For the classifications not written out in full in this section the full text can be found in section 16

2.2 Label elements

Globally Harmonized System (GHS)

Signal word

Danger

Hazard statements

H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash with plenty of water and soap thoroughly after handling.

Response

P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/attention if you feel unwell. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

(Disposal) P501 Dispose of contents/container in accordance with local regulations. Labeling of special preparations (GHS) Contains isocyanates. May produce an allergic reaction.

2.3 Other hazards

According to UN GHS criteria No specific dangers known, if the regulations/notes for storage and handling are considered.

2.1 Classification of the substance or mixture

According to UN GHS criteria Acute Tox. 4 (Inhalation - mist) Skin Corr./Irrit. 2 Eye Dam./Irrit. 2A Resp. Sens. 1 Skin Sens. 1B Carc. 2 STOT SE 3 (irritating to respiratory system) STOT RE (Olfactory organs) 2 (by inhalation) For the classifications not written out in full in this section the full text can be found in section 16.

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