FREEHAND 1.75G HERBICIDE

BASF CORPORATION

Revision date : 2016-10-20

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GHS07
Health risk rating 2
Safety risk rating 1
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

14808-60-7

Name of the chemical

Silica, crystalline

Concentration

N/A

EC/CAS

40487-42-1

Name of the chemical

Pendimethalin (ISO); N-(1-Ethylpropyl)-2,6-dinitro-3,4-xyliden (2022/692)

Concentration

N/A

General Information

Revision date

2016-10-20

Product name

FREEHAND 1.75G HERBICIDE

Chemical name

aniline derivative, carboxylic acid amide, halogenated

1.2.1 Relevant identified uses

herbicide

Emergency telephone

1-800-424-9300

Icons in SDS

Company Information

company name

BASF CORPORATION

GHS Information

Signal word

Warning

Hazard Codes

Hazard statements (CLP)

H319, H402, H412

Hazard statements

Code

Statements

H319

Causes serious eye irritation

Section 2

SECTION 2: Hazards identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

2.1 Classification of the substance or mixture

Eye Dam./Irrit. 2A Serious eye damage/eye irritation Aquatic Acute 3 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation. H402 Harmful to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Prevention

P280 Wear eye/face protection. P260 Do not breathe dust/gas/mist/vapours. P273 Avoid release to the environment. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/attention if you feel unwell. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Precautionary statements

Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.

2.3 Other hazards

Labeling of special preparations (GHS): The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 88 - 92 % dermal The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 0 - 1 % oral The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 0 - 1 % Inhalation - dust Product contains the following components and may cause an allergic skin reaction: pendimethalin This product is not combustible in the form in which it is shipped by the manufacturer, but may form a combustible dust through downstream activities (e.g. grinding, pulverizing) that reduce its particle size. According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency overview CAUTION: May cause moderate but temporary irritation to the eyes. HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts.

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