AUTOFROTH9300A ISOCYANATE

Hazard statements (CLP)

H280, H315, H317, H320, H332, H334, H335, H351, H373

Code

Statements

H280

Contains gas under pressure; may explode if heated

SECTION 2: Hazards identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to Regulation

2.1 Classification of the substance or mixture

Press. Gas Compr. Gas Gases under pressure Acute Tox. 4 (Inhalation - mist) Acute toxicity Skin Corr./Irrit. 2 Skin corrosion/irritation Eye Dam./Irrit. 2B Serious eye damage/eye irritation Resp. Sens. 1 Respiratory sensitization Skin Sens. 1B Skin sensitization Carc. 2 Carcinogenicity STOT SE 3 (irritating to Specific target organ toxicity — single exposure respiratory system) STOT RE 2 (by inhalation) Specific target organ toxicity — repeated exposure

Signal word

Danger

Hazard statements

H280 Contains gas under pressure; may explode if heated. H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash with plenty of water and soap thoroughly after handling.

Response

P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/attention if you feel unwell. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Storage

P410 + P403 Protect from sunlight. Store in a well-ventilated place. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.

2.3 Other hazards

No specific dangers known, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.