Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
(W/W) >= 50.0 - < 75.0%
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
(W/W) >= 25.0 - < 50.0%
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
(W/W) >= 3.0 - < 7.0%
General Information
Version
2.0
Revision date
2023-09-06
Product name
K285
Chemical name
aromatic isocyanates
1.2.1 Relevant identified uses
polyurethane component; industrial chemicals
Emergency telephone
+1 289 360-1300, 1-800-424-9300
Icons in SDS
Company Information
company name
BASF Canada Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H320, H332, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
According to Hazardous Products Regulations (HPR) (SOR/2015-17) According to Hazardous Products Regulations (HPR) (SOR/2015-17)
2.1 Classification of the substance or mixture
Acute Tox. 4 (Inhalation - mist) Acute toxicity Skin Irrit. 2 Skin irritation Eye Irrit. 2B Eye irritation Resp. Sens. 1 Respiratory sensitization Skin Sens. 1B Skin sensitization STOT SE 3 (irritating to Specific target organ toxicity — single exposure respiratory system) STOT RE 2 (by inhalation) Specific target organ toxicity — repeated exposure
Signal word
Danger
Hazard statements
H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation).
Prevention
P280 Wear protective gloves. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe mist or vapour or spray. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash contaminated body parts thoroughly after handling.
Response
P312 Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P314 Get medical advice/attention if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P337 + P313 If eye irritation persists: Get medical attention. P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Precautionary statements
(Disposal) P501 Dispose of contents/container in accordance with local regulations.
2.3 Other hazards
Labeling of special preparations (GHS) CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.