Allyl isothiocyanate

Hazard statements (CLP)

H226, H301, H310+H330, H315, H317, H319, H335, H361, H371, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid Light yellow pungent Emergency Overview Causes serious eye irritation. Fatal if inhaled. May cause respiratory irritation. Moisture sensitive. Lachrymator (substance which increases the flow of tears). Flammable liquid and vapor. Toxic if swallowed. Causes skin irritation. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. May cause damage to organs. Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Fatal in contact with skin. Classification of the substance or mixture Flammable liquids Category 3 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 2 Acute Inhalation Toxicity - Vapors Category 2 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Skin Sensitization Category 1 Reproductive Toxicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Category 2 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity Category 1 ______________________________________________________________________________________________

Signal word

Danger

Hazard statements

H226 - Flammable liquid and vapor H319 - Causes serious eye irritation H335 - May cause respiratory irritation H301 - Toxic if swallowed H315 - Causes skin irritation H317 - May cause an allergic skin reaction H361 - Suspected of damaging fertility or the unborn child H371 - May cause damage to organs H410 - Very toxic to aquatic life with long lasting effects H310 + H330 - Fatal in contact with skin or if inhaled

Prevention

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P262 - Do not get in eyes, on skin, or on clothing P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P284 - Wear respiratory protection

Response

P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P362 + P364 - Take off contaminated clothing and wash it before reuse

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Vapors may cause flash fire or explosion. Flammable liquid.

Health hazards

Causes serious eye irritation. Fatal if inhaled. May cause respiratory irritation. Toxic if swallowed. Causes skin irritation. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. May cause damage to organs. Fatal in contact with skin.

Environmental hazards

Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems. ______________________________________________________________________________________________

2.3 Other hazards

Lachrymator (substance which increases the flow of tears) Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.

2.1 Classification of the substance or mixture

Flammable liquids. Category 3 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 2 Acute Inhalation Toxicity - Vapors Category 2 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Skin Sensitization Category 1 Reproductive Toxicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Category 2 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity Category 1