LUPRANATE8020 ISOCYANATE

Hazard statements (CLP)

H315, H317, H319, H330, H334, H335, H351, H373, H402, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

According to Hazardous Products Regulations (HPR) (SOR/2022-272)

2.1 Classification of the substance or mixture

Acute Tox. 1 (Inhalation - vapour) Acute toxicity Skin Irrit. 2 Skin irritation Eye Irrit. 2A Eye irritation Resp. Sens. 1 Respiratory sensitization Skin Sens. 1 Skin sensitization Carc. 2 Carcinogenicity STOT SE 3 (irritating to Specific target organ toxicity — single exposure respiratory system) STOT RE 2 (by inhalation) Specific target organ toxicity — repeated exposure Aquatic Acute 3 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic

Signal word

Danger

Hazard statements

H319 Causes serious eye irritation. H315 Causes skin irritation. H330 Fatal if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation). H402 Harmful to aquatic life. H412 Harmful to aquatic life with long lasting effects.

Prevention

P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, protective clothing and eye protection or face protection. P260 Do not breathe mist or vapour or spray. P201 Obtain special instructions before use. P284 In case of inadequate ventilation wear respiratory protection. P273 Avoid release to the environment. P202 Do not handle until all safety precautions have been read and understood. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash contaminated body parts thoroughly after handling.

Response

P310 Immediately call a POISON CENTER or physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P341 + P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P337 + P313 If eye irritation persists: Get medical attention. P308 + P313 IF exposed or concerned: Get medical attention. P362 + P364 Take off contaminated clothing and wash it before reuse.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.

Precautionary statements

(Disposal) P501 Dispose of contents and container to hazardous or special waste collection point.

2.3 Other hazards

Labeling of special preparations (GHS) CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.