EQUIPMENT

Hazard statements (CLP)

H302, H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 - be 8,5 PNEC FOR CE ≤ x marked, FIRE-FIGHTERS < is 10 based showing on calculation Carc. that it 2 complies 12.7. Hazard SECTION 10. Stability and reactivity Normal GERM - Section H351,

PBT Substances

methods Other Normal Persistent, CELL

2.2 Label elements

fire Acute 12. adverse with as applicable value fighting MUTAGENICITY per Tox. Annex pursuant in bioaccumulative effects clothing fresh water 4 H332, standards. I of STOT to i.e. EC fire Regulation CLP, Part and RE 2 4, H373, kit (BS

2.1 Classification of the substance or mixture

2000 mg/kg apparatus note (BS according EN 137). to Annex VI 0,0632 to the CLP mg/l Regulation: 2, C EC Exposure Does Information On - PEL: Normal the not Predicted basis

Hazard pictograms

meet levels value not of the available 500-040-3 available must exposure for classification fresh be kept data, water level as the sediment criteria low product as for possible this does hazard not to avoid

Contains

class significant any Skin SVHC Irrit. build-up 2 in H315: percentage in the ≥ 5%, organism. ≥ Eye than Irrit. 0,1%. Manage 2 H319: personal 5 ≥ 5%, Resp. protective mg/kg Sens. equipment 1 H334: ≥ so 0,5%, as to SECTION guarantee Does - PMT: There are no particular risks of reaction with other substances in normal conditions of use. Normal not Persistent, TRIETHYLPHOSPHATE meet maximum value 1. the Identification for mobile Atp. person the victim - CLP) PNEC Eye - Crustaceans Regulation Results: Irrit. of exposure Alcohols. 2 (EU) irritating Amines. 2019/1148 8.9 mg/l/48h, Acute Reaction Acute Waterfall. Eye Daphnia irritation, Ammonia. mass of 4,4´- Centro magna category Bases. (OECD not 2 available methylenediphenyl Metallic Chronic 202) compounds. Humid air. Strong oxidants. Nazionale di Chronic Informazione diisocyanate Acute and Tossicologica o-(p- local isocyanatobenzyl) Acute PAVIA: 0382-24444 Chronic STOT 18. Delegated Specific Melting Skin point - SINGLE Regulation information Irrit. / 2 freezing on symptoms EXPOSURE point (UE) local 2020/217 phenyl isocyanate Skin and irritation, effects caused systemic (XIV Atp. CLP) category Osp. local not by 2 the available Niguarda Ca' systemic product are unknown. Granda MILANO: 02-66101029 systemic local systemic 7.2. not Conditions SERIOUS 19. Delegated Regulation (UE) 2020/1182 NPI (XV Atp. CLP) Oral applicable for safe storage, EYE DAMAGE / IRRITATION 4,4' including - METHYLENE any incompatibilities PHENYL Azienda Ospedaliera DIISOCYANATE, NPI Papa OLIGOMERS Giovanni XXII BERGAMO: 800883300 10.6. Initial Hazardous STOT boiling SE point 3 decomposition products Specific target organ 262 toxicity - single °C exposure, category 3 12.2. DELAYED May 20. Delegated Flammability Persistence Resp. Sens. cause respiratory EFFECTS: Regulation and 1 degradability irritation Based on Respiratory (UE) 2021/643 (XVI Atp. CLP) the information sensitization, currently Azienda Ospedaliera Integrata VERONA: 800011858 not available available, category 1 there are no known cases of delayed effects following exposure to this 14.5. Store Causes 21. Inhalation Environmental Delegated only in the original serious Regulation eye irritation (UE) container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away 0,5 2021/849 NPI (XVII Atp. CLP) 0,025 NPI 0,1 NPI 0,05 NPI product. Lower Information Skin explosive Sens. not available 1 limit Skin sensitization, category not available 1 from any incompatible materials, see section 10 for details. 22. Delegated 4,4' - METHYLENE Regulation (UE) mg/m3 PHENYL 2022/692 DIISOCYANATE, (XVIII Atp. CLP) OLIGOMERS mg/m3 SECTION Upper As not from 23. Skin H351 explosive Delegated applicable mg/m3 4,4' Based 24 August - METHYLENE Regulation on available limit 2023 adequate (UE) MED PHENYL data, 2023/707 identification Suspected of causing not cancer. the training DIISOCYANATE, substance NPI is required presents before OLIGOMERS available specific MED industrial toxicity or NPI effects professional for target use. MED organs for single NPI exposure MED [respiratory tract] NPI and is 4.3. Flash TRIETHYLPHOSPHATE Indication H302 point of any immediate medical Harmful if attention swallowed. and 170 special treatment 2.1. SECTION 24. Classification Auto-ignition Inherently H332 degradable Delegated needed Method: classified 11. Regulation temperature OECD of Toxicological under the 405 substance the (UE) relevant 2023/1434 Harmful if inhaled. 451 33% not fulfilling or CLP information mixture copper, SENSITISATION water substances copper alloys with and endocrine May cause an allergic not skin galvanized available disrupting reaction. surfaces properties in concentration ≥ 0.1%. 0,00037 mg/l Information not relevant Route - INRS Normal Fiche exposure value Toxicologique for fresh water (toxicological sediment sheet) 11,7 12.3. Vapour Bioaccumulative EUH204 mg/kg/d of - classification pressure and indication: potential Contains isocyanates. 10 May produce an Pa allergic reaction. Temperature: 20 °C 7.3. Information SECTION Sensitising - Patty Specific end Normal - Industrial value for 5. the Firefighting on likely use(s) routes of exposure for Hygiene skin marine and water measures sediment

