TDA 90% Vicinal

BASF Canada Inc

Revision date : 2023-05-05

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GHS09 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

496-72-0

Name of the chemical

Toluene-3,4-Diamine and its salts, when used as a substance in hair dye products

Concentration

(W/W) >= 50.0 - < 75.0%

EC/CAS

95-80-7

Name of the chemical

4-methyl-m-phenylenediamine

Concentration

(W/W) > 0.0 - < 5.0%

EC/CAS

823-40-5

Name of the chemical

2-Methyl-m-phenylendiamin

Concentration

(W/W) > 0.0 - < 5.0%

EC/CAS

26915-12-8

Name of the chemical

Toluidines, their isomers, salts and halogenated and sulphonated derivatives

Concentration

(W/W) >= 3.0 - < 5.0%

EC/CAS

95-70-5

Name of the chemical

1,4-Benzenediamine, 2-methyl- 2,5-Diaminotoluene sulphate

Concentration

(W/W) > 0.0 - < 3.0%

EC/CAS

108-45-2

Name of the chemical

m-phenylenediamine

Concentration

(W/W) >= 0.1 - < 1.0%

General Information

Version

2.0

Revision date

2023-05-05

Product name

TDA 90% Vicinal

Chemical name

Preparation based on: amines, aromatic

1.2.1 Relevant identified uses

Chemical, Raw material

Emergency telephone

+1 289 360-1300, 1-800-424-9300

Icons in SDS

GHS08 GHS09 M004 M008 M009 M010 M011 M014 M017

Company Information

company name

BASF Canada Inc

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301+H331, H312+H332, H317, H319, H341, H350, H361, H373, H401, H411

Hazard statements

Code

Statements

H301+H331

Toxic if swallowed or if inhaled

Section 2

SECTION 2: Hazards identification

According to Hazardous Products Regulations (HPR) (SOR/2015-17) According to Hazardous Products Regulations (HPR) (SOR/2015-17) Classification of the product Acute Tox (Inhalation - dust) Acute toxicity Acute Tox (Inhalation - vapour) Acute toxicity Acute Tox (oral) Acute toxicity Acute Tox (dermal) Acute toxicity Eye Dam./Irrit 2A Serious eye damage/eye irritation Skin Sens Skin sensitization Muta Germ cell mutagenicity Carc 1B Carcinogenicity Repr (fertility) Reproductive toxicity STOT RE Specific target organ toxicity — repeated exposure Aquatic Acute Hazardous to the aquatic environment - acute Aquatic Chronic Hazardous to the aquatic environment - chronic Label elements Pictogram

Signal word

Danger Hazard Statement H319 Causes serious eye irritation H317 May cause an allergic skin reaction H361 Suspected of damaging fertility H350 May cause cancer H341 Suspected of causing genetic defects H301 + H331 Toxic if swallowed or if inhaled H312 + H332 Harmful in contact with skin or if inhaled H373 May cause damage to organs (Liver, Testes) through prolonged or repeated exposure H401 Toxic to aquatic life H411 Toxic to aquatic life with long lasting effects Precautionary Statements (Prevention) P280 Wear protective gloves, protective clothing and eye protection or face protection P271 Use only outdoors or in a well-ventilated area P201 Obtain special instructions before use P260 Do not breathe dust or mist or vapour P273 Avoid release to the environment P280 Wear eye protection P202 Do not handle until all safety precautions have been read and understood P264 Wash contaminated body parts thoroughly after handling P272 Contaminated work clothing should not be allowed out of the workplace Precautionary Statements (Response) P311 Call a POISON CENTER or physician P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or physician P308 + P313 IF exposed or concerned: Get medical attention P302 + P352 IF ON SKIN: Wash with plenty of soap and water P333 + P313 If skin irritation or rash occurs: Get medical attention P337 + P313 If eye irritation persists: Get medical attention P330 Rinse mouth P361 + P364 Take off immediately all contaminated clothing and wash it before reuse P391 Collect spillage Precautionary Statements (Storage) P403 + P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up

Precautionary statements

(Disposal) P501 Dispose of contents/container in accordance with local regulations.

2.3 Other hazards

No specific dangers known, if the regulations/notes for storage and handling are considered.

2.1 Classification of the substance or mixture

Acute Tox. 4 (Inhalation - dust) Acute toxicity Acute Tox. 3 (Inhalation - vapour) Acute toxicity Acute Tox. 3 (oral) Acute toxicity Acute Tox. 4 (dermal) Acute toxicity Eye Dam./Irrit. 2A Serious eye damage/eye irritation Skin Sens. 1 Skin sensitization Muta. 2 Germ cell mutagenicity Carc. 1B Carcinogenicity Repr. 2 (fertility) Reproductive toxicity STOT RE 2 Specific target organ toxicity — repeated exposure Aquatic Acute 2 Hazardous to the aquatic environment - acute Aquatic Chronic 2 Hazardous to the aquatic environment - chronic

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