AUTOFROTH 15000A ISOCYANATE

Hazard statements (CLP)

H280, H315, H317, H320, H332, H334, H335, H373

Code

Statements

H280

Contains gas under pressure; may explode if heated

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Press. Gas Compr. Gas Gases under pressure Acute Tox. 4 (Inhalation - mist) Acute toxicity Eye Dam./Irrit. 2B Serious eye damage/eye irritation Skin Corr./Irrit. 2 Skin corrosion/irritation Skin Sens. 1B Skin sensitization Resp. Sens. 1 Respiratory sensitization STOT SE 3 (irritating to Specific target organ toxicity — single exposure respiratory system) STOT RE 2 (by inhalation) Specific target organ toxicity — repeated exposure

Signal word

Danger

Hazard statements

H280 Contains gas under pressure; may explode if heated. H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).

Prevention

P280 Wear protective gloves. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash contaminated body parts thoroughly after handling.

Response

P312 Call a POISON CENTER or doctor/physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/attention if you feel unwell. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Storage

P410 + P403 Protect from sunlight. Store in a well-ventilated place. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

(Disposal) P501 Dispose of contents/container in accordance with local regulations.

2.3 Other hazards

No specific dangers known, if the regulations/notes for storage and handling are considered. Labeling of special preparations (GHS) CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.