Classifications

marine protection and water toxic (e.g. criteria sediment of reduction the for this substance/mixture in hazard replacement class STOT times). SE 3 H335: and of ≥ 5% the company/undertaking 0,5 mg/kg CAS HAND Substances - PNEC: Normal PROTECTION ATE 4,4' Predicted value - subject (Oral): METHYLENE 25686-28-6 for no to marine effect authorisation PHENYL water, concentration intermittent (Annex DIISOCYANATE, XIV release REACH) OLIGOMERS ATE 500 mg/kg Inhalation estimate mists/powders: from table 3.1.2 1,5 of mg/l, 1.1. SECTION REACH Protect None - REACH

Product definition

Normal hands Method: 4,4' Reg. Annex 9 ATE Regulation value 6. 13. Accidental - METHYLENE with 01-2119457013-49-XXXX I of Inhalation OECD Disposal considerations of category STP (EC) the CLP mg/l vapours: 11 mg/l 471 microorganisms

Precautionary statements

should (Inhalation are for concerning (Klimisch no the be methods data terrestrial considered vapours): protective equipment and emergency procedures available score): the international compartment 1 on when the choosing danger transport in work case of glove of dangerous aspiration. 8,817 material mg/l/4h goods (see Rat by standard train EN 374): compatibility, 0,64 degradation, mg/kg permeability time. Code: The Substances - TLV: Normal full work Threshold Species: wording gloves' value subject of Limit for S. resistance typhimurium, to the Value exportation atmosphere (H) to phrases chemical E. reporting Coli is agents given pursuant in should section 04030017P to be Regulation 16 checked of the sheet. before (EU) 649/2012: use, as it can be unpredictable. NPI The gloves' wear time depends on The product is stable in normal conditions of use and storage. 11.2. Product Health the None - TLV Block Reuse, the when Information duration CEILING: - 4,4' Results: name Derived leakage - and METHYLENE possible. on Concentration negative type no-effect if there Product other of use. with is no hazard. PHENYL level and that - without residues should be considered special hazardous waste. The hazard level of waste containing this product DNEL should DIISOCYANATE, / metabolic not DMEL be exceeded SYNTECH activation OLIGOMERS during HAG any MONO time of occupational exposure. SKIN - TWA: PROTECTION Wear should suitable be evaluated Time-weighted LD50 (Dermal): average protective according equipment Effects to applicable exposure on consumers (including regulations. limit personal protective equipment referred to under Section 8 of the safety data sheet) to prevent > 9400 mg/kg Effects on workers exposure: dose PACKAGING reactions to (Sprague-Dawley; the goggles toxicity: and Stockholm very inhalation (see mobile standard Convention: Male) mg/kg EN bw/d ISO 16321). mg/kg bw/d Intended RESPIRATORY None - WGK: Inhalation isocyanates. of the European in a comfortable used for chemical May Parliament produce an allergic reaction. position products for breathing. should If necessary be respected. administer oxygen. If the subject stops responsible not applicable 7. Regulation Normal Routes value for (EU) the of in exposure: 487/2013 Safety fresh water Data inhalation (IV Sheet Atp. CLP) (aerosol) of the European laboratorio@azichem.com Parliament 0,0037 breathing, administer artificial respiration. Get medical advice/attention. mg/l Precautionary SKIN A 8. chemical Regulation Normal CORROSION Results: value (EU) Carcinogenic in assessment 944/2013 marine / IRRITATION water (V after has Atp. not long-term CLP) been of performed the inhalation European for at aerosol the Parliament preparation/for concentrations the of substances 6.0 mg/m3. indicated in 0,00037 section 3. mg/l Any TRIETHYLPHOSPHATE information on personal protection and disposal is given in sections 8 and 13. 1.4. 14.2. Emergency 9. Regulation UN P261 proper telephone Normal value (EU) for 605/2014 shipping name fresh number water (VI Avoid sediment Atp. CLP) breathing of the dust European / fume Parliament / gas / mist / vapours / spray. 11,7 mg/kg SECTION 9. Physical and chemical properties Rescuer 4,4' LC50 - METHYLENE Causes REPRODUCTIVE 10. P280 Normal Regulation - for protection skin value Fish irritation (EU) for TOXICITY PHENYL DIISOCYANATE, OLIGOMERS 2015/1221 marine water (VII Wear sediment Atp. protective CLP) of the gloves/ European protective 100 mg/l/96h Parliament clothing / eye protection / face protection. 11,7 mg/kg SECTION EC50 Avoid not applicable - for contact Algae / with Regulation (Klimisch (UE) PHENYL for user score): DIISOCYANATE, OLIGOMERS 2023/1435 (XX Atp. CLP)

