Note: Ingredients listed on restricted chemical lists
EC/CAS
14808-60-7
Name of the chemical
Silica, crystalline
Concentration
N/A
EC/CAS
40487-42-1
Name of the chemical
Pendimethalin (ISO); N-(1-Ethylpropyl)-2,6-dinitro-3,4-xyliden (2022/692)
Concentration
N/A
General Information
Revision date
2016-10-20
Product name
FREEHAND 1.75G HERBICIDE
Chemical name
aniline derivative, carboxylic acid amide, halogenated
1.2.1 Relevant identified uses
herbicide
Emergency telephone
1-800-424-9300
Icons in SDS
Company Information
company name
BASF CORPORATION
GHS Information
Signal word
Warning
Hazard Codes
Hazard statements (CLP)
H319, H402, H412
Hazard statements
Code
Statements
H319
Causes serious eye irritation
Section 2
SECTION 2: Hazards identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
2.1 Classification of the substance or mixture
Eye Dam./Irrit. 2A Serious eye damage/eye irritation Aquatic Acute 3 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic
Signal word
Warning
Hazard statements
H319 Causes serious eye irritation. H402 Harmful to aquatic life. H412 Harmful to aquatic life with long lasting effects.
Prevention
P280 Wear eye/face protection. P260 Do not breathe dust/gas/mist/vapours. P273 Avoid release to the environment. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling.
Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/attention if you feel unwell. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.
Precautionary statements
Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.
2.3 Other hazards
Labeling of special preparations (GHS): The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 88 - 92 % dermal The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 0 - 1 % oral The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 0 - 1 % Inhalation - dust Product contains the following components and may cause an allergic skin reaction: pendimethalin This product is not combustible in the form in which it is shipped by the manufacturer, but may form a combustible dust through downstream activities (e.g. grinding, pulverizing) that reduce its particle size. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency overview CAUTION: May cause moderate but temporary irritation to the eyes. HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts.