Mule-Hide Helix - Part A (Non-Pressurized Containers)

BASF CORPORATION

Revision date : 2017-03-24

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

General Information

Revision date

2017-03-24

Product name

Mule-Hide Helix - Part A (Non-Pressurized Containers)

Product Synonyms

Diphenylmethane Diisocynate

1.2.1 Relevant identified uses

Polyurethane Component, Industrial Chemicals

1.2.2. Uses advised against

Suitable for use in industrial sector: Polymers Industry, Chemical Industry

supplier name

BASF CORPORATION

Emergency telephone

800-424-9300

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Company Information

company name

BASF CORPORATION

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H320, H332, H334, H335, H343, H351

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

OSHA Hazards According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR 1910.1200

2.1 Classification of the substance or mixture

Acute Tox. 4 (Inhalation - mist) Acute toxicity Eye Dam./Irrit. 2B Serious eye damage/eye irritation Skin Corr./Irrit. 2 Skin corrosion/irritation Skin Sens 1B Skin sensitization Resp. Sens. 1 Respiratory sensitization Carc. 2 Carcinogenicity STOT SE 3 (irritating to resp. system) Specific target organ toxicity-single exposure STOT RE 2 (by inhalation) Specific target organ toxicity-repeated exposure

2.2 Label elements

Symbol(s)

Signal word

Danger

Hazard statements

H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H343 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P201 Obtain special instructions before use. P261 Avoid breathing mist. P202 Do not handle until all safety precautions have been read and understood. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash with plenty of water and soap thoroughly after handling.

Response

P312 Call a POISON CENTER or doctor/physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308 + P311 If exposed of concerned: Call a POISON CENTER or doctor/physician. P314 Get medical advice/attention if you feel unwell. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P362 + P 364 Take off contaminated clothing and wash it before reuse. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/container to hazardous or special waste collection point.

2.3 Other hazards

No specific dangers known, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG- TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency overview DANGER: CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION. AVOID CONTACT WITH SKIN AND EYES. SKIN OR EYE CONTACT MAY CAUSE IRRITATION.

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