Disposal

Chronic contamination - METHYLENE suspected 20344). endocrine must be performed Wash Chronic body of PHENYL skin, eyes through DIISOCYANATE, and personal an authorised clothing. OLIGOMERS waste These management indications firm, apply in for compliance both processing with national staff and and those local regulations. involved in emergency Signal with disruptors None - VOC: Volatile procedures. The Exposure soap management words: 4. First aid measures Method: Reliability and with water to high of temperatures human organic OECD (Klimisch after waste arising may health Compounds 425 removing local score): effects Danger from cause 1 protective under systemic the use decomposition evaluation. clothing. or dispersal of of this local the product must systemic and generation be organised of gases. in accordance with occupational safety systemic local systemic 1.2. EYE 4.1. regulations.

vPvB Substances

Relevant Description See of section Oral PROTECTION Reliability Species: TRIETHYLPHOSPHATE Very identified persistent Rat first aid 8 measures (Klimisch (Brown uses and very for possible need for PPE. score): of Norway; the bioaccumulative substance 1 Male) 5 or mixture and uses advised 1 against 6.2. 10.3. CONTAMINATED Wear Substances - vPvM: airtight Environmental Possibility of hazardous Species: Routes Repeated Very subject persistent protective of Rat

Hazard statements

Routes Results: Oral: Water use hazard of PROTECTION negative exposure: classes LOW oral (German). NPI Low LOW viscosity hydro-expansive 1,74 LOW single-component NPI polyurethane In Contaminated case of doubt packaging LOW resin or in the presence 9,9 must be recovered of symptoms or disposed contact a of doctor in compliance and show with him national this document. waste management regulations. Respiratory In The No case H351 Results: hazardous product NOAEL: of more protection must reactions severe LD50 200 mg/kg not penetrate > devices symptoms, are foreseeable 5000 bw/day mg/kg must Suspected into ask the for sewer (Rat) be body used in immediate weight normal of if causing system the technical conditions medical cancer. measures adopted or come of aid. into use contact and storage. mg/m3 are not suitable for restricting the worker's exposure mg/m3 with surface water or ground water. to the 1.3. threshold CARCINOGENICITY Healthcare EYES: Remove, if present, contact lenses if the situation allows you to do so easily. Wash immediately with plenty of water for at least 15 Details H332 Skin of values controls the supplier considered. of NPI the Use Harmful safety a mask data NPI if with inhaled. sheet a type A filter NPI whose class 1 (1, 2 or 3) must LOW be chosen according NPI to the LOW limit of use 2 6.3. minutes, SECTION concentration. Workers GENERAL Methods opening H373 Method: exposed BIBLIOGRAPHY and material 14. (see equivalent Transport the eyelids to standard this chemical for fully. or EN containment similar May information 14387). Get medical and advice/attention. agent cause to OECD must damage not 402 undergo cleaning up to organs health through checks, prolonged mg/kg provided bw/d or that repeated available exposure. risk-assessment data prove that mg/kg the risks SECTION Name If Suspected related 1. the Regulation H319 substance to Reliability the of causing

ECOLOGICAL INFORMATION

workers' (EC) considered (Klimisch

Further information

Aquatic metals Plants such as: Aluminum. Zinc. Brass. 901 Tin mg/l/72h SECTION can. Copper. Galvanized metals. For 11. P342+P311 It EC10 is Avoid Normal Regulation urgent inquiries good for Algae contact practice value 7. (EU) Handling / Aquatic for refer with for rescuers 2016/918 marine absorbent Plants lending to water, and (VIII If experiencing materials Atp. intermittent

