13-302A Iso Component Part A

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification of the hazardous chemical Classification according to the Environmental Protection Authority notices (EPA Hazardous Substances and New Organisms Act 1996) Acute toxicity (inhalation:vapour) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, Respiratory H335 tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373

2.2 Label elements

GHS NZ labelling

Hazard pictograms

(GHS NZ)

Signal word

Danger

Contains

Polymeric MDI (9016-87-9); 4,4'-Methylenediphenyl diisocyanate (101-68-8); 1,3-Bis(4-((4- isocyanatophenyl)methyl)phenyl)-1,3-diazetidine-2,4-dione; Isocyanic acid, polymethylenepolyphenylene ester, polymer with a-hydro-ω-hydroxypoly(oxy-1,2- ethanediyl)

Hazard statements

(GHS NZ) : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation H351 - Suspected of causing cancer H373 - May cause damage to organs (respiratory system) through prolonged or repeated exposure (Inhalation)

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe fume, spray, vapours. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P284 - Wear respiratory protection.

Response

P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P331 - Do NOT induce vomiting. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P308+P313 - IF exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTER or doctor if you feel unwell.

Storage

P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up.

Disposal

P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

Other hazards which do not result in classification

No additional information available

2.1 Classification of the substance or mixture

Classification according to the Environmental Protection Authority notices (EPA Hazardous Substances and New Organisms Act 1996) Acute toxicity (inhalation:vapour) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, Respiratory H335 tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373