Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>=25.0-<50.0%
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
>=0.3-<1.0%
General Information
Revision date
2016-05-24
Product name
ELASTOCAST* TIE95
1.2.1 Relevant identified uses
polyurethane component; industrial chemicals Suitable for use in industrial sector: Polymers industry; chemical industry
Emergency telephone
1-800-424-9300
Icons in SDS
Company Information
company name
BASF CORPORATION
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H320, H332, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to Regulation
2.1 Classification of the substance or mixture
Acute Tox. 4 (Inhalation - mist) Acute toxicity Eye Dam./Irrit. 2B Serious eye damage/eye irritation Skin Corr./Irrit. 2 Skin corrosion/irritation Skin Sens. 1B Skin sensitization Resp. Sens. 1 Respiratory sensitization STOT SE 3 (irritating to Specific target organ toxicity — single exposure respiratory system) STOT RE 2 (by inhalation) Specific target organ toxicity — repeated exposure
Signal word
Danger
Hazard statements
H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).
Prevention
P280 Wear protective gloves. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P261 Avoid breathing mist. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash with plenty of water and soap thoroughly after handling.
Response
P312 Call a POISON CENTER or doctor/physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/attention if you feel unwell. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Precautionary statements
Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.
2.3 Other hazards
No specific dangers known, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.