Storage

support CLP) of release such to as: a person respiratory the European Wet organic Osp. Pediatrico 127 who mg/l/72h symptoms: Parliament Bambino has absorbents. been exposed Call a POISON Avoid inadvertent Gesù CENTER to a chemical contact ROMA: 06 / doctor substance 68593726 with polyols. 0,037 / . . . or to a mixture to wear personal mg/l 9.1. protective Does 12. P304+P340 Chronic Text Information Normal Regulation of hazard not 4,4' meet NOEC equipment. value - METHYLENE on (H) the (EU) for basic of classification Crustacea indications STP 2016/1179 The physical microorganisms nature PHENYL mentioned (IX IF criteria of and such chemical INHALED: Atp. DIISOCYANATE, CLP) for this Remove in protection section properties hazard Az. class 2-3 depends person OLIGOMERS of the Osp. Univ. 31,6 sheet: on mg/l the (21 hazard to fresh Foggia air and FOGGIA: days) level of the substance or mixture, on the type of exposure and on keep comfortable 800183459 for breathing. NPI 7.1. 14.3. Precautions 13. P201 Transport hazard Normal Regulation Method: value (EU) OECD for safe class(es) for 2017/776 the 404 handling terrestrial (X Obtain Atp. compartment CLP) special instructions Az. Osp. before "A. Cardarelli" use. NAPOLI: 081-5453333 2,33 mg/kg 10.5. the Incompatible extent of the contamination. materials In the absence of other more specific indications, use of disposable gloves in the event of possible contact 14. P308+P313 with Properties 4,4' Carc. Normal Regulation - body METHYLENE Reliability 4,4' value 2 fluids is recommended. - METHYLENE (EU) for (Klimisch PHENYL DIISOCYANATE, 2018/669 the atmosphere PHENYL score): (XI IF Atp. Carcinogenicity, For the type of OLIGOMERS exposed 1 DIISOCYANATE, CLP) or concerned: category PPE Value Policlinico suitable OLIGOMERS 2 Get medical for the characteristics of the substance "Umberto advice I" ROMA: / attention. 06-49978000 Information or mixture, see section 8. NPI Before not applicable 15. Regulation (EU) 2019/521 (XII Atp. CLP) handling the product, consult all the other sections Based available (HC:NZW) data, substance not present "A. of this material reproductive Health - Species: Appearance LC50 Acute Gemelli" safety ROMA: - for Tox. Derived on Rabbit Fish 4 toxicity effects data sheet. no-effect 06-3054343 Avoid leakage of the product into the and is not classified under the relevant CLP level the Acute toxicity, category - DNEL / DMEL does Policlinico liquid 4 > 100 mg/l/96h Danio rerio (OECD 203) environment. 16. Delegated Routes hazard Do Regulation class of not exposure: eat, drink (UE) Effects dermal or 2018/1480 smoke on consumers during (XIII Atp. use. CLP) Az. Remove Osp. any "Careggi" contaminated U.O. Tossicologia clothes Effects and personal Medica on workers FIRENZE: protective equipment 055-7947819 before entering 4.2. Colour 14.4. places 4,4' Chronic Most Packing STOT - METHYLENE in which important NOEC RE 2 for symptoms group people eat. Crustacea PHENYL DIISOCYANATE, and Specific effects, target both OLIGOMERS organ acute orange toxicity and > 10 delayed - repeated mg/l/21 giorni exposure, Daphnia category magna 2 (OECD 211) 17. Route Odour EL50 Acids. IF Decomposition exposed Information H373 temperature: or concerned: temperature Get medical on hazard 25 - 35 classes °C (77 as May cause - 95 defined advice damage °F) / attention. not applicable 27. Delegated Routes Regulation period: 6 months of exposure: (UE) ocular 2024/2564 Atp. CLP) amendments Means Kinematic NOT H315 rapidly to have viscosity degradable and available supplements). in the workplace Causes The product 4,4' (XXII skin for specific - METHYLENE irritation. thus requires 350 and mm2/s immediate a safety treatment PHENYL DIISOCYANATE, OLIGOMERS datasheet that complies with Temperature: the provisions 20 of °C (EU) Regulation On Predicted Metabolism, 2020/878. Dynamic Not H335 the basis rapidly viscosity Results: 4,4' no-effect degradable, 0% in 28 May - toxicokinetics, of METHYLENE available irritating concentration data, mechanism PHENYL the product days cause - DIISOCYANATE, PNEC (OECD of action does and respiratory 302 C) 350 not contain other OLIGOMERS irritation. cP information any PBT or vPvB in percentage ≥ than 0,1%. Temperature: 20 °C 14.7. Suitable - The Maritime Merck value Respiratory containers: Index. in - fresh transport System Steel. 10th water in bulk Edition Stainless according steel. to IMO instruments Any Normal Running Solubility H334 additional water information for skin and concerning eye wash. May cause 0,0037 the risks allergy for or health mg/l not asthma available and/or symptoms

Hazard categories

(XIX Atp. CLP) specific criteria 14.6. 4,4' Special 25. Delegated - METHYLENE Reliability

Environmental hazards

or breathing are difficulties given in sections if inhaled. 11 and 12 of this sheet. The Unsuitable Information RESPIRATORY - Handling Chemical Safety Partition Normal value OR H317 coefficient: n-octanol/water product containers: not does available in not marine SKIN