Titanium(IV) chloride, 1M solution in dichloromethane

Hazard statements (CLP)

H314, H331, H335, H336, H351

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid No information available Emergency Overview Toxic if inhaled. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause drowsiness and dizziness. Reacts violently with water. Moisture sensitive. Classification of the substance or mixture Acute Inhalation Toxicity - Vapors Category 2 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 1 Category 3

Signal word

Danger

Hazard statements

H314 - Causes severe skin burns and eye damage H351 - Suspected of causing cancer H336 - May cause drowsiness or dizziness H335 - May cause respiratory irritation H331 - Toxic if inhaled

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P284 - Wear respiratory protection P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P362 + P364 - Take off contaminated clothing and wash it before reuse

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Reacts violently with water.

Health hazards

Corrosive. Causes skin and eye burns. Causes serious eye damage. Suspected of causing cancer. May cause drowsiness or dizziness. Toxic if inhaled.

Environmental hazards

Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Reacts violently with water. . Toxic to terrestrial vertebrates. Contains a known or suspected endocrine disruptor. Contains a substance on the National Authorities Endocrine Disruptor Lists.

2.1 Classification of the substance or mixture

Category 2 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 1 Category 3 Label Elements