Note: Ingredients listed on restricted chemical lists
EC/CAS
40487-42-1
Name of the chemical
Pendimethalin (ISO); N-(1-Ethylpropyl)-2,6-dinitro-3,4-xyliden (2022/692)
Concentration
N/A
EC/CAS
14808-60-7
Name of the chemical
Silica, crystalline
Concentration
N/A
General Information
Revision date
2019-05-22
Product name
Freehand 1.75G Herbicide
Chemical name
aniline derivative, carboxylic acid amide, halogenated
1.2.1 Relevant identified uses
crop protection product, herbicide
Emergency telephone
1-800-424-9300
Icons in SDS
Company Information
company name
BASF CORPORATION
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H319, H350, H372, H373, H402, H412
Hazard statements
Code
Statements
H319
Causes serious eye irritation
Section 2
SECTION 2: Hazards identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
2.1 Classification of the substance or mixture
Eye Dam./Irrit. 2A Serious eye damage/eye irritation Carc. 1A (by inhalation) Carcinogenicity Aquatic Acute 3 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic STOT RE 2 (by inhalation) Specific target organ toxicity — repeated exposure STOT RE 1 (by inhalation) Specific target organ toxicity — repeated exposure
Signal word
Danger
Hazard statements
H319 Causes serious eye irritation. H350 May cause cancer by inhalation. H372 Causes damage to organs (Kidney, Immune system, Lung) through prolonged or repeated exposure (inhalation). H373 May cause damage to organs (Kidney, Immune system, Lung) through prolonged or repeated exposure (inhalation). H402 Harmful to aquatic life. H412 Harmful to aquatic life with long lasting effects.
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection. P201 Obtain special instructions before use. P260 Do not breathe dust/gas/mist/vapours. P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling.
Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/attention if you feel unwell. P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.
Storage
P405 Store locked up.
Precautionary statements
Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.
2.3 Other hazards
Labeling of special preparations (GHS): May produce an allergic reaction. Contains: pendimethalin, (S)-dimethenamid This product is not combustible in the form in which it is shipped by the manufacturer, but may form a combustible dust through downstream activities (e.g. grinding, pulverizing) that reduce its particle size.