MAGNACIDE- B Microbiocide

Hazard statements (CLP)

H225, H300, H311, H314, H318, H330, H400, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 [CLP]] Classification of the substance or mixture

Product definition

Mixture Classification according to UK CLP/GHS Flam. Liq. 2, H225 Acute Tox. 2, H300 Acute Tox. 3, H311 Acute Tox. 1, H330 Skin Corr. 1B, H314 Eye Dam. 1, H318 Aquatic Acute 1, H400 (M=1) Aquatic Chronic 1, H410 (M=1) EUH071 EUH208

Hazard pictograms

GHS02 GHS06 GHS05 GHS09

Signal word

Danger

Hazard statements

Highly flammable liquid and vapour. Fatal if swallowed or if inhaled. Toxic in contact with skin. Causes severe skin burns and eye damage. Very toxic to aquatic life with long lasting effects. : H225, H300 + H330, H311, H314, H410 (Code)

Prevention

Wear protective gloves > 8 hours (breakthrough time) Butyl rubber gloves.. Wear protective clothing. Wear eye or face protection. In case of inadequate ventilation wear respiratory protection Recommended full-face mask and organic vapour filter (Type A). Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid release to the environment. Do not breathe vapour. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.

Response

Collect spillage. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse. IF ON SKIN: Call a POISON CENTER or doctor if you feel unwell. Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Storage

Not applicable.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazardous Ingredients

acrylaldehyde

Supplemental label elements

Corrosive to the respiratory tract.

Contains

1,4-dihydroxybenzene. May produce an allergic reaction

Precautionary statements

P280, P284, P210, P273, P260, P270, P264, P391, P304 + P340, P310, P301 + (Code) P310, P330, P331, P303 + P361 + P353, P310, P363, P302 + P312, P352, P305 + P351 + P338, P310, P501

2.3 Other hazards

Product meets the criteria for PBT or vPvB according : This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

Other hazards which do not result in classification

None known.

Additional information

Overexposure to acrolein vapours may be fatal. Inhalation exposure studies have determined the rat LC50 for acrolein to be 26 ppm at one hour exposure and at four hour exposure to be 8.3 ppm. The NIOSH IDLH (Immediately Dangerous to Life and Health) value for acrolein is 2 ppm. The primary route of exposure is inhalation; acute exposure may result in lacrimation, tracheobronchitis, pneumonia, and lung injury (at 20 ppm acrolein). Acrolein’s low odour detection (0.03 – 0.21 ppm) and irritation threshold (0.25 - 0.5 ppm) and acutely irritating effects usually prevent chronic toxicity effects. Splashes to the eye may result in blepharoconjunctivitis (bloodshot eyes), lid oedema, fibrinous or pustular discharge, and deep or long- lasting corneal injury. See Section 11 for additional information. Mixing of chemicals may create a reaction hazardous to one’s health, to the environment, or a potential fire hazard.

2.1 Classification of the substance or mixture

Product definition : Mixture Classification according to UK CLP/GHS Flam. Liq. 2, H225 Acute Tox. 2, H300 Acute Tox. 3, H311 Acute Tox. 1, H330 Skin Corr. 1B, H314 Eye Dam. 1, H318 Aquatic Acute 1, H400 (M=1) Aquatic Chronic 1, H410 (M=1) EUH071 EUH208 SECTION 2: Hazards identification