MasterSeal P 176

Hazard statements (CLP)

H225, H304, H315, H317, H319, H332, H335, H361, H373, H402

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

2.1 Classification of the substance or mixture

Flam. Liq. 2 Flammable liquids Acute Tox. 4 (Inhalation - mist) Acute toxicity Skin Corr./Irrit. 2 Skin corrosion/irritation Eye Dam./Irrit. 2A Serious eye damage/eye irritation Skin Sens. 1 Skin sensitization Repr. 2 (unborn child) Reproductive toxicity STOT SE 3 (irritating to Specific target organ toxicity — single exposure respiratory system) STOT RE 2 Specific target organ toxicity — repeated exposure Asp. Tox. 1

Aspiration hazard

Aquatic Acute 3 Hazardous to the aquatic environment - acute

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H317 May cause an allergic skin reaction. H304 May be fatal if swallowed and enters airways. H335 May cause respiratory irritation. H361 Suspected of damaging the unborn child. H373 May cause damage to organs (Auditory organ, Central nervous system, Liver, Kidney) through prolonged or repeated exposure. H402 Harmful to aquatic life.

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection. P271 Use only outdoors or in a well-ventilated area. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/gas/mist/vapours. P243 Take action to prevent static discharges. P261 Avoid breathing mist. P273 Avoid release to the environment. P201 Obtain special instructions before use. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P202 Do not handle until all safety precautions have been read and understood. P272 Contaminated work clothing should not be allowed out of the workplace. P242 Use only non-sparking tools. P240 Ground and bond container and receiving equipment. P264 Wash with plenty of water and soap thoroughly after handling.

Response

P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P314 Get medical advice/attention if you feel unwell. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P362 + P364 Take off contaminated clothing and wash it before reuse. P332 + P313 If skin irritation occurs: Get medical advice/attention. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. P370 + P378 In case of fire: Use water spray, dry powder, foam or carbon dioxide for extinction. P331 Do NOT induce vomiting.

Storage

P403 + P235 Store in a well-ventilated place. Keep cool. P233 Keep container tightly closed. P405 Store locked up.

Precautionary statements

Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.

2.3 Other hazards

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.