Methyldichlorophosphine

Hazard statements (CLP)

H226, H250, H302+H332, H314

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid Colorless No information available Emergency Overview Flammable liquid and vapor. Catches fire spontaneously if exposed to air. Harmful if swallowed. Causes severe skin burns and eye damage. Harmful if inhaled. Reacts violently with water. Contact with water liberates toxic gas. Moisture sensitive. Air sensitive. Lachrymator (substance which increases the flow of tears). Classification of the substance or mixture Flammable liquids Category 3 Pyrophoric liquids Category 1 Acute Oral Toxicity Category 4 Acute Inhalation Toxicity - Vapors Category 4 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Label Elements

Signal word

Danger Hazard Statements H226 - Flammable liquid and vapor H250 - Catches fire spontaneously if exposed to air H314 - Causes severe skin burns and eye damage H302 + H332 - Harmful if swallowed or if inhaled

Prevention

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P222 - Do not allow contact with air P233 - Keep container tightly closed P242 - Use non-sparking tools P243 - Take action to prevent static discharges P264 - Wash face, hands and any exposed skin thoroughly after handling P240 - Ground and bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting equipment P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P302 + P334 - IF ON SKIN: Immerse in cool water or wrap in wet bandages P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P362 + P364 - Take off contaminated clothing and wash it before reuse

Storage

P403 + P235 - Store in a well-ventilated place. Keep cool P422 - Store contents under inert gas

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Flammable liquid. Vapors may cause flash fire or explosion. Catches fire spontaneously if exposed to air. Reacts violently with water.

Health hazards

Harmful if swallowed. Corrosive. Causes skin and eye burns. Harmful if inhaled. Lachrymator (substance which increases the flow of tears).

Environmental hazards

Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Reacts violently with water. Will likely be mobile in the environment due to its volatility. The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.

2.3 Other hazards

Lachrymator (substance which increases the flow of tears) This product does not contain any known or suspected endocrine disruptors.

2.1 Classification of the substance or mixture

Flammable liquids. Category 3 Pyrophoric liquids Category 1 Acute Oral Toxicity Category 4 Acute Inhalation Toxicity - Vapors Category 4